4-Fluorobenzyl chloride
- Product Name
- 4-Fluorobenzyl chloride
- CAS No.
- 352-11-4
- Chemical Name
- 4-Fluorobenzyl chloride
- Synonyms
- JACS-352-11-4;Benzyl for CFCs;AKOS BBS-00003856;p-Fluorbenzylchlorid;alpha-Chloro-p-fluor;Fluorobenzyl chlorid;p-fluorochlorobenzyl;P-FLUOROBENZYL CHLORIDE;4-FLUOROBENZYL CHLORIDE;-Chloro-p-fluorotoluene
- CBNumber
- CB7166866
- Molecular Formula
- C7H6ClF
- Formula Weight
- 144.57
- MOL File
- 352-11-4.mol
4-Fluorobenzyl chloride Property
- Melting point:
- -18 °C
- Boiling point:
- 82 °C26 mm Hg(lit.)
- Density
- 1.207 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.513(lit.)
- Flash point:
- 141 °F
- storage temp.
- Store below +30°C.
- solubility
- Chloroform (Slightly), Hexanes (Slightly)
- form
- Powder or Crystals
- Specific Gravity
- 1.207
- color
- Yellow
- explosive limit
- 1.30%(V)
- Water Solubility
- 417mg/L(temperature not stated)
- Sensitive
- Lachrymatory
- BRN
- 742272
- InChI
- 1S/C7H6ClF/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
- InChIKey
- IZXWCDITFDNEBY-UHFFFAOYSA-N
- SMILES
- Fc1ccc(CCl)cc1
- CAS DataBase Reference
- 352-11-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-(chloromethyl)-4-fluoro-(352-11-4)
- EPA Substance Registry System
- Benzene, 1-(chloromethyl)-4-fluoro- (352-11-4)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-22
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2920 8/PG 2
- WGK Germany
- 2
- F
- 19
- Hazard Note
- Corrosive/Lachrymatory
- TSCA
- TSCA listed
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29036990
- Storage Class
- 8A - Combustible corrosive hazardous materials
- Hazard Classifications
- Skin Corr. 1B
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- F8004
- Product name
- 4-Fluorobenzyl chloride
- Purity
- 99%
- Packaging
- 25g
- Price
- $42.5
- Updated
- 2025/07/31
- Product number
- F8004
- Product name
- 4-Fluorobenzyl chloride
- Purity
- 99%
- Packaging
- 100g
- Price
- $69.6
- Updated
- 2025/07/31
- Product number
- F0204
- Product name
- 4-Fluorobenzyl Chloride
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $59
- Updated
- 2025/07/31
- Product number
- F0204
- Product name
- 4-Fluorobenzyl Chloride
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $374
- Updated
- 2025/07/31
- Product number
- F588360
- Product name
- p-FluorobenzylChloride
- Packaging
- 10g
- Price
- $110
- Updated
- 2021/12/16
4-Fluorobenzyl chloride Chemical Properties,Usage,Production
Chemical Properties
clear colorless to slightly yellow liquid
Uses
p-Fluorobenzyl Chloride is a chemical intermediate in the synthesis of various pharmaceutical and agricultural goods.
Synthesis
Photocatalyst: nanosilver/silver chloride surface plasma composite;
Substrate: p-fluorotoluene; Halogenator: potassium chloride;
(1) 50 ml of water, 7 g of sodium chloride and 2.5 ml of hydrochloric acid (mass fraction 35%) were added in a photocatalytic reactor, respectively, and dissolved with stirring;
(2) then add 0.3 g of nanosilver/silver chloride as a photocatalyst (nanosilver loading 8.5 mol%) and 0.05 g of tetrabutylammonium chloride as a phase-transfer catalyst, and finally add 15 ml of p-fluorotoluene; the loading is the molar amount of nanoprecious metals as a molar percentage of the total amount of nanoprecious metal/semiconductor surface plasmonic composite.
(3) Under strong magnetic stirring, then turn on 300W xenon lamp irradiation, and react for 5h at room temperature;
(4) Filtering to recover the catalyst, separating out the organic phase and recycling the aqueous phase for reuse. Samples were analyzed by GS, the conversion rate of p-fluorotoluene was 36%, and no polychlorinated products were detected. Distillation to collect 180.5-182 fraction, got 4-fluorobenzyl chloride, yield 89%.
4-Fluorobenzyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Fluorobenzyl chloride manufacturers
- Product
- 4-Fluorobenzyl chloride 352-11-4
- Price
- US $30.00-10.00/KG
- Min. Order
- 50KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-11-05
- Product
- 4-Fluorobenzyl chloride 352-11-4
- Price
- US $15.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20 tons
- Release date
- 2023-10-25
- Product
- 4-Fluorobenzyl chloride 352-11-4
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99.%
- Supply Ability
- 10 ton
- Release date
- 2024-08-19