Benzyl methacrylate
Uses in Perfume- Product Name
- Benzyl methacrylate
- CAS No.
- 2495-37-6
- Chemical Name
- Benzyl methacrylate
- Synonyms
- BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;CHLUMICRYI BZMA Monomer;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER
- CBNumber
- CB7306028
- Molecular Formula
- C11H12O2
- Formula Weight
- 176.21
- MOL File
- 2495-37-6.mol
Benzyl methacrylate Property
- Melting point:
- <25 °C
- Boiling point:
- 95-98 °C/4 mmHg (lit.)
- Density
- 1.04 g/mL at 25 °C (lit.)
- vapor pressure
- 3Pa at 20℃
- refractive index
- n20/D 1.512(lit.)
- Flash point:
- 225 °F
- storage temp.
- 2-8°C(protect from light)
- form
- clear liquid
- color
- Colorless
- Water Solubility
- Insoluble in water.
- Sensitive
- Light Sensitive
- BRN
- 2045924
- Stability:
- Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive.
- LogP
- 3.1 at 20℃
- CAS DataBase Reference
- 2495-37-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzyl methacrylate(2495-37-6)
- EPA Substance Registry System
- 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 409448
- Product name
- Benzyl methacrylate
- Purity
- 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 250ml
- Price
- $80.75
- Updated
- 2025/07/31
- Product number
- 409448
- Product name
- Benzyl methacrylate
- Purity
- 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
- Packaging
- 1l
- Price
- $259.35
- Updated
- 2025/07/31
- Product number
- M0279
- Product name
- Benzyl Methacrylate (stabilized with MEHQ)
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $19
- Updated
- 2025/07/31
- Product number
- M0279
- Product name
- Benzyl Methacrylate (stabilized with MEHQ)
- Purity
- >98.0%(GC)
- Packaging
- 500mL
- Price
- $72
- Updated
- 2025/07/31
- Product number
- M-138
- Product name
- Benzyl methacrylate
- Packaging
- 100g
- Price
- $31
- Updated
- 2024/07/03
Benzyl methacrylate Chemical Properties,Usage,Production
Uses in Perfume
Benzyl methacrylate has found some use in perfume compositions where it may introduce very desirable notes in Rose and other floral fragrances, in Chypre, Oriental and heavy woody fragrance types, etc. It blends excellently with Oakmoss, Vetiver, Phenylacetaldehyde dimethylacetal, Citrcnel101,as well as with Lavender, Lavandin, Spike Lavender, etc. The ester is also used in soap and detergent perfumes, where its low cost allows for a more liberal application.
Description
The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].
Chemical Properties
Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.
Uses
Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Flammability and Explosibility
Not classified
Synthesis
80-62-6
100-51-6
2495-37-6
GENERAL METHODS: In Examples 62-64, methyl methacrylate was converted to benzyl methacrylate with benzyl alcohol by an ester exchange reaction as shown in Table 13. In Example 62, lanthanum nitrate and tri-n-octylphosphine were first azeotropically refluxed with dimethyl carbonate for 1 hour according to the method of Example 24, followed by evaporation of the dimethyl carbonate at room temperature, and the resulting catalyst was used in the reaction. In Examples 63 and 64, methyltridecylammonium methyl carbonate was used directly as the catalyst. Under these conditions, benzyl methacrylate was obtained in high yields. It is to be noted that in Example 62, higher yields than Example 62 are expected to be obtained if isolated phosphonium salts are used rather than in situ prepared catalysts. Although not listed in Table 13, a variety of by-products are generated when potassium tert-butoxide is used as a catalyst.
Advantages
The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.
References
[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.
Benzyl methacrylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzyl methacrylate manufacturers
- Product
- Benzyl methacrylate 2495-37-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- Customise
- Release date
- 2025-10-09
- Product
- Benzyl Methacrylate 2495-37-6
- Price
- US $0.00/kg
- Min. Order
- 1000kg
- Purity
- 98
- Supply Ability
- 40tons
- Release date
- 2025-06-23
- Product
- Benzyl methacrylate 2495-37-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-08