ChemicalBook > CAS DataBase List > Mefenpyr-diethyl

Mefenpyr-diethyl

Product Name
Mefenpyr-diethyl
CAS No.
135590-91-9
Chemical Name
Mefenpyr-diethyl
Synonyms
EMBARK;HOE-107892;1-(3,4-Dic;Mefenpyr-dieth;Mefenpyr-diethy;MEFENPYR-DIETHYL;Mefenpyr-diethyl >Mefenpyr-diethyl [iso];Mefenpyr-diethyl Standard;Oxymetazoline Impurity 17
CBNumber
CB7190999
Molecular Formula
C16H18Cl2N2O4
Formula Weight
373.23
MOL File
135590-91-9.mol
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Mefenpyr-diethyl Property

Melting point:
50-52°
Boiling point:
451.1±55.0 °C(Predicted)
Density 
1.34±0.1 g/cm3(Predicted)
vapor pressure 
0-0.001Pa at 20-50℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
-5.89±0.70(Predicted)
form 
Solid
color 
Off-White to Light Beige
Water Solubility 
Water: < 0.1 mg/mL (insoluble)
InChI
InChI=1S/C16H18Cl2N2O4/c1-4-23-14(21)12-9-16(3,15(22)24-5-2)20(19-12)13-7-6-10(17)8-11(13)18/h6-8H,4-5,9H2,1-3H3
InChIKey
OPGCOAPTHCZZIW-UHFFFAOYSA-N
SMILES
N1(C2=CC=C(Cl)C=C2Cl)C(C)(C(OCC)=O)CC(C(OCC)=O)=N1
LogP
4 at 25℃ and pH4-9
CAS DataBase Reference
135590-91-9(CAS DataBase Reference)
NIST Chemistry Reference
Mefenpyr-diethyl(135590-91-9)
EPA Substance Registry System
Mefenpyr-diethyl (135590-91-9)
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Safety

Hazard Codes 
N
Risk Statements 
51/53
Safety Statements 
60-61
RIDADR 
UN 3077
WGK Germany 
3
RTECS 
UQ6473000
HS Code 
2933.19.4300
HazardClass 
9
PackingGroup 
III
Toxicity
Log P (octanol/water): 3.83 (pH 6.3, 21°). LD50 in rats (mg/kg): >5000 orally, >4000 dermally; LC50 in carp (mg/l): 2.4 (Hacker)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CRM46302
Product name
Mefenpyr-diethyl
Purity
certified reference material, TraceCERT?, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Packaging
50MG
Price
$86.5
Updated
2025/07/31
Sigma-Aldrich
Product number
46302
Product name
Mefenpyr-diethyl
Purity
PESTANAL
Packaging
100mg
Price
$126
Updated
2025/07/31
TCI Chemical
Product number
M2604
Product name
Mefenpyr-diethyl
Purity
>98.0%(HPLC)
Packaging
1g
Price
$95
Updated
2025/07/31
TCI Chemical
Product number
M2604
Product name
Mefenpyr-diethyl
Purity
>98.0%(HPLC)
Packaging
5g
Price
$285
Updated
2025/07/31
Chem-Impex
Product number
39359
Product name
Mefenpyr-diethyl,≥98%(HPLC)Hazmat
Purity
≥98%(HPLC)
Packaging
5G
Price
$327.31
Updated
2021/12/16
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Mefenpyr-diethyl Chemical Properties,Usage,Production

Description

Mefenpyr-diethyl is a foliar-acting safener of the pyrazoline chemical group, and after its absorption, the metabolization and detoxification of herbicides occur in treated plants. It is often used with fenoxaprop-P-ethyl and iodosulfuron for selective weed control in cereals. However, it does not have herbicidal activity.

Uses

Mefenpyr-diethyl is used in herbicidal and herbicide-safener combinations as a resistant breaking solution for modern agriculture.

Uses

Herbicide safener.

Synthesis

97-63-2

27143-12-0

135590-91-9

The general procedure for the synthesis of diethyl 1-(2,4-dichlorophenyl)-5-methyl-4,5-dihydro-1H-pyrazole-3,5-dicarboxylate from ethyl methacrylate and ethyl 2-chloro-2-(2-(2,4-dichlorophenyl)hydrazinylidene)acetate was as follows: 22.8 g of ethyl methacrylate and 14.8 g of 2-chloro-2-(2-(2,4-dichlorophenyl) hydrazinyl) ethyl acetate were mixed and heated to 50-60 °C. Over 30 minutes, 7.6 g of triethylamine was slowly added dropwise to the reaction mixture. Subsequently, the reaction temperature was raised to 70 °C and the reaction was continued with stirring for 2 hours. After completion of the reaction, the reaction mixture was allowed to cool to room temperature and the precipitate was isolated by filtration. The filtrate was carefully concentrated under reduced pressure to afford 18.1 g of the target product 1-(2,4-dichlorophenyl)-5-methyl-4,5-dihydro-1H-pyrazole-3,5-dicarboxylic acid diethyl ester.

References

[1] Patent: WO2017/92466, 2017, A1. Location in patent: Page/Page column 11

Mefenpyr-diethyl Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Mefenpyr-diethyl manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
mefenpyr-diethyl 135590-91-9
Price
US $50.00/KG
Min. Order
25KG
Purity
99
Supply Ability
100ton
Release date
2020-07-22
Huizhili (Changzhou) Life Technology Co., Ltd
Product
mefenpyr-diethyl 135590-91-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
97%
Supply Ability
ES:100 tons
Release date
2025-02-14
Longyan Tianhua Biological Technology Co., Ltd
Product
Mefenpyr-diethyl 135590-91-9
Price
US $90.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2020-10-29

135590-91-9, Mefenpyr-diethylRelated Search:


  • 1-(2,4-Dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylic acid diethyl ester
  • MEFENPYR-DIETHYL
  • EMBARK
  • Mefenpyr-diethyl [iso]
  • 1H-Pyrazole-3,5-dicarboxylic acid, 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-, diethyl ester
  • mefenpyr-diethyl (bsi, pa iso)
  • Herbicide Safener Mefenpyr-Diethyl
  • HOE-107892
  • Mefenpyr-diethy
  • Mefenpyr-dieth
  • Diethyl 1-(2,4-dichlorophenyl)-5-methyl-4,5-dihydro-1H-pyrazole-3,5-dicarboxylate
  • basic nickel(ous) carbonate
  • Mefenpyr-diethyl &gt
  • Mefenpyr-diethyl Standard
  • Mefenpyr-diethyl@1000 μg/mL in Methanol
  • Mefenpyr-diethyl@100 μg/mL in Methanol
  • 1H-Pyrazole-3,5-dicarboxylic acid, 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-, 3,5-diethyl ester
  • 1-(3,4-Dic
  • Diethyl 1-(2,4-Dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate
  • Diethyl 1-(3,4-Dichlorophenyl)-5-methyl-2-pyrazoline-3,5-dicarboxylate
  • 3,5-diethyl 1-(2,4-dichlorophenyl)-5-methyl-4,5-dihydro-1H-pyrazole-3,5-dicarboxylate
  • Mefenpyr-diethyl in methanol
  • Mefenpyr-diethyl 100 μg/ml Acetonitrile
  • Mefenpyr-diethyl in Acetone
  • Oxymetazoline Impurity 17
  • 135590-91-9
  • C16H18Cl2N2O4