ChemicalBook > CAS DataBase List > TRANS-2-METHYL-2-BUTENAL

TRANS-2-METHYL-2-BUTENAL

Product Name
TRANS-2-METHYL-2-BUTENAL
CAS No.
497-03-0
Chemical Name
TRANS-2-METHYL-2-BUTENAL
Synonyms
2-METHYL-2-BUTENAL;(E)-2-methylbut-2-enal;(E)-2-Methyl-2-butenal;TIGLALDEHYDE;FEMA 3407;tigaldehyde;Methylbutenal;TIGLINALDEHYDE;CH3CH=C(CH3)CHO;(E)-tiglaldehyde
CBNumber
CB7276338
Molecular Formula
C5H8O
Formula Weight
84.12
MOL File
497-03-0.mol
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TRANS-2-METHYL-2-BUTENAL Property

Melting point:
-101.15°C (estimate)
Boiling point:
116-119 °C752 mm Hg(lit.)
Density 
0.871 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.448(lit.)
FEMA 
3407 | 2-METHYL-2-BUTENAL
Flash point:
65 °F
storage temp. 
Flammables area
solubility 
soluble in Chloroform
form 
Liquid
color 
Clear colorless to yellow
Odor
at 0.10?%?in?dipropylene glycol. strong green fruit
Water Solubility 
Soluble in water
Sensitive 
Air Sensitive
JECFA Number
1201
BRN 
1698207
Stability:
Air sensitive, Light Sensitive
LogP
1.065 (est)
CAS DataBase Reference
497-03-0(CAS DataBase Reference)
EPA Substance Registry System
trans-2-Methylcrotonaldehyde (497-03-0)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38-10
Safety Statements 
16-26-36
RIDADR 
UN 1989 3/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29121990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W340707
Product name
trans-2-Methyl-2-butenal
Purity
sumofisomers,≥99%,FG
Packaging
100g
Price
$204
Updated
2024/03/01
Sigma-Aldrich
Product number
W340707
Product name
trans-2-Methyl-2-butenal
Purity
sumofisomers,≥99%,FG
Packaging
1kg
Price
$1320
Updated
2024/03/01
Sigma-Aldrich
Product number
W340707
Product name
trans-2-Methyl-2-butenal
Purity
sumofisomers,≥99%,FG
Packaging
5kg
Price
$5160
Updated
2024/03/01
Sigma-Aldrich
Product number
192619
Product name
Tiglic aldehyde
Purity
≥96%
Packaging
5g
Price
$44.6
Updated
2024/03/01
Sigma-Aldrich
Product number
192619
Product name
Tiglic aldehyde
Purity
≥96%
Packaging
25g
Price
$93.7
Updated
2024/03/01
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TRANS-2-METHYL-2-BUTENAL Chemical Properties,Usage,Production

Description

2-Methyl-2-butenal has a penetrating, powerful green ethereal odor. May be prepared by condensation of acetaldehyde and propionaldehyde.

Chemical Properties

trans-2-Methyl-2-butenal is a clear colorless to yellow liquid. B.P. 135℃. Sp.Gr. 0.87. Almost insoluble in water, soluble in alcohol and oils. Powerful and very diffusive, penetrating “gassy” odor of green-ethereal character. Very poor tenacity.

Uses

Tiglic aldehyde was used in the concise total synthesis of 7-demethylpiericidin A1. It was used as starting reagent during the synthesis of:

  • alkyl-branched tetraene hydrocarbons, pheromone component for dried fruit beetle
  • E,E-2,4-dimethyl-2,4-hexa dienal, volatile constituents of the defensive secretions of Leiobunum nigripalpi
  • 4-methyl-2,4-hexadiene-1-ol

General Description

trans-2-Methyl-2-butenal is one of the major volatile constituents of coriander and olive oil.

TRANS-2-METHYL-2-BUTENAL Preparation Products And Raw materials

Raw materials

Preparation Products

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TRANS-2-METHYL-2-BUTENAL Suppliers

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View Lastest Price from TRANS-2-METHYL-2-BUTENAL manufacturers

Career Henan Chemical Co
Product
TRANS-2-METHYL-2-BUTENAL 497-03-0
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

497-03-0, TRANS-2-METHYL-2-BUTENALRelated Search:

DUROQUINONE Methyl 1-cyclohexene-1-carboxylate Tetraphenylcyclopentadienone DIPHENYLCYCLOPROPENONE trans-2-Methyl-2-pentenoic acid 1-Cyclohexene-1-carboxylic acid 1-Cyclopentenecarboxylic acid (-)-PERILLALDEHYDE Mordant Blue 29 1-ACETYL-1-CYCLOHEXENE VITAMIN K1 Jasmone NAPHTHOCHROME GREEN alpha-Methylcinnamic acid 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone Acrolein Crotonaldehyde 2-Butene

  • (2E)-2-Methyl-2-butenal
  • (E)-2-Methyl-2-butenal
  • (E)-2-methylbut-2-en-1-al
  • (E)-2-methylbut-2-enal
  • 2,2-Dimethylacrolein
  • 2-Butenal,2-methyl-,(2E)-
  • 2-Butenal,2-methyl-,(E)-
  • 2-methyl-(E)-2-butenal
  • 2-methyl-,(E)-2-Butenal
  • 2-methyl-2(E)-butenal
  • 2-Methyl-2-butenal, (E)
  • 2-Methyl-2-butenal, trans
  • a-methylcrotonaldehyde
  • CH3CH=C(CH3)CHO
  • Crotonaldehyde, 2-methyl-, (E)-
  • crotonaldehyde,2-methyl-,(E)-
  • E-2-Methyl-2-butenal
  • Tiglaldehyde (2-Methyl-2-butenal)
  • Tiglic acid aldehyde
  • trans-2-methyl-but-2-enal
  • trans-Tiglaldehyde
  • TIGLINALDEHYDE
  • TIGLALDEHYDE
  • 2-METHYL-2-BUTENAL
  • FEMA 3407
  • 2-Methylcrotonaldehyde~Tiglic aldehyde
  • Methylbutenal
  • TRANS-2-METHYL-2-BUTENAL, 96+%
  • 2-METHYLPENTANAL 97+%
  • trans-2-Methyl-2-butenal,97%
  • α,β-dimethylacrolein
  • α,β-dimethylacrylic aldehyde
  • 2-METHYL-2-BUTENE-AL
  • tigaldehyde
  • trans-2,3-Dimethylacrolein, trans-2-Methyl-2-butenal, Tiglic aldehyde, Tiglinaldehyde
  • trans-2,3-Dimethylacrolein, trans-2-Methyl-2-butenal, Tiglinaldehyde
  • (E)-2,3-Dimethylacrylaldehyde
  • Tiglic aldehyde,trans-2,3-Dimethylacrolein, trans-2-Methyl-2-butenal, Tiglinaldehyde
  • trans-2-Methyl-2-butenal,trans-2,3-Dimethylacrolein, trans-2-Methyl-2-butenal, Tiglic aldehyde, Tiglinaldehyde
  • trans-2-Methyl-2-butenal, 98% 5GR
  • Tiglic aldehyde >=96%
  • <i>trans</i>-2-Methyl-2-butenal
  • trans-2-Methyl-2-butenal,98%
  • trans-Methyl-2-butenal
  • TRANS-2-METHYL-2-BUTENAL USP/EP/BP
  • cis-2-methyl-2-butyraldehyde
  • (E)-tiglaldehyde
  • Tiglic AldehydeQ: What is Tiglic Aldehyde Q: What is the CAS Number of Tiglic Aldehyde Q: What is the storage condition of Tiglic Aldehyde Q: What are the applications of Tiglic Aldehyde
  • TRANS-2-METHYL-2-BUT
  • trans-2-Methyl-2-butenal, ≥ 95.0%
  • 497-03-0
  • 11156-11-3
  • ALDEHYDE
  • C1 to C6
  • Carbonyl Compounds
  • Aldehydes
  • Building Blocks
  • Organic Building Blocks