ChemicalBook > CAS DataBase List > 2-METHOXY-6-METHYLBENZALDEHYDE

2-METHOXY-6-METHYLBENZALDEHYDE

Product Name
2-METHOXY-6-METHYLBENZALDEHYDE
CAS No.
54884-55-8
Chemical Name
2-METHOXY-6-METHYLBENZALDEHYDE
Synonyms
6-Methoxy-2-methylbenzaldehyde;2-METHOXY-6-METHYLBENZALDEHYDE;Benzaldehyde, 2-Methoxy-6-Methyl-
CBNumber
CB7225811
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
54884-55-8.mol
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2-METHOXY-6-METHYLBENZALDEHYDE Property

Melting point:
40-41℃
Boiling point:
256℃
Density 
1.062
Flash point:
113℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Off-white to yellow <40°C Solid,>41°C Liquid
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Safety

HS Code 
2912490090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M263450
Product name
2-Methoxy-6-methylbenzaldehyde
Packaging
100mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2715-1-44
Product name
2-Methoxy-6-methylbenzaldehyde
Purity
97%
Packaging
1g
Price
$108
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0379052
Product name
2-METHOXY-6-METHYL BENZALDEHYDE
Purity
95.00%
Packaging
5MG
Price
$502.14
Updated
2021/12/16
AK Scientific
Product number
Z4871
Product name
2-Methoxy-6-methylbenzaldehyde
Packaging
10g
Price
$702
Updated
2021/12/16
Chemenu
Product number
CM253595
Product name
2-Methoxy-6-methylbenzaldehyde
Purity
95+%
Packaging
25g
Price
$926
Updated
2021/12/16
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2-METHOXY-6-METHYLBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis Reference(s)

Synthesis, p. 1000, 1983 DOI: 10.1055/s-1983-30599

Synthesis

2944-49-2

54884-55-8

General procedure for the synthesis of 2-methoxy-6-methylbenzaldehyde from 1-methoxy-2,3-dimethylbenzene: Potassium peroxydisulfate (89.31 g, 0.33 mol) and copper(II) sulfate pentahydrate (27.22 g, 0.11 mol) were added to a mixture of 1-methoxy-2,3-dimethylbenzene (15 g, 0.11 mol) in aqueous acetonitrile ( 750 mL, V/V=1:1). The reaction mixture was stirred under reflux conditions for 15 minutes until complete consumption of the feedstock was confirmed by thin layer chromatography (TLC) detection. Upon completion of the reaction, the mixture was cooled to room temperature and the product was extracted with dichloromethane (2 x 225 mL). The organic layers were combined and washed sequentially with water (2 x 100 mL) and saturated saline (100 mL). The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain the crude product. The crude product was purified by silica gel column chromatography with the eluent of 4/96 (V/V) ethyl acetate/hexane to afford 2-methoxy-6-methylbenzaldehyde (7.32 g, 44.2% yield). The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3): δ 2.60 (3H, s), 3.90 (3H, s), 6.80 (2H, t), 7.40 (1H, t), 10.65 (1H, s).

References

[1] Tetrahedron, 1996, vol. 52, # 6, p. 2199 - 2216
[2] Chemical Communications, 2013, vol. 49, # 77, p. 8626 - 8628
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 2, p. 762 - 766
[4] Angew. Chem., 2013, vol. 125, # 2, p. 791 - 796,6
[5] Chemistry - A European Journal, 2015, vol. 21, # 29, p. 10322 - 10325

2-METHOXY-6-METHYLBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-METHOXY-6-METHYLBENZALDEHYDE manufacturers

Career Henan Chemical Co
Product
2-METHOXY-6-METHYLBENZALDEHYDE 54884-55-8
Price
US $9.80/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-03