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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

Product Name
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
CAS No.
13811-71-7
Chemical Name
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
Synonyms
DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
CBNumber
CB7105982
Molecular Formula
C8H14O6
Formula Weight
206.19
MOL File
13811-71-7.mol
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Property

Melting point:
17 °C
Boiling point:
162 °C/19 mmHg (lit.)
alpha 
-9 º (neat)
Density 
1.205 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.446(lit.)
Flash point:
200 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform (Slightly), Water (Slightly)
form 
Viscous Liquid
pka
11.61±0.20(Predicted)
Specific Gravity
1.21
color 
Clear colorless
optical activity
[α]23/D 8.5°, neat
Water Solubility 
insoluble
Merck 
14,3855
BRN 
1727143
CAS DataBase Reference
13811-71-7(CAS DataBase Reference)
NIST Chemistry Reference
Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-(13811-71-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-36-26
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29181300
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
213969
Product name
(?)-Diethyl D-tartrate
Purity
≥99%
Packaging
5g
Price
$52.7
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18685
Product name
(2S,3S)-(-)-Diethyl tartrate
Purity
for synthesis
Packaging
25mL
Price
$87
Updated
2024/03/01
Sigma-Aldrich
Product number
213969
Product name
(?)-Diethyl D-tartrate
Purity
≥99%
Packaging
25g
Price
$90.7
Updated
2024/03/01
TCI Chemical
Product number
T1195
Product name
Diethyl D-(-)-Tartrate
Purity
>97.0%(GC)
Packaging
25g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
T1195
Product name
Diethyl D-(-)-Tartrate
Purity
>97.0%(GC)
Packaging
250g
Price
$115
Updated
2024/03/01
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.

Purification Methods

Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Preparation Products And Raw materials

Raw materials

DL-Tartaric acid

Preparation Products

(-)-DIOP (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Suppliers

Belgium 2 Canada 2 China 395 Europe 2 Germany 10 India 69 Italy 1 Japan 5 Poland 1 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 United Kingdom 16 United States 57 Global 567
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd
Product
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
Price
US $80.00-800.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-31
airuikechemical co., ltd.
Product
(2s,3s)(-)-dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08
Hebei Yanxi Chemical Co., Ltd.
Product
Diisopropyl D-tartrate 13811-71-7
Price
US $40.00-40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-28

13811-71-7, (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl esterRelated Search:

2,3-Di-O-para-toluoyl-D-tartaric acid (-)-Dibenzoyl-L-tartaric acid monohydrate (+)-Dimethyl L-tartrate (-)-DIBUTYL-D-TARTRATE (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Bis(diethyl-D-tartrate glycolato)diboron Diethyl succinate Bis(diethyl-L-tartrate glycolato)diboron (2R,3R)(+)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER Bis(diisopropyl-L-tartrate glycolato)diboron Bis(diisopropyl-D-tartrate glycolato)diboron Diisopropyl D-tartrate (-)-DIBENZYL D-TARTRATE (-)-DI-TERT-BUTYL D-TARTRATE 3-PYRIDYLMETHYL D-TARTRATE (2S,3S)-(+)-DIETHYL 2,3-O-BENZYLIDENETARTRATE

  • (-)-Diethyl D-tartrate, Made froM unnatural tartaric acid, 99% 25ML
  • (R,R)-(+)-Weinsaeure-diethylester
  • (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (-)-Diethyl (2S,3S)-2,3-dihydroxysuccinate
  • D-(-)-TARTARIC ACID DIETHYL ESTER
  • (2S,3S)-(-)-DIETHYL TARTRATE
  • (2S,3S)(-)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER
  • diethyl [S-(R*,R*)]-tartrate
  • D-tartrate
  • MINUS-TARTARIC ACID DIETHYL ESTER
  • DIETHYL D-TARTRATE, 99+%
  • D (-)Diethy tartrate
  • (-)-Diethyl D-tartrate, made from unnatural tartaric acid, 99%
  • Butanedioic acid, 2,3-dihydroxy-, diethyl ester, S-(R*,R*)-
  • Diethyl-L-(+)-Tartarte
  • D-(-)-WEINSURE-DIETHYLESTER
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Diethyl D-
  • tartrate D-Tartaric acid diethyl ester
  • (2R,3R)-diethyl 2,3-dihydroxysuccinate
  • D-ethyl tartrate
  • (-)-Diethyl D-tartrate
  • Diethyl-D(-)-Tartrate99.0%Min
  • (-)-Diethyl d-tartrate, 99%, made from unnatural tartaric acid
  • (2S,3S)-2,3-Dihydroxysuccinic acid diethyl ester
  • Diethyl dextro-tartrate
  • (2S,3S)(-)-Dihydroxy
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
  • 3S)(-)-Dihydroxybutane-1
  • 4-dioic acid diethyl ester
  • diethyl laevo-tartrate
  • DI-ETHYL-D-TARTRATE (Pure) 13811-71-7
  • Diethyl-D-Tartarate (13811-71-7)
  • EsoMeprazo interMediate C
  • D- two ethyl acetate
  • Dihydroxybutane-1,4-dioic acid diethyl ester
  • D(-)diethyl tartarate
  • D-Tartaric Acid Diethyl Ester,99%e.e.
  • (2S,3S)-(-)-Diethyl tartrate for synthesis
  • dlethyl-tartrate
  • ETHYL TARTRATE
  • (-)-DIETHYL-2,3-DIHYDROXYSUCCINATE
  • (-)-DIETHYL-D-TARTRATE
  • DIETHYL D-(-)-TARTRATE
  • DIETHYL D-TARTRATE
  • DET
  • [-]-TARTARIC ACID DIETHYL ESTER
  • D(-)-DIETHYL TARTRATE
  • D-DET
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester in stock Factory
  • Butanedioic acid, 2,3-dihydroxy-, 1,4-diethyl ester, (2S,3S)-
  • D-(-)-Diethyl L-tartrate
  • (-)-Diethyl D-tartrate >=99%
  • Diethyl Tartrate D(-)
  • (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate,
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
  • diethyl (2S,3S)-2,3-dihydroxybutanedioate
  • (-)-Diethyl tartrate
  • D-(-)-Tartaric Acid Diethyl Ester Diethyl-D-tartrate
  • ( - ) Di Ethyl D Tartrate