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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

Product Name
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
CAS No.
13811-71-7
Chemical Name
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
Synonyms
DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
CBNumber
CB7105982
Molecular Formula
C8H14O6
Formula Weight
206.19
MOL File
13811-71-7.mol
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Property

Melting point:
17 °C
Boiling point:
162 °C/19 mmHg (lit.)
alpha 
-9 º (neat)
Density 
1.205 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.446(lit.)
Flash point:
200 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly), Water (Slightly)
form 
Viscous Liquid
pka
11.61±0.20(Predicted)
Specific Gravity
1.21
color 
Clear colorless
optical activity
[α]23/D 8.5°, neat
Water Solubility 
insoluble
Merck 
14,3855
BRN 
1727143
CAS DataBase Reference
13811-71-7(CAS DataBase Reference)
NIST Chemistry Reference
Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-(13811-71-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-36-26
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29181300
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
213969
Product name
(?)-Diethyl D-tartrate
Purity
≥99%
Packaging
5g
Price
$52.7
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18685
Product name
(2S,3S)-(-)-Diethyl tartrate
Purity
for synthesis
Packaging
25mL
Price
$87
Updated
2024/03/01
Sigma-Aldrich
Product number
213969
Product name
(?)-Diethyl D-tartrate
Purity
≥99%
Packaging
25g
Price
$90.7
Updated
2024/03/01
TCI Chemical
Product number
T1195
Product name
Diethyl D-(-)-Tartrate
Purity
>97.0%(GC)
Packaging
25g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
T1195
Product name
Diethyl D-(-)-Tartrate
Purity
>97.0%(GC)
Packaging
250g
Price
$115
Updated
2024/03/01
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.

Purification Methods

Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Suppliers

Chengdu Likai Chiral Tech Co., LTD.
Tel
028-85247892 18980630336;
Email
zhenzhenge@lkchiralchina.com
Country
China
ProdList
40
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58
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
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64
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4775
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Shanghai Hongbang Pharmaceutical Co., Ltd.
Tel
021-64975436 18917636693
Fax
021-24280809
Email
1377976036@qq.com
Country
China
ProdList
297
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Chengdu rongchuangyiheng Biomedical Technology Co., Ltd
Tel
13438025684
Email
28296972@qq.com
Country
China
ProdList
129
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58
Hubei YiKangYuan Chemical Co., Ltd.
Tel
027-87182908 18064088908
Fax
027-87182900
Email
65824125@qq.com
Country
China
ProdList
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Shandong Winner Biotechnology Co., Ltd.
Tel
15315319889 15315319889
Email
wannaswsw@163.com
Country
China
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224
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
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INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
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View Lastest Price from (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester manufacturers

airuikechemical co., ltd.
Product
(2s,3s)(-)-dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08
Zibo Hangyu Biotechnology Development Co., Ltd
Product
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
Price
US $80.00-800.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-31
Hebei Yanxi Chemical Co., Ltd.
Product
Diisopropyl D-tartrate 13811-71-7
Price
US $40.00-40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-28

13811-71-7, (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl esterRelated Search:


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