ChemicalBook > CAS DataBase List > (4-MORPHOLIN-4-YL-PHENYL)METHANOL

(4-MORPHOLIN-4-YL-PHENYL)METHANOL

Product Name
(4-MORPHOLIN-4-YL-PHENYL)METHANOL
CAS No.
280556-71-0
Chemical Name
(4-MORPHOLIN-4-YL-PHENYL)METHANOL
Synonyms
(4-MORPHOLINOPHENYL)METHANOL;BUTTPARK 98\50-30;RARECHEM AL BD 1130;4-Morpholinobenzyl Alcohol;4-(Morpholin-4-yl)benzyl alcohol;4-(4-Morpholinyl)benzenemethanol;(4-MORPHOLIN-4-YL-PHENYL)METHANOL;Benzenemethanol, 4-(4-morpholinyl)-;(4-MORPHOLIN-4-YL-PHENYL)METHANOL 95%;4-(Morpholin-4-yl)benzyl alcohol, 4-[4-(Hydroxymethyl)phenyl]morpholine
CBNumber
CB7215272
Molecular Formula
C11H15NO2
Formula Weight
193.24
MOL File
280556-71-0.mol
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(4-MORPHOLIN-4-YL-PHENYL)METHANOL Property

Melting point:
96 °C
Boiling point:
378.4±42.0 °C(Predicted)
Density 
1.160±0.06 g/cm3(Predicted)
storage temp. 
Storage temp. 2-8°C
form 
powder
pka
14.40±0.10(Predicted)
color 
White
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M732738
Product name
(4-Morpholin-4-yl-phenyl)methanol
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
M732738
Product name
(4-Morpholin-4-yl-phenyl)methanol
Packaging
50mg
Price
$60
Updated
2021/12/16
Apolloscientific
Product number
OR23268
Product name
[4-(Morpholin-4-yl)phenyl]methanol
Purity
98%
Packaging
1g
Price
$66
Updated
2021/12/16
SynQuest Laboratories
Product number
4H01-1-X2
Product name
[(4-Morpholin-4-yl)phenyl]methanol
Purity
98%
Packaging
1g
Price
$72
Updated
2021/12/16
Matrix Scientific
Product number
071840
Product name
(4-Morpholin-4-yl-phenyl)methanol
Purity
95+%
Packaging
1g
Price
$93
Updated
2021/12/16
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(4-MORPHOLIN-4-YL-PHENYL)METHANOL Chemical Properties,Usage,Production

Synthesis

541-41-3

7470-38-4

280556-71-0

C. Synthesis of 4-(4-morpholinyl)benzyl alcohol. At -10 °C, 4-(4-morpholinyl)benzoic acid (1.00 g, 4.83 mmol) and 4-methylmorpholine (0.53 mL, 4.8 mmol) were dissolved in tetrahydrofuran (25 mL), followed by the addition of ethyl chloroformate (0.46 mL, 4.8 mmol). After 0.25 h of reaction, sodium borohydride (550 mg, 14.5 mmol) was added to the mixture followed by slow addition of methanol (50 mL). Next, the mixture was treated with 5% aqueous acetic acid, after which the mixture was concentrated. The residue was purified by silica gel column chromatography (eluent: ethyl acetate/hexane) to give 164 mg (18% yield) of 4-morpholinobenzyl alcohol. The product was characterized by 1H NMR, IR spectroscopy, field desorption mass spectrometry (FD-MS, m/e 193 (M+)), and elemental analysis (calculated values for C11H15NO2: C, 68.37; H, 7.82; N, 7.25; measured values: C, 68.46; H, 7.95; N, 7.21).

References

[1] Patent: US6610704, 2003, B1

(4-MORPHOLIN-4-YL-PHENYL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-MORPHOLIN-4-YL-PHENYL)METHANOL Suppliers

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280556-71-0, (4-MORPHOLIN-4-YL-PHENYL)METHANOLRelated Search:

4-Morpholinobenzoic acid (4-MORPHOLIN-4-YL-PHENYL)METHANOL ETHYL 4-MORPHOLINOBENZENECARBOXYLATE 3-Amino-4-morpholin-4-yl-benzoic acid 3-AMINO-4-MORPHOLIN-4-YL-BENZOIC ACID ETHYL ESTER 4-(N-MORPHOLINO)-BENZENE METHYLCARBOXYLATE METHYL 2-CHLORO-4-MORPHOLINOBENZENECARBOXYLATE (4-MORPHOLINO-3-NITROPHENYL)METHANOL HYDROCHLORIDE 4-MORPHOLIN-4-YL-3-NITRO-BENZOIC ACID 3-ACETYLAMINO-4-MORPHOLIN-4-YL-BENZOIC ACID (2-MORPHOLIN-4-YL-PHENYL)METHANOL,(2-MORPHOLIN-4-YL-PHENYL)METHANOL 95% 2-CHLORO-4-MORPHOLINOBENZENECARBOXYLIC ACID 5(6)-IODOACETAMIDOMORPHOLINORHODAMINE AMINOMORPHOLINORHODAMINE RARECHEM AL BI 1086 RARECHEM AL BP 1086 METHYL 4-(2,6-DIMETHYLMORPHOLINO)-3-NITROBENZENECARBOXYLATE RARECHEM AL BF 1086

  • 4-Morpholinobenzyl Alcohol
  • 4-(Morpholin-4-yl)benzyl alcohol
  • 4-(Morpholin-4-yl)benzyl alcohol, 4-[4-(Hydroxymethyl)phenyl]morpholine
  • (4-MORPHOLINOPHENYL)METHANOL
  • (4-MORPHOLIN-4-YL-PHENYL)METHANOL
  • RARECHEM AL BD 1130
  • BUTTPARK 98\50-30
  • (4-MORPHOLIN-4-YL-PHENYL)METHANOL 95%
  • Benzenemethanol, 4-(4-morpholinyl)-
  • 4-(4-Morpholinyl)benzenemethanol
  • 280556-71-0
  • ALCOHOL
  • Alcohols and Derivatives
  • Heterocycles