Chlorodiisopropylphosphine
- Product Name
- Chlorodiisopropylphosphine
- CAS No.
- 40244-90-4
- Chemical Name
- Chlorodiisopropylphosphine
- Synonyms
- Di-i-propyL;AURORA KA-1318;98% (i-Pr)2PCl;CHLORODIISOPROPYLPHOSHINE;DIISOPROPYLCHLOROPHOSPHINE;CHLORODIISOPROPYLPHOSPHINE;DI-I-PROPYLCHLOROPHOSPHINE;Chlorodiiosopropylphosphine;bis-isopropylchlorophosphine;CHLORODIISOPROPYLPHOSPHINE,96%
- CBNumber
- CB7202728
- Molecular Formula
- C6H14ClP
- Formula Weight
- 152.6
- MOL File
- 40244-90-4.mol
Chlorodiisopropylphosphine Property
- Boiling point:
- 69 °C33 mm Hg(lit.)
- Density
- 0.959 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.475(lit.)
- Flash point:
- 39 °F
- storage temp.
- Refrigerator
- form
- Liquid
- color
- Clear light yellow
- Sensitive
- air sensitive, moisture sensitive
- InChI
- InChI=1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
- InChIKey
- JZPDBTOWHLZQFC-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)Cl
- CAS DataBase Reference
- 40244-90-4(CAS DataBase Reference)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 16-26-27-36/37/39-45-1
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 3
- HazardClass
- 3.1
- PackingGroup
- II
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 337773
- Product name
- Chlorodiisopropylphosphine
- Purity
- 96%
- Packaging
- 5g
- Price
- $85.1
- Updated
- 2025/07/31
- Product number
- 337773
- Product name
- Chlorodiisopropylphosphine
- Purity
- 96%
- Packaging
- 25g
- Price
- $247
- Updated
- 2025/07/31
- Product number
- C4014
- Product name
- Chlorodiisopropylphosphine
- Packaging
- 5G
- Price
- $135
- Updated
- 2025/07/31
- Product number
- C1720
- Product name
- Chlorodiisopropylphosphine
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 15-1800
- Product name
- Di-i-propylchlorophosphine, min. 97%
- Packaging
- 1g
- Price
- $49
- Updated
- 2024/03/01
Chlorodiisopropylphosphine Chemical Properties,Usage,Production
Description
Chlorodiisopropylphosphine is an organophosphorus compound of particular interest in synthetic chemistry, where it is used as a reagent in the preparation of phosphine ligands for transition metal complexes. Its utility in synthesising these complexes is due to the reactivity of the chloro group, which other groups can substitute to create a diverse array of ligands. This reactivity is also exploited in the study of catalysis, as the resulting phosphine ligands can be used to modulate the activity and selectivity of metal catalysts. In addition, Chlorodiisopropylphosphine is investigated for its potential in forming new organophosphorus compounds with applications in materials science. Researchers are also interested in the compound′s role in synthesising flame retardants, where its phosphorus content could contribute to the material′s flame-retarding properties.
Chemical Properties
Colorless to light yellow liqui
Uses
Chlorodiisopropylphosphine can be used:
- To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
- As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
- A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.
Application
Chlorodiisopropylphosphine is widely used for preparing organic phosphine pesticides, secondary phosphine, organic phosphine ligand and high-efficiency organic metal catalyst in thermoplastic elastomer synthesis, can also be used as an important component of a non-lethal weapon system, and is recently used for electrochemically synthesizing novel electrolyte salt fluoroalkyl lithium phosphonate of a lithium ion secondary battery as a green energy source due to the special structure of the organic phosphine catalyst.[1]
reaction suitability
reagent type: ligand
reaction type: Arylations
Synthesis
Chlorodiisopropylphosphine can be synthesized by using Mg, chloro iso-propane and phosphine trichloride as the main raw material. The optimum reacting condition for the synthesis includes, the material proportioning being PCl3 : i-C3H7C1 = 1 : 1.8 (mol ratio), the reaction temperature being -30 deg. C, dropping time being 1.25h. By employing THF for substituting ether as the solvent, the reaction can be accelerated and the yield can be increased.[1]
References
[1] The synthetic method of diisopropyl phosphine chloride. Patent CN1724548A.
Chlorodiisopropylphosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Chlorodiisopropylphosphine manufacturers
- Product
- Chlorodiisopropylphosphine 40244-90-4
- Price
- US $0.00-0.00/Kg
- Min. Order
- 0.10000000149011612Kg
- Purity
- 98％
- Supply Ability
- 100kg
- Release date
- 2024-07-26
- Product
- Chlorodiisopropylphosphine, AcroSeal 40244-90-4
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2020-01-15
- Product
- CHLORODIISOPROPYLPHOSPHINE 40244-90-4
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-10