Tetrabutylammonium fluoride trihydrate

Product Name: Tetrabutylammonium fluoride trihydrate
CAS No.: 87749-50-6
Chemical Name: Tetrabutylammonium fluoride trihydrate
Synonyms: TBAF 3H2O;TETRABUTYLAMMONIUM FLUORIDE HYDRATE;TETRA-N-BUTYLAMMONIUM FLUORIDE 3 H2O;TBAF TRIHYDRATE;TBAF Hydrate;TETRABUTYLAMMONIUMFLUORID-3-HYDRAT;TETRA-N-BUTYLAMMONIUM FLUORIDE TRIHYDRATE;1-Butanaminium, N,N,N-tributyl-, fluoride, trihydrate;Tetra(but-1-;uoride hydrate
CBNumber: CB7247235
Molecular Formula: C16H38FNO
Formula Weight: 279.48
MOL File: 87749-50-6.mol

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Tetrabutylammonium fluoride trihydrate Property

Melting point:: 62-63 °C(lit.)
Flash point:: -17℃
storage temp.: Store below +30°C.
form: Crystalline Powder, Crystals and/or Chunks
Specific Gravity: 0.887
color: White to slightly yellow
PH: pH (50g/l, 25℃) : 5.0～8.0
Water Solubility: SOLUBLE
Sensitive: Hygroscopic
BRN: 3761900
Exposure limits: ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
InChI: InChI=1S/C16H36N.FH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1
InChIKey: UQCWXKSHRQJGPH-UHFFFAOYSA-M
SMILES: [N+](CCCC)(CCCC)(CCCC)CCCC.[F-].O
CAS DataBase Reference: 87749-50-6(CAS DataBase Reference)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-36/37/38
Safety Statements: 26-36/37/39-45-26 37/39
RIDADR: UN 1759 8/PG 1
WGK Germany: 3
F: 3-10
Hazard Note: Irritant
TSCA: T
HazardClass: 6.1
PackingGroup: II
HS Code: 38220000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 86843
Product name: Tetrabutylammonium fluoride trihydrate
Purity: technical, ≥90% (T)
Packaging: 50g
Price: $213
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18164
Product name: Tetra-n-butylammonium fluoride trihydrate
Purity: for synthesis
Packaging: 5G
Price: $70.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 86843
Product name: Tetrabutylammonium fluoride trihydrate
Purity: technical, ≥90% (T)
Packaging: 250g
Price: $608
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18164
Product name: Tetra-n-butylammonium fluoride trihydrate
Purity: for synthesis
Packaging: 10g
Price: $79.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18164
Product name: Tetra-n-butylammonium fluoride trihydrate
Purity: for synthesis
Packaging: 50g
Price: $356
Updated: 2024/03/01

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Tetrabutylammonium fluoride trihydrate Chemical Properties,Usage,Production

Description

Tetrabutylammonium fluoride trihydrate is a commonly used salt within the realms of organic chemistry and biochemistry. This compound is employed as a potent base, finding extensive use in diverse applications, including organic compound synthesis, buffer preparation, and protein purification. It plays a pivotal role in the synthesis of various organic compounds, such as carboxylic acids, amines, and alcohols. Additionally, this compound facilitates the purification of nucleic acids, including DNA and RNA. Acting as a strong base, tetrabutylammonium fluoride trihydrate possesses the ability to deprotonate a wide range of organic compounds. It is commonly used in applications such as preparation of deprotecting agents, synthesis of lipophilic peprides during DNA transfections, and many more.

Chemical Properties

white crystals or crystalline powder

Uses

Reactant for:
Preparation of deprotecting agents in preparation of cellulose derivatives
Synthesis of lipophilic peptides for DNA transfections in vivo
Dehydrobromination reactions

General Description

Tetrabutylammonium fluoride trihydrate is a mild base used in reactions like aldol-type condensation reactions, Michael-type reactions, ring-opening reactions. Its is also used as a promoter in cross-coupling reactions and cyclization of carbocycles and heterocycles.

Tetrabutylammonium fluoride trihydrate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tetrabutylammonium fluoride trihydrate manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: Tetrabutylammonium fluoride trihydrate 87749-50-6
Price: US $1000.00-800.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-16

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Tetrabutylammonium Fluoride Trihydrate 87749-50-6
Price: US $180.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-28

hebei hongtan Biotechnology Co., Ltd

Product: Tetrabutylammonium fluoride trihydrate 87749-50-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000
Release date: 2024-03-22

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87749-50-6

C16F1H36N1

C16H36FN3H2O

C16H36NF3H2O

C16H42FNO3

CH3CH2CH2CH24NF3H2O

CH3CH234NF3H2O

Synthetic Reagents

Protection and Derivatization

Fluoride Sources

Deprotection

Pyridines ,Heterocyclic Acids

Pharmaceutical intermediates

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