2-METHOXY-6-METHYLBENZALDEHYDE
- Product Name
- 2-METHOXY-6-METHYLBENZALDEHYDE
- CAS No.
- 54884-55-8
- Chemical Name
- 2-METHOXY-6-METHYLBENZALDEHYDE
- Synonyms
- 6-Methoxy-2-methylbenzaldehyde;2-METHOXY-6-METHYLBENZALDEHYDE;Benzaldehyde, 2-Methoxy-6-Methyl-
- CBNumber
- CB7225811
- Molecular Formula
- C9H10O2
- Formula Weight
- 150.17
- MOL File
- 54884-55-8.mol
2-METHOXY-6-METHYLBENZALDEHYDE Property
- Melting point:
- 40-41℃
- Boiling point:
- 256℃
- Density
- 1.062
- Flash point:
- 113℃
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Appearance
- Off-white to yellow <40°C Solid,>41°C Liquid
Safety
- HS Code
- 2912490090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M263450
- Product name
- 2-Methoxy-6-methylbenzaldehyde
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 2715-1-44
- Product name
- 2-Methoxy-6-methylbenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $108
- Updated
- 2021/12/16
- Product number
- CHM0379052
- Product name
- 2-METHOXY-6-METHYL BENZALDEHYDE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $502.14
- Updated
- 2021/12/16
- Product number
- Z4871
- Product name
- 2-Methoxy-6-methylbenzaldehyde
- Packaging
- 10g
- Price
- $702
- Updated
- 2021/12/16
- Product number
- CM253595
- Product name
- 2-Methoxy-6-methylbenzaldehyde
- Purity
- 95+%
- Packaging
- 5g
- Price
- $266
- Updated
- 2021/12/16
2-METHOXY-6-METHYLBENZALDEHYDE Chemical Properties,Usage,Production
Synthesis Reference(s)
Synthesis, p. 1000, 1983 DOI: 10.1055/s-1983-30599
Synthesis
2944-49-2
54884-55-8
General procedure for the synthesis of 2-methoxy-6-methylbenzaldehyde from 1-methoxy-2,3-dimethylbenzene: Potassium peroxydisulfate (89.31 g, 0.33 mol) and copper(II) sulfate pentahydrate (27.22 g, 0.11 mol) were added to a mixture of 1-methoxy-2,3-dimethylbenzene (15 g, 0.11 mol) in aqueous acetonitrile ( 750 mL, V/V=1:1). The reaction mixture was stirred under reflux conditions for 15 minutes until complete consumption of the feedstock was confirmed by thin layer chromatography (TLC) detection. Upon completion of the reaction, the mixture was cooled to room temperature and the product was extracted with dichloromethane (2 x 225 mL). The organic layers were combined and washed sequentially with water (2 x 100 mL) and saturated saline (100 mL). The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain the crude product. The crude product was purified by silica gel column chromatography with the eluent of 4/96 (V/V) ethyl acetate/hexane to afford 2-methoxy-6-methylbenzaldehyde (7.32 g, 44.2% yield). The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3): δ 2.60 (3H, s), 3.90 (3H, s), 6.80 (2H, t), 7.40 (1H, t), 10.65 (1H, s).
References
[1] Tetrahedron, 1996, vol. 52, # 6, p. 2199 - 2216
[2] Chemical Communications, 2013, vol. 49, # 77, p. 8626 - 8628
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 2, p. 762 - 766
[4] Angew. Chem., 2013, vol. 125, # 2, p. 791 - 796,6
[5] Chemistry - A European Journal, 2015, vol. 21, # 29, p. 10322 - 10325
2-METHOXY-6-METHYLBENZALDEHYDE Preparation Products And Raw materials
Raw materials
Preparation Products
2-METHOXY-6-METHYLBENZALDEHYDE Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
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View Lastest Price from 2-METHOXY-6-METHYLBENZALDEHYDE manufacturers
- Product
- 2-METHOXY-6-METHYLBENZALDEHYDE 54884-55-8
- Price
- US $9.80/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg -1000kg
- Release date
- 2020-01-03