4-Boc-2-(broMoMethyl)Morpholine

Product Name: 4-Boc-2-(broMoMethyl)Morpholine
CAS No.: 765914-78-1
Chemical Name: 4-Boc-2-(broMoMethyl)Morpholine
Synonyms: 4-Boc-broMoMethylMorpholine;4-Boc-2-(broMoMethyl)Morpholine;n-boc-(2)-(broMoMethyl)Morpholine;tert-butyl 2-(broMoMethyl)Morpholine-4-carboxylate;2-Bromomethylmorpholine-4-carboxylic acid tert-butyl ester;4-Morpholinecarboxylic acid, 2-(bromomethyl)-, 1,1-dimethylethyl ester
CBNumber: CB72651737
Molecular Formula: C10H18BrNO3
Formula Weight: 280.16
MOL File: 765914-78-1.mol

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4-Boc-2-(broMoMethyl)Morpholine Property

Boiling point:: 328.8±32.0 °C(Predicted)
Density: 1.334±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: -2.34±0.40(Predicted)
Appearance: White to yellow Solid

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Safety

HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Activate Scientific

Product number: AS3686
Product name: N-Boc-(2)-(Bromomethyl)morpholine
Purity: 95+%
Packaging: 250mg
Price: $308
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0365482
Product name: 4-BOC-2-(BROMOMETHYL)MORPHOLINE
Purity: 95.00%
Packaging: 5MG
Price: $503.42
Updated: 2021/12/16

Activate Scientific

Product number: AS3686
Product name: N-Boc-(2)-(Bromomethyl)morpholine
Purity: 95+%
Packaging: 1g
Price: $620
Updated: 2021/12/16

Matrix Scientific

Product number: 093665
Product name: 4-Boc-2-(bromomethyl)morpholine
Purity: 95+%
Packaging: 250mg
Price: $756
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H56-9-5R
Product name: 4-Boc-2-(bromomethyl)morpholine
Packaging: 1g
Price: $1440
Updated: 2021/12/16

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4-Boc-2-(broMoMethyl)Morpholine Chemical Properties,Usage,Production

Synthesis

135065-69-9

765914-78-1

To a solution of tert-butyl 2-(hydroxymethyl)morpholine-4-carboxylate (0.67 g, 3.1 mmol) in dichloromethane (35 mL) was added carbon tetrabromide (CBr4, 2.06 g, 6.17 mmol) at -20 °C, followed by the slow dropwise addition of a solution of triphenylphosphine (PPh3, 1.70 g, 6.48 mmol) in dichloromethane (25 mL). The reaction mixture was maintained at -15 °C for 18 h, and subsequently brought to room temperature with continued stirring for 1.5 h. The reaction was carried out under reduced pressure. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue was purified by silica gel column chromatography (eluent: ethyl acetate/hexane) to afford the target product tert-butyl 2-(bromomethyl)morpholine-4-carboxylate 0.55 g in 63% yield, which was used directly in the subsequent reaction.

References

[1] Patent: WO2007/58850, 2007, A2. Location in patent: Page/Page column 44

4-Boc-2-(broMoMethyl)Morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Boc-2-(broMoMethyl)Morpholine Suppliers

China 39 India 1 United Kingdom 2 United States 5 Global 47

ForeChem (Nantong) Technology Co.,Ltd.

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4-Boc-2-(broMoMethyl)Morpholine

4-Boc-broMoMethylMorpholine

tert-butyl 2-(broMoMethyl)Morpholine-4-carboxylate

n-boc-(2)-(broMoMethyl)Morpholine

2-Bromomethylmorpholine-4-carboxylic acid tert-butyl ester

4-Morpholinecarboxylic acid, 2-(bromomethyl)-, 1,1-dimethylethyl ester

765914-78-1