PHENYL METHACRYLATE
- Product Name
- PHENYL METHACRYLATE
- CAS No.
- 2177-70-0
- Chemical Name
- PHENYL METHACRYLATE
- Synonyms
- NSC 177877;PHENYL METHACRYLATE;Phenyl methacrylate , s;Phenyl methacrylate,>95%;phenyl 2-methylprop-2-enoate;Methacrylic acid phenyl ester;Phenyl Methacrylate, 95%, stab.;Phenyl methacrylate, stabilized;2-Methylacrylic acid phenyl ester;2-methyl-2-propenoicaciphenylester
- CBNumber
- CB7108059
- Molecular Formula
- C10H10O2
- Formula Weight
- 162.19
- MOL File
- 2177-70-0.mol
PHENYL METHACRYLATE Property
- Melting point:
- 17 °C
- Boiling point:
- 95-100 °C/16 mmHg (lit.)
- Density
- 1.052 g/mL at 25 °C (lit.)
- vapor pressure
- 0.5Pa at 20℃
- refractive index
- n20/D 1.512(lit.)
- Flash point:
- 140 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- clear liquid
- color
- Colorless to Light yellow
- Water Solubility
- Not miscible or difficult to mix with water.
- Sensitive
- Light Sensitive
- BRN
- 1907503
- LogP
- 2.7 at 23.3℃
- CAS DataBase Reference
- 2177-70-0(CAS DataBase Reference)
- EPA Substance Registry System
- Phenyl methacrylate (2177-70-0)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-42/43
- Safety Statements
- 23-26-37-60-45-24
- RIDADR
- UN 3272 3/PG 3
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29161400
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 392162
- Product name
- Phenyl methacrylate
- Purity
- 90%
- Packaging
- 15ml
- Price
- $241
- Updated
- 2025/07/31
- Product number
- P2134
- Product name
- Phenyl Methacrylate (stabilized with BHT)
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $68
- Updated
- 2025/07/31
- Product number
- P2134
- Product name
- Phenyl Methacrylate (stabilized with BHT)
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $198
- Updated
- 2025/07/31
- Product number
- M-229
- Product name
- Phenyl methacrylate
- Packaging
- 10g
- Price
- $80
- Updated
- 2024/07/03
- Product number
- M-229
- Product name
- Phenyl methacrylate
- Packaging
- 20g
- Price
- $130
- Updated
- 2024/07/03
PHENYL METHACRYLATE Chemical Properties,Usage,Production
Uses
Phenyl methacrylate is used as thermoset acrylic resin, fiber finishing agent and comonomers of resin lens.
Flammability and Explosibility
Non flammable
Synthesis
920-46-7
108-95-2
2177-70-0
Phenyl methacrylate was synthesized from methacryloyl chloride and phenol by esterification reaction. The procedure was as follows: phenol (1.0 eq.) was mixed with methacryloyl chloride (1.1 eq.) in anhydrous dichloromethane under dry reaction conditions, triethylamine (1.2 eq.) was added as a base, and the reaction was stirred for 12 hours at room temperature. Upon completion of the reaction, the organic phase was washed with dilute hydrochloric acid to remove unreacted base, followed by washing with saturated sodium bicarbonate solution and water, and finally dried over anhydrous sodium sulfate. The solvent was removed by distillation under reduced pressure to give the crude product. Purification by column chromatography (eluent: petroleum ether/ethyl acetate = 10:1) afforded phenyl methacrylate as a clear oil in 1.45 g yield, 84%. The structure of the product was confirmed by 1H NMR and 13C NMR, and the data were consistent with those reported in the literature.1H NMR (500 MHz, DMSO): δ 7.46-7.41 (m, 2H), 7.30-7.26 (m, 1H), 7.19-7.15 (m, 2H), 6.28 (m, 1H), 5.90 (app p, J=1.55 Hz, 1H ), 2.00 (m, 3H); 13C NMR (125 MHz, DMSO): δ 165.3, 150.6, 135.3, 129.5, 127.7, 125.9, 121.8, 18.1. High-resolution mass spectrometry (HRMS-ESIpos) analysis: calculated value C10H10O2Na [M+Na]+ 185.0572299, measured value 185.057440.
References
[1] Molecular Crystals and Liquid Crystals, 2011, vol. 542, p. 132 - 140
[2] Central European Journal of Chemistry, 2011, vol. 9, # 4, p. 557 - 566
[3] Synlett, 2015, vol. 26, # 14, p. 1973 - 1976
[4] Journal of Polymer Science, Part A: Polymer Chemistry, 2014, vol. 52, # 9, p. 1353 - 1358
[5] Patent: GB470397, 1936,
PHENYL METHACRYLATE Preparation Products And Raw materials
Raw materials
Preparation Products
PHENYL METHACRYLATE Suppliers
- Tel
- --
- Fax
- --
- sales-in@tcichemicals.com
- Country
- India
- ProdList
- 6768
- Advantage
- 58
View Lastest Price from PHENYL METHACRYLATE manufacturers
- Product
- phenyl 2-methylprop-2-enoate 2177-70-0
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-24
- Product
- Phenyl methacrylate 2177-70-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%+
- Supply Ability
- 10000kg per Month
- Release date
- 2022-10-12
- Product
- PHENYL METHACRYLATE 2177-70-0
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-03-29