ChemicalBook > CAS DataBase List > PHENYL METHACRYLATE

PHENYL METHACRYLATE

Product Name
PHENYL METHACRYLATE
CAS No.
2177-70-0
Chemical Name
PHENYL METHACRYLATE
Synonyms
NSC 177877;PHENYL METHACRYLATE;Phenyl methacrylate , s;Phenyl methacrylate,>95%;phenyl 2-methylprop-2-enoate;Methacrylic acid phenyl ester;Phenyl Methacrylate, 95%, stab.;Phenyl methacrylate, stabilized;2-Methylacrylic acid phenyl ester;2-methyl-2-propenoicaciphenylester
CBNumber
CB7108059
Molecular Formula
C10H10O2
Formula Weight
162.19
MOL File
2177-70-0.mol
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PHENYL METHACRYLATE Property

Melting point:
17 °C
Boiling point:
95-100 °C/16 mmHg (lit.)
Density 
1.052 g/mL at 25 °C (lit.)
vapor pressure 
0.5Pa at 20℃
refractive index 
n20/D 1.512(lit.)
Flash point:
140 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Light yellow
Water Solubility 
Not miscible or difficult to mix with water.
Sensitive 
Light Sensitive
BRN 
1907503
LogP
2.7 at 23.3℃
CAS DataBase Reference
2177-70-0(CAS DataBase Reference)
EPA Substance Registry System
Phenyl methacrylate (2177-70-0)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-42/43
Safety Statements 
23-26-37-60-45-24
RIDADR 
UN 3272 3/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29161400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392162
Product name
Phenyl methacrylate
Purity
90%
Packaging
15ml
Price
$241
Updated
2025/07/31
TCI Chemical
Product number
P2134
Product name
Phenyl Methacrylate (stabilized with BHT)
Purity
>97.0%(GC)
Packaging
5g
Price
$68
Updated
2025/07/31
TCI Chemical
Product number
P2134
Product name
Phenyl Methacrylate (stabilized with BHT)
Purity
>97.0%(GC)
Packaging
25g
Price
$198
Updated
2025/07/31
scipoly
Product number
M-229
Product name
Phenyl methacrylate
Packaging
10g
Price
$80
Updated
2024/07/03
scipoly
Product number
M-229
Product name
Phenyl methacrylate
Packaging
20g
Price
$130
Updated
2024/07/03
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PHENYL METHACRYLATE Chemical Properties,Usage,Production

Uses

Phenyl methacrylate is used as thermoset acrylic resin, fiber finishing agent and comonomers of resin lens.

Flammability and Explosibility

Non flammable

Synthesis

920-46-7

108-95-2

2177-70-0

Phenyl methacrylate was synthesized from methacryloyl chloride and phenol by esterification reaction. The procedure was as follows: phenol (1.0 eq.) was mixed with methacryloyl chloride (1.1 eq.) in anhydrous dichloromethane under dry reaction conditions, triethylamine (1.2 eq.) was added as a base, and the reaction was stirred for 12 hours at room temperature. Upon completion of the reaction, the organic phase was washed with dilute hydrochloric acid to remove unreacted base, followed by washing with saturated sodium bicarbonate solution and water, and finally dried over anhydrous sodium sulfate. The solvent was removed by distillation under reduced pressure to give the crude product. Purification by column chromatography (eluent: petroleum ether/ethyl acetate = 10:1) afforded phenyl methacrylate as a clear oil in 1.45 g yield, 84%. The structure of the product was confirmed by 1H NMR and 13C NMR, and the data were consistent with those reported in the literature.1H NMR (500 MHz, DMSO): δ 7.46-7.41 (m, 2H), 7.30-7.26 (m, 1H), 7.19-7.15 (m, 2H), 6.28 (m, 1H), 5.90 (app p, J=1.55 Hz, 1H ), 2.00 (m, 3H); 13C NMR (125 MHz, DMSO): δ 165.3, 150.6, 135.3, 129.5, 127.7, 125.9, 121.8, 18.1. High-resolution mass spectrometry (HRMS-ESIpos) analysis: calculated value C10H10O2Na [M+Na]+ 185.0572299, measured value 185.057440.

References

[1] Molecular Crystals and Liquid Crystals, 2011, vol. 542, p. 132 - 140
[2] Central European Journal of Chemistry, 2011, vol. 9, # 4, p. 557 - 566
[3] Synlett, 2015, vol. 26, # 14, p. 1973 - 1976
[4] Journal of Polymer Science, Part A: Polymer Chemistry, 2014, vol. 52, # 9, p. 1353 - 1358
[5] Patent: GB470397, 1936,

PHENYL METHACRYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from PHENYL METHACRYLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
phenyl 2-methylprop-2-enoate 2177-70-0
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-24
Shanghai Qyubiotech Co., Ltd.
Product
Phenyl methacrylate 2177-70-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%+
Supply Ability
10000kg per Month
Release date
2022-10-12
Shaanxi Dideu New Materials Co. Ltd
Product
PHENYL METHACRYLATE 2177-70-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-29

2177-70-0, PHENYL METHACRYLATERelated Search:

9-Anthracenylmethyl methacrylate POLY(ETHYLENE GLYCOL) METHYL ETHER METHACRYLATE Benzyl methacrylate 9-Anthryl Methacrylate tetradecyl methacrylate ETHYL COUMARIN-3-CARBOXYLATE AFLATOXIN G1 3-acetyl-6-bromo-2H-chromen-2-one 3-ACETYL-7-HYDROXY-2H-CHROMEN-2-ONE BISPHENOL A DIMETHACRYLATE 3-CARBETHOXYUMBELIFERONE 8-ACETYL DIMETHOXYCOUMARIN DICUMAROL COUMACHLOR Coumarin-3-carboxylic acid METHYL 3-METHYLPENTANOATE Methacrylic acid 2-METHYLVALERIC ACID

  • PHENYL METHACRYLATE
  • 2-methyl-2-propenoicaciphenylester
  • Methacrylic acid phenyl ester
  • Phenyl methacrylate, 94%, stab. with 50ppm BHT
  • 2-Methylacrylic acid phenyl ester
  • 2-Methylpropenoic acid phenyl ester
  • Phenyl methacrylate, 95%, stab. with BHT
  • phenyl 2-methylprop-2-enoate
  • Phenyl Methacrylate, 95%, stab.
  • NSC 177877
  • Phenyl Methacrylate (stabilized with BHT)
  • Phenyl methacrylate, stabilized
  • Phenyl methacrylate , s
  • Phenyl methacrylate stab. with 50ppm BHT
  • PhenylMethacrylate(stabilizedwithBHT)&gt
  • Phenyl methacrylate,>95%
  • 2177-70-0
  • H2CCCH3CO2C6H5
  • Esters
  • Organic Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Building Blocks
  • Acrylic Monomers
  • C10 to C11Monomers
  • Carbonyl Compounds
  • Esters
  • Methacrylate