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2-Amino-4-(benzyloxy)pyridine

Product Name
2-Amino-4-(benzyloxy)pyridine
CAS No.
85333-26-2
Chemical Name
2-Amino-4-(benzyloxy)pyridine
Synonyms
4-(Benzyloxy)pyridin-2-amine;2-Amino-4-(benzyloxy)pyridine;4-phenylmethoxypyridin-2-amine;4-phenylmethoxy-2-pyridinamine;2-Pyridinamine, 4-(phenylmethoxy)-;4-(benzyloxy)pyridin-2-amine - [B87559]
CBNumber
CB72470314
Molecular Formula
C12H12N2O
Formula Weight
200.24
MOL File
85333-26-2.mol
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2-Amino-4-(benzyloxy)pyridine Property

Boiling point:
379.7±27.0 °C(Predicted)
Density 
1.180
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
7.76±0.11(Predicted)
Appearance
Light yellow to yellow Solid
InChI
InChI=1S/C12H12N2O/c13-12-8-11(6-7-14-12)15-9-10-4-2-1-3-5-10/h1-8H,9H2,(H2,13,14)
InChIKey
RAFCWIXBEWVPGL-UHFFFAOYSA-N
SMILES
C1(N)=NC=CC(OCC2=CC=CC=C2)=C1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B288050
Product name
4-(Benzyloxy)pyridin-2-amine
Packaging
500mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
W8806
Product name
4-(Benzyloxy)-2-pyridinamine
Packaging
1g
Price
$117
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB153561
Product name
4-(Benzyloxy)pyridin-2-amine
Packaging
2g
Price
$170
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB153561
Product name
4-(Benzyloxy)pyridin-2-amine
Packaging
500mg
Price
$55
Updated
2021/12/16
Matrix Scientific
Product number
075559
Product name
4-(Benzyloxy)pyridin-2-amine
Purity
95+%
Packaging
1g
Price
$278
Updated
2021/12/16
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2-Amino-4-(benzyloxy)pyridine Chemical Properties,Usage,Production

Synthesis

182556-72-5

85333-26-2

Step A: Preparation of 4-(benzyloxy)pyridin-2-amine: 4-(benzyloxy)-2-chloropyridine (1.10 g, 5.01 mmol), Pd2dba3 (46 mg, 0.05 mmol), and 2-(dicyclohexylphosphino)-2',4',6'-tripropyl-1,1 '-biphenyl (57 mg, 0.120 mmol) were dissolved in THF (10 mL) in THF (10 mL) and a 1.0 M solution of ammonia in THF (6 mL) was added. The mixture was heated to 65 °C for 30 min of reaction and then cooled to room temperature. The reaction mixture was concentrated by a silica gel column and eluted with a 20:1 solvent mixture of ethyl acetate/methanol to give a light golden solid product (0.97 g, 96% yield).

References

[1] Patent: EP2090575, 2009, A1. Location in patent: Page/Page column 54-55
[2] Patent: WO2018/65365, 2018, A1. Location in patent: Page/Page column 114-115
[3] Patent: WO2007/89512, 2007, A1. Location in patent: Page/Page column 181

2-Amino-4-(benzyloxy)pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Amino-4-(benzyloxy)pyridine Suppliers

Abblis Chemicals LLC
Tel
+1-832-373-8299
Fax
+1-713-664-0347
Email
info@abblis.com
Country
United States
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Accela ChemBio Inc.
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+1(858) 699-3322
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+1(858) 876-1948
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marketing@accelachem.com
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United States
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6024
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Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
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Alchem Pharmtech,Inc.
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8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
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Aladdin Scientific
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Email
tp@aladdinsci.com
Country
United States
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52923
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Aceschem Inc.
Tel
+1-817863-6948 +1-(817)863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
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Combi-Blocks Inc.
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Email
sales@combi-blocks.com
Country
United States
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Matrix Scientific
Tel
--
Fax
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Email
sales@matrixscientific.com
Country
United States
ProdList
6632
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80
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View Lastest Price from 2-Amino-4-(benzyloxy)pyridine manufacturers

Shanghai Rlavie Technology Co ltd
Product
4-phenylmethoxy-2-pyridinamine 85333-26-2
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%minHPLC
Supply Ability
500kgs/month
Release date
2021-11-20

85333-26-2, 2-Amino-4-(benzyloxy)pyridineRelated Search:


  • 2-Amino-4-(benzyloxy)pyridine
  • 4-(Benzyloxy)pyridin-2-amine
  • 4-phenylmethoxy-2-pyridinamine
  • 4-phenylmethoxypyridin-2-amine
  • 2-Pyridinamine, 4-(phenylmethoxy)-
  • 4-(benzyloxy)pyridin-2-amine - [B87559]
  • 85333-26-2