ChemicalBook > CAS DataBase List > Furo[2,3-c]pyridine-5-carboxylic acid (9CI)

Furo[2,3-c]pyridine-5-carboxylic acid (9CI)

Product Name
Furo[2,3-c]pyridine-5-carboxylic acid (9CI)
CAS No.
478148-62-8
Chemical Name
Furo[2,3-c]pyridine-5-carboxylic acid (9CI)
Synonyms
Furo[2,3-c]pyridine-5-carboxylic acid (9CI)
CBNumber
CB71048198
Molecular Formula
C8H5NO3
Formula Weight
163.13
MOL File
478148-62-8.mol
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Furo[2,3-c]pyridine-5-carboxylic acid (9CI) Property

Boiling point:
366.8±22.0 °C(Predicted)
Density 
1.455
storage temp. 
2-8°C
pka
1.06±0.30(Predicted)
Appearance
White to light yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
F865315
Product name
Furo[2,3-C]pyridine-5-carboxylicAcid
Packaging
10mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
119205
Product name
Furo[2,3-c]pyridine-5-carboxylic acid
Purity
95+%
Packaging
250mg
Price
$429
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0392684
Product name
FURO[2,3-C]PYRIDINE-5-CARBOXYLIC ACID
Purity
95.00%
Packaging
5MG
Price
$495.62
Updated
2021/12/16
Matrix Scientific
Product number
119205
Product name
Furo[2,3-c]pyridine-5-carboxylic acid
Purity
95+%
Packaging
1g
Price
$1072
Updated
2021/12/16
AK Scientific
Product number
W6445
Product name
Furo[2,3-c]pyridine-5-carboxylicacid
Packaging
5g
Price
$2786
Updated
2021/12/16
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Furo[2,3-c]pyridine-5-carboxylic acid (9CI) Chemical Properties,Usage,Production

Synthesis

478148-61-7

478148-62-8

The general procedure for the synthesis of furo[2,3-c]pyridine-5-carboxylic acid from furo[2,3-c]pyridine-5-carboxaldehyde was as follows: furo[2,3-c]pyridine-5-carboxaldehyde (850 mg, 5.8 mmol) was dissolved in 10 mL of dimethyl sulfoxide (DMSO). To this solution was added a 3 mL aqueous solution of potassium dihydrogen phosphate (KH2PO4, 221 mg, 1.6 mmol) followed by a 7 mL aqueous solution of sodium chlorite (NaClO2, 920 mg, 8.2 mmol). The reaction mixture was stirred for 3 h at room temperature. After completion of the reaction, the reaction mixture was diluted with 25 mL of water, the pH was adjusted to 10 with 2 N sodium hydroxide (NaOH) solution, and then extracted with ether (3 x 20 mL). The combined ether layers were discarded. The aqueous layer was adjusted to pH 3.5 with 10% aqueous hydrochloric acid (HCl) solution and then extracted with 10% methanol/dichloromethane (MeOH/CH2Cl2, 13 × 10 mL). The combined organic layers were dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated in vacuum to give a light-colored oil. Residual DMSO was removed at room temperature under a stream of nitrogen (N2) to give a white paste. The paste was dissolved in methanol (MeOH) and concentrated to dryness. The white solid was washed with ether and dried to give the crude furano[2,3-c]pyridine-5-carboxylic acid (94% yield). The compound with molecular formula C8H5NO3 was obtained by mass spectrometry (ESI) analysis with a mass-to-charge ratio (m/z) of 162.8 (M-H)-.

References

[1] Patent: US2003/153595, 2003, A1
[2] Patent: US2003/45540, 2003, A1
[3] Patent: WO2004/52894, 2004, A1. Location in patent: Page 36
[4] Journal of Medicinal Chemistry, 2006, vol. 49, # 14, p. 4425 - 4436

Furo[2,3-c]pyridine-5-carboxylic acid (9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Furo[2,3-c]pyridine-5-carboxylic acid (9CI) manufacturers

Career Henan Chemical Co
Product
Furo[2,3-c]pyridine-5-carboxylic acid (9CI) 478148-62-8
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-02-20