Sodium ferrocyanide

Chemical properties Applications Production Storage Reactivity appearance

Product Name: Sodium ferrocyanide
CAS No.: 13601-19-9
Chemical Name: Sodium ferrocyanide
Synonyms: Sodium hexacyanoferrate;Sodium ferrocyanide;Sodium hexacyanoferr;SODIUMFERROCYANIDE,FCC;SODIUM PRUSSIATE, YELLOW;YELLOW PRUSSIATE OF SODA;Sodiumferrocyanide10xH2O;Sodiumhexacyanoferrat(II);sodiumhexacyanoferate(11);sodiumprussiateyellow[qr]
CBNumber: CB7179592
Molecular Formula: C6FeN6.4Na
Formula Weight: 303.91
MOL File: 13601-19-9.mol

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Sodium ferrocyanide Property

Melting point:: 82°C -10H₂O
Density: 1.458
solubility: insoluble in organic solvents
form: yellow monoclinic crystals
color: yellow monoclinic crystals, crystalline
Water Solubility: soluble
Merck: 14,8616
Stability:: Stable. Incompatible with strong oxidizing agents.
LogP: -0.250 (est)
CAS DataBase Reference: 13601-19-9(CAS DataBase Reference)
EPA Substance Registry System: Ferrate(4-), hexakis(cyano-.kappa.C)-, sodium (1:4), (OC-6-11)- (13601-19-9)

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Safety

Hazard Codes: Xn
Risk Statements: 21/22-32-52/53
Safety Statements: 36/37-61
RIDADR: UN1588
HazardClass: 6.1
PackingGroup: III
Hazardous Substances Data: 13601-19-9(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: ING0008372
Product name: SODIUM FERROCYANIDE
Purity: 95.00%
Packaging: 5MG
Price: $504.01
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0008372
Product name: SODIUM FERROCYANIDE
Purity: 95.00%
Packaging: 5KG
Price: $795
Updated: 2021/12/16

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Sodium ferrocyanide Chemical Properties,Usage,Production

Chemical properties

Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN)6]4−. In its hydrous form, Na4Fe(CN)6 • 10H2O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ferrocyanide anion. Despite the presence of the cyanide ligands, sodium ferrocyanide has low toxicity (acceptable daily intake 0–0.025 mg/kg body weight). The ferrocyanides are less toxic than many salts of cyanide, because they tend not to release free cyanide.However, like all ferrocyanide salt solutions, addition of an acid can result in the production of hydrogen cyanide gas, which is toxic.

Applications

Sodium hexacyanoferrate(II) decahydrate is being used and studied as a possible cathode material for sodium ion batteries.

Production

Sodium ferrocyanide is produced industrially from hydrogen cyanide, ferrous chloride, and calcium hydroxide, the combination of which affords Ca2[Fe(CN)6] • 11H2O. A solution of this salt is then treated with sodium salts to precipitate the mixed calcium-sodium salt CaNa2[Fe(CN)6], which in turn is treated with sodium carbonate to give the tetrasodium salt.

Storage

Hygroscopic, -20°C Freezer, Under inert atmosphere

Reactivity

Sodium ferrocyanide is a coordination compound of iron. The cyanide ligands are tightly bound to the iron, so it is not as toxic as simple inorganic cyanide salts. However, this compound can release hydrogen cyanide gas upon reaction with acids.

appearance

Sodium ferrocyanide is a yellow crystalline salt Na4Fe(CN)6 similar to potassium ferrocyanide and used in making iron blue pigments, blueprint paper, and dyes — Called also yellow prussiate of soda

Chemical Properties

solid

Uses

Sodium Ferrocyanide is an anticaking agent and crystallizing agent. It is sometimes added as a crystallizing agent to salt when it crystallizes to generate lagged and bulky crystals which resist caking. It also functions as a water-soluble anticaking agent.

Uses

Manufacture of sodium ferricyanide, blue pig- ments, blueprint paper, anticaking agent for salt, ore flotation, pickling metals, polymerization catalyst, photographic fixing agent.

Definition

ChEBI: Sodium hexacyanoferrate(4-) is a hexacyanoferrate(4-) salt.

General Description

Odorless yellow solid. Sinks and mixes with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sodium ferrocyanide has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.

Health Hazard

None recorded.

Flammability and Explosibility

Non flammable

Safety Profile

When heated to decomposition emits toxic fumes of CN-.

Purification Methods

Crystallise it from hot water (0.7mL/g), until free of ferricyanide as shown by the absence of formation of Prussian Blue colour with ferrous sulfate solution.

Sodium ferrocyanide Preparation Products And Raw materials

Raw materials

Black cyanide Tetrapotassium hexacyanoferrate trihydrate Calcium Ferrocyanide Sodium cyanide HYDROGEN CYANIDE FERROUS SULFATE Potassium ferrocyanide trihyrate Iron Ferrous sulfate heptahydrate Sodium carbonate

Preparation Products

Tetrapotassium hexacyanoferrate trihydrate Prussian Blue Lactic acid Potassium ferrocyanide trihyrate

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View Lastest Price from Sodium ferrocyanide manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Sodium ferrocyanide 13601-19-9
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-18

Hebei Chuanghai Biotechnology Co,.LTD

Product: Sodium ferrocyanide 13601-19-9
Price: US $100.00-50.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-20

Henan Bao Enluo International TradeCo.，LTD

Product: Sodium ferrocyanide 13601-19-9
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-05-26

13601-19-9, Sodium ferrocyanideRelated Search:

5-Chlorovaleric acid Zirconium dioxide Sodium chloride Sodium bicarbonate Sodium benzoate DL-α-Tocopherol D(+)-Glucose Sodium citrate Potassium ferrocyanide trihyrate Prussian Blue Sodium chlorite Tetrapotassium hexacyanoferrate trihydrate Sodium thiocyanate Sulfuric acid iron(2+) salt monohydrate Soda lime SODIUM CARBONATE, MONOHYDRATE Diphenolic acid Ferrous sulfate heptahydrate

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sodium ferrocyanide anhydrous

YELLOW PRUSSIATE OF SODA

ferrate(4-),hexakis(cyano-c)-,tetrasodium,(oc-6-11)-[qr]

hexacyano-ferrate(4-tetrasodium[qr]

hexakis(cyano-C)-,tetrasodium,(OC-6-11)-Ferrate(4-)

sodiumferrocyanide(na4(fe(cn)6))[qr]

sodiumhexacyanoferate(11)

sodiumhexacyanoferate(ii)[qr]

sodiumhexacyanoferrate(ii)[qr]

sodiumprussiateyellow[qr]

tetrasodium,(oc-6-11)-ferrate(4-hexakis(cyano-c)-

tetrasodiumferrocyanide[qr]

tetrasodiumhexacyanoferrate(4-)[qr]

tetrasodiumhexacyanoferrate[qr]

tetrasodiumhexakis(cyano-c)ferrate(4-)

yellowprussiateofsoda[qr]

SodiumFerrocyanideYellowSodaPrussiateNa4Fe(Cn)6.10H2O

Sodiumferrocyanide10xH2O

Ferrate(4-), hexakis(cyano-.kappa.C)-, tetrasodium, (OC-6-11)-

SODIUMFERROCYANIDE,FCC

SODIUMFERROCYANIDE,REAGENT

Sodium ferrocyanide

Natriumhexacyanoferrat (II)

Ferrate(4-), hexakis(cyano-C)-, tetrasodium, (OC-6-11)-

Ferrate(4-), hexakis(cyano-κC)-, sodium (1:4), (OC-6-11)-

Ferrate(4-), hexakis(cyano-.kappa.C)-, sodium (1:4), (OC-6-11)-

Sodium ferrocyanide ISO 9001：2015 REACH

high quality Sodium ferrocyanide 13601-19-9

13601-19-9

1443-22-1

Na4FeCN6鈥0H2O

Na4FeCN6

Na4FeCN610H2O

Na4FeCN610H20

C6FeN64Na

Intermediates of Dyes and Pigments

Inorganics