ChemicalBook > CAS DataBase List > 5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE

5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE

Product Name
5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE
CAS No.
90381-07-0
Chemical Name
5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE
Synonyms
2-trifluoromethyl-5-chlorobenzaldehyde;Benzaldehyde, 5-chloro-2-(trifluoromethyl)-
CBNumber
CB71091013
Molecular Formula
C8H4ClF3O
Formula Weight
208.57
MOL File
90381-07-0.mol
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5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Property

Boiling point:
82-86℃
Density 
1.423±0.06 g/cm3(Predicted)
refractive index 
1.4880
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
liquid
color 
Clear, colourless
Sensitive 
Air Sensitive
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Safety

Risk Statements 
22-36-43
Safety Statements 
26-36/37
HS Code 
2913000090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
C381705
Product name
5-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
50mg
Price
$60
Updated
2021/12/16
Matrix Scientific
Product number
074464
Product name
5-Chloro-2-(trifluoromethyl)benzaldehyde
Purity
95+%
Packaging
1g
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC67847
Product name
5-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
10g
Price
$56
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC67847
Product name
5-Chloro-2-(trifluoromethyl)benzaldehyde
Packaging
25g
Price
$112
Updated
2021/12/16
Apolloscientific
Product number
PC302415
Product name
5-Chloro-2-(trifluoromethyl)benzaldehyde
Purity
98%
Packaging
5g
Price
$77
Updated
2021/12/16
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5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

261763-21-7

90381-07-0

General procedure for the synthesis of 5-chloro-2-trifluoromethylbenzaldehyde from (5-chloro-2-trifluoromethylphenyl)methanol: (5-chloro-2-trifluoromethylphenyl)methanol (347 mg, 1.66 mmol) was dissolved in dichloromethane (10 mL). Pyridinium chlorochromate (717 mg, 3.32 mmol) was added to the solution and the reaction mixture was stirred for 2 hours at room temperature. After the reaction was completed, the reaction solution was diluted with ether and stirring was continued for 1 hour. Subsequently, the reaction mixture was filtered to remove insoluble impurities and the filtrate was concentrated to remove solvent. Finally, the crude product was purified by silica gel column chromatography using a hexane solution of 10% ethyl acetate as eluent to afford 5-chloro-2-trifluoromethylbenzaldehyde as a colorless oil (285 mg, 82% yield).1H NMR (400 MHz, MeOH-d4) δ 10.33 (s, 1H), 7.90 (s, 1H), 7.69 (d, 1H, J = 8.4 Hz), 7.54 (d, 1H, J = 8.4 Hz).

References

[1] Patent: WO2006/44454, 2006, A1. Location in patent: Page/Page column 13-14

5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE 90381-07-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE 90381-07-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
5-CHLORO-2-(TRIFLUOROMETHYL)BENZALDEHYDE 90381-07-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
200kg
Release date
2018-12-17