4,4'-Bis(hydroxymethyl)biphenyl

Product Name: 4,4'-Bis(hydroxymethyl)biphenyl
CAS No.: 1667-12-5
Chemical Name: 4,4'-Bis(hydroxymethyl)biphenyl
Synonyms: 4,4'-BISBENZYL ALCOHOL;4,4'-Biphenyldimethanol;4,4'-Biphenyldimethanol;DIPHENYL-4,4'-DIMETHANOL;4,4'-BiphenyldimethanolCAS;4,4'-Biphenyldimethanol CAS;4,4'-Biphenyldimethanol >4,4'-Dihydroxymethylbiphenyl;(Biphenyl-4,4'-diyl)dimethanol;[1,1ˊ-biphenyl] 4,4ˊ-dimethanol
CBNumber: CB7121319
Molecular Formula: C14H14O2
Formula Weight: 214.26
MOL File: 1667-12-5.mol

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4,4'-Bis(hydroxymethyl)biphenyl Property

Melting point:: 191-192°C
Boiling point:: 416.3±40.0 °C(Predicted)
Density: 1.174±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: almost transparency in hot EtOH
form: powder to crystal
pka: 14.01±0.10(Predicted)
color: White to Light yellow
CAS DataBase Reference: 1667-12-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 41
Safety Statements: 26-39
HS Code: 2906.29.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H304May be fatal if swallowed and enters airways

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P331Do NOT induce vomiting.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2623
Product name: 4,4'-Biphenyldimethanol
Purity: >98.0%(GC)
Packaging: 5g
Price: $165
Updated: 2025/07/31

TRC

Product number: H939930
Product name: 4,4''-Bis(hydroxymethyl)biphenyl
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: H939930
Product name: 4,4''-Bis(hydroxymethyl)biphenyl
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB55013
Product name: 4,4'-Bisbenzyl alcohol
Packaging: 25g
Price: $131.25
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB55013
Product name: 4,4'-Bisbenzyl alcohol
Packaging: 10g
Price: $55
Updated: 2021/12/16

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4,4'-Bis(hydroxymethyl)biphenyl Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Synthesis

792-74-5

1667-12-5

a) Preparation of 4,4'-bis(hydroxy-methyl)biphenyl. In a 2-liter flask equipped with a mechanical stirrer, condenser, addition funnel and heating bath, 789 mg (20.8 mmol) of LiAlH4 was dissolved in 150 ml of anhydrous THF (tetrahydrofuran). A solution of 7.5 g (27.7 mmol) of 4,4'-bis(methoxycarbonyl)biphenyl dissolved in 500 ml of anhydrous THF was heated to 50 °C under an inert atmosphere and added dropwise to the above mixture over 1 hour. After the dropwise addition, stirring was continued at 50 °C for 30 minutes. Subsequently, the reaction mixture was cooled to room temperature and 15 ml of THF/H2O (80:20) mixture was carefully added to quench the excess LiAlH4. The reaction mixture was filtered through a Septum G2 filter and the precipitate was washed with ethanol (3 x 100 ml). The filtrate and washings were combined and evaporated to dryness under vacuum in a heating bath at 40 °C. The residue was redissolved in 100 ml of hot acetone (50 °C), filtered to remove insoluble matter, dried with anhydrous Na2SO4 and evaporated again to dryness. Finally 5.74 g of 4,4'-bis(hydroxymethyl)biphenyl was obtained in 96.6% molar yield.

References

[1] Patent: EP469682, 1992, A1
[2] Russian Journal of Organic Chemistry, 2008, vol. 44, # 8, p. 1172 - 1179
[3] Chemical Physics Letters, 2008, vol. 460, # 4-6, p. 474 - 477

4,4'-Bis(hydroxymethyl)biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-Bis(hydroxymethyl)biphenyl Suppliers

Americas 1 China 99 Europe 2 India 3 Japan 4 United Kingdom 8 United States 16 Global 133

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

kemikalieimport

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Email: Sales@kemikalieimport.dk
Country: Europe
ProdList: 6685
Advantage: 47

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View Lastest Price from 4,4'-Bis(hydroxymethyl)biphenyl manufacturers

Career Henan Chemical Co

Product: 4,4'-Bis(hydroxymethyl)biphenyl 1667-12-5
Price: US $8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100KG
Release date: 2018-12-15

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