Benzyl methacrylate

Uses in Perfume

Product Name: Benzyl methacrylate
CAS No.: 2495-37-6
Chemical Name: Benzyl methacrylate
Synonyms: BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER;Benzyl Methacrylate, stabilized
CBNumber: CB7306028
Molecular Formula: C11H12O2
Formula Weight: 176.21
MOL File: 2495-37-6.mol

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Benzyl methacrylate Property

Melting point:: <25 °C
Boiling point:: 95-98 °C/4 mmHg (lit.)
Density: 1.04 g/mL at 25 °C (lit.)
vapor pressure: 3Pa at 20℃
refractive index: n20/D 1.512(lit.)
Flash point:: 225 °F
storage temp.: 2-8°C(protect from light)
form: clear liquid
color: Colorless
Water Solubility: Insoluble in water.
Sensitive: Light Sensitive
BRN: 2045924
Stability:: Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive.
LogP: 3.1 at 20℃
CAS DataBase Reference: 2495-37-6(CAS DataBase Reference)
NIST Chemistry Reference: Benzyl methacrylate(2495-37-6)
EPA Substance Registry System: 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 1
TSCA: Yes
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 409448
Product name: Benzyl methacrylate
Purity: 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 250ml
Price: $82.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 409448
Product name: Benzyl methacrylate
Purity: 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor
Packaging: 1l
Price: $264
Updated: 2024/03/01

TCI Chemical

Product number: M0279
Product name: Benzyl Methacrylate (stabilized with MEHQ)
Purity: >98.0%(GC)
Packaging: 25mL
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: M0279
Product name: Benzyl Methacrylate (stabilized with MEHQ)
Purity: >98.0%(GC)
Packaging: 500mL
Price: $76
Updated: 2024/03/01

Alfa Aesar

Product number: L10840
Product name: Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol
Packaging: 50g
Price: $23.65
Updated: 2024/03/01

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Benzyl methacrylate Chemical Properties,Usage,Production

Uses in Perfume

Benzyl methacrylate has found some use in perfume compositions where it may introduce very desirable notes in Rose and other floral fragrances, in Chypre, Oriental and heavy woody fragrance types, etc. It blends excellently with Oakmoss, Vetiver, Phenylacetaldehyde dimethylacetal, Citrcnel101,as well as with Lavender, Lavandin, Spike Lavender, etc. The ester is also used in soap and detergent perfumes, where its low cost allows for a more liberal application.

Description

The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].

Chemical Properties

Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.

Uses

Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Flammability and Explosibility

Not classified

Advantages

The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.

References

[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.

Benzyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl methacrylate Suppliers

Americas 1 Belgium 1 China 257 Europe 2 Germany 7 India 6 Japan 9 South Korea 4 Switzerland 1 The Netherlands 2 United Kingdom 5 United States 32 Global 327

BOC Sciences

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Alfa Chemistry

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Aceschem Inc.

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Alfa Chemistry

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Waterstone Technology, LLC

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Monomer Polymer & Dajac Labs

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KOWA American Corporation (part of Kowa Group)

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San Esters Corp.

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Exim-Indis, Inc. (part of Exim Corporation and Indis N.V.)

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Parchem Fine & Specialty Chemicals

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GEO Specialty Chemicals Inc (a division of CPS Performance Materials.)

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Alichem Inc.

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TCI America, Inc. (part of Tokyo Chemical Industry)

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Spectrum Chemicals & Laboratory Products

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Fine Chem Trading LTD

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TCI America

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Riedel-de Haen AG

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Chemstock Inc.

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Alfa Aesar

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3B Scientific Corporation

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View Lastest Price from Benzyl methacrylate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Benzyl methacrylate 2495-37-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-08

Qingdao RENAS Polymer Material Co., Ltd.

Product: Benzyl methacrylate 2495-37-6
Price: US $0.00/kg
Min. Order: 20kg
Purity: 99.5％
Supply Ability: 10 toms
Release date: 2024-04-26

Hebei Yanxi Chemical Co., Ltd.

Product: Benzyl methacrylate 2495-37-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 20tons
Release date: 2023-09-14

2495-37-6, Benzyl methacrylateRelated Search:

Benzoyl peroxide Methacrylic acid 2-Methyl-2-propenoic acid cyclohexyl ester Isobornyl methacrylate Methyl acrylate Benzyl alcohol Methyl propiolate Benzyl chloride 2-BENZYLACRYLIC ACID Poly(methyl methacrylate) Octadecyl methacrylate Tris(trimethylsilyl)phosphate Benzyl benzoate Benzyl acetate 9-Anthracenylmethyl methacrylate POLY(ETHYLENE GLYCOL) METHYL ETHER METHACRYLATE PHENYL METHACRYLATE 9-Anthryl Methacrylate

2-methyl-2-propenoicaciphenylmethylester

2-Propenoic acid, 2-methyl-, phenylmethyl ester

2-Propenoicacid,2-methyl-,phenylmethylester

Benzyl 2-methylacrylate

Benzyl Methacrylate, 98%, stabilized

Benzyl Methacrylate, stabilized

Benzyl methacrylate, stabilized with &ap:50 to 100ppm 4-methoxyphenol

benzyl 2-methylprop-2-enoate

Benzyl Methacrylate 96%, contains 50 ppM MonoMethyl ether hydroquinone as inhibitor

BENZYL METHACRYLATE

METHACRYLIC ACID BENZYL ESTER

Benzylmethacrylat

Phenylmethyl 2-methylprop-2-enoate

Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol

Benzyl Methacrylate (stabilized with MEHQ)

Phenylmethyl-2-methyl-2-propenoate

METHACRYLIC ACID BENZYL ESTER (STABILIZED WITH MEHQ) 98+%

2-Methylacrylic acid benzyl ester

2-Methylpropenoic acid benzyl ester

Methacrylic acid benzyl

Benzyl methacrylate ,98%

BZMA

BenzylMethacrylate(stabilizedwithMEHQ)&gt

BENZYLMETHACRAYLATE

Benzyl methacrylate CAS NO.2495-37-6

2495-37-6

H2CCCH3CO2CH2C6H5

Organic Building Blocks

Esters

Building Blocks

Carbonyl Compounds

C10 to C11

Acrylic Monomers

C10 to C11Monomers

Carbonyl Compounds

Esters

Methacrylate