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TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE

Product Name
TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE
CAS No.
159217-89-7
Chemical Name
TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE
Synonyms
TERT-BUTYL 4-IODOPHENYLCARBAMATE;N-BOC-4-IODOANILIN;N-BOC-4-IODOANILINE;N-Boc-4-iodoaniline;ert-Butyl(4-iodophenyl)carbamate;TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE;N-(tert-Butoxycarbonyl)-4-iodoaniline;(4-Iodophenyl)carbamic acid tert-butyl ester;N-(4-iodophenyl)carbamic acid tert-butyl ester;Carbamic acid, N-(4-iodophenyl)-, 1,1-dimethylethyl ester
CBNumber
CB7118623
Molecular Formula
C11H14INO2
Formula Weight
319.14
MOL File
159217-89-7.mol
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TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE Property

Melting point:
144-148 °C
Boiling point:
299.0±23.0 °C(Predicted)
Density 
1.591±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
solid
pka
13.12±0.70(Predicted)
Appearance
White to off-white Solid
Sensitive 
Light Sensitive
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-43-50
Safety Statements 
36/37-61
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
HS Code 
2924297099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
761826
Product name
N-Boc-4-iodoaniline
Purity
95%
Packaging
5g
Price
$201
Updated
2023/06/20
Sigma-Aldrich
Product number
761826
Product name
N-Boc-4-iodoaniline
Purity
95%
Packaging
1g
Price
$41.2
Updated
2022/05/15
American Custom Chemicals Corporation
Product number
HCH0027219
Product name
TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE
Purity
95.00%
Packaging
5G
Price
$830.74
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0027219
Product name
TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE
Purity
95.00%
Packaging
25G
Price
$1257.63
Updated
2021/12/16
Oakwood
Product number
010776
Product name
tert-ButylN-(4-iodophenyl)carbamate
Purity
95%
Packaging
100g
Price
$345
Updated
2021/12/16
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TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE Chemical Properties,Usage,Production

Synthesis

24424-99-5

540-37-4

159217-89-7

GENERAL STEPS: The reaction was carried out in a 50 mL round-bottomed flask at 80°C under reduced pressure for 10 minutes. In a typical experiment, 5 mmol of p-iodoaniline was mixed with 5 mmol of di-tert-butyl dicarbonate and the reaction lasted for 10 minutes. Upon completion of the reaction, the solvent was removed by rotary evaporator under vacuum to give tert-butyl (4-iodophenyl)carbamate.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2006, vol. 16, # 22, p. 5864 - 5869
[2] Research on Chemical Intermediates, 2017, vol. 43, # 3, p. 1355 - 1363
[3] Chemical Communications, 2013, vol. 49, # 61, p. 6909 - 6911
[4] Patent: WO2004/12736, 2004, A1. Location in patent: Page/Page column 24
[5] Organic Letters, 2018, vol. 20, # 7, p. 1693 - 1697

TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE Suppliers

Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80

159217-89-7, TERT-BUTYL N-(4-IODOPHENYL)CARBAMATERelated Search:


  • N-(tert-Butoxycarbonyl)-4-iodoaniline
  • N-BOC-4-IODOANILINE
  • TERT-BUTYL 4-IODOPHENYLCARBAMATE
  • TERT-BUTYL N-(4-IODOPHENYL)CARBAMATE
  • (4-Iodophenyl)carbamic acid tert-butyl ester
  • N-(4-iodophenyl)carbamic acid tert-butyl ester
  • Carbamic acid, N-(4-iodophenyl)-, 1,1-dimethylethyl ester
  • ert-Butyl(4-iodophenyl)carbamate
  • <i>N</i>-Boc-4-iodoaniline
  • N-BOC-4-IODOANILIN
  • 159217-89-7
  • C11H14INO2