ChemicalBook > CAS DataBase List > 3-PHENOXYBROMOBENZENE

3-PHENOXYBROMOBENZENE

Product Name: 3-PHENOXYBROMOBENZENE
CAS No.: 6876-00-2
Chemical Name: 3-PHENOXYBROMOBENZENE
Synonyms: 1-Bromo-3-phenoxybenzene;PBDE 2;BDE No2;NSC 57095;PBDE No. 2;3-PHENOXYBROMOBENZENE;m-Phenoxybromobenzene;m-Bromophenoxybenzene;m-Bromodiphenyl ether;m-Phenoxyphenyl bromide
CBNumber: CB7307267
Molecular Formula: C12H9BrO
Formula Weight: 249.1
MOL File: 6876-00-2.mol

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3-PHENOXYBROMOBENZENE Property

Boiling point:: 200-203℃ (50 Torr)
Density: 1.3944 g/cm3 (20℃)
refractive index: 1.6076 (589.3 nm 20℃)
Flash point:: >110℃
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Sparingly)
form: liquid
color: Colourless
EPA Substance Registry System: PBDE 002 (6876-00-2)

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Safety

Hazard Codes: Xi,N
Risk Statements: 37/38-41-43-51/53
Safety Statements: 26-36/37/39-61
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
RTECS: CY9040554
Hazard Note: Irritant
HS Code: 2909303890

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H335May cause respiratory irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 728969
Product name: 3-Bromodiphenyl ether
Purity: 97%
Packaging: 1g
Price: $34.6
Updated: 2025/07/31

TCI Chemical

Product number: B6471
Product name: 1-Bromo-3-phenoxybenzene
Purity: min. 97.0 %
Packaging: 1G
Price: $115
Updated: 2025/07/31

TCI Chemical

Product number: B6471
Product name: 1-Bromo-3-phenoxybenzene
Purity: min. 97.0 %
Packaging: 5G
Price: $345
Updated: 2025/07/31

TRC

Product number: B687225
Product name: 1-Bromo-3-phenoxybenzene
Packaging: 1g
Price: $75
Updated: 2021/12/16

Apolloscientific

Product number: OR13134
Product name: 3-Bromodiphenyl ether
Packaging: 1g
Price: $38
Updated: 2021/12/16

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3-PHENOXYBROMOBENZENE Chemical Properties,Usage,Production

Uses

1-Bromo-3-phenoxybenzene is part of a group of compounds called polybrominated diphenyl ethers. 1-Bromo-3-phenoxybenzene, along with other similar compounds, are widely used in industry as brominated flame retardants. Unfortunately, with their release into the environment, they pose significant hazards to the humans and wildlife that live in surrounding areas. 1-Bromo-3-phenoxybenzene is also known to induce toxic effects on the central nervous system, the liver, and kidneys in rats.

Synthesis

108-36-1

108-95-2

6876-00-2

Example 6 Synthesis of 1-bromo-3-phenoxybenzene (A): a mixture of meso-dibromobenzene (3 g, 12.75 mmol), phenol (1 g, 10.6 mmol), copper(I) oxide (152 mg, 1 mmol), and cesium carbonate (3.46 g, 10.6 mmol) was dissolved in 8 mL of N-methylpyrrolidone (NMP). The reaction mixture was microwaved at 195 °C for 20 min. Upon completion of the reaction, the non-homogeneous mixture was filtered through a bed of diatomaceous earth and the residue was washed with ethyl acetate (EtOAc, 1 × 20 mL). The filtrate was diluted with 1N sodium hydroxide solution (200 mL) and subsequently extracted with ethyl acetate (3 × 100 mL). The organic phases were combined, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give the crude product as a yellow oil. The crude product was purified by column chromatography (100% hexane as eluent) to afford 1-bromo-3-phenoxybenzene as a colorless oil (1.4 g, 53% yield).LCMS m/z 250 (M + 1).

References

[1] Patent: US2005/234042, 2005, A1. Location in patent: Page/Page column 25-26
[2] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 16, p. 5900 - 5905
[3] Patent: EP1489077, 2004, A1. Location in patent: Page 31

3-PHENOXYBROMOBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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6876-00-2, 3-PHENOXYBROMOBENZENERelated Search:

3-PHENOXYBROMOBENZENE 3,3',4,4'-TETRABROMODIPHENYL ETHER Pentabromodiphenyl ether 3',4',4-tribde TETRADECABROMO-1,4-DIPHENOXYBENZENE 2,2',4,4',5,6'-HEXABROMODIPHENYL ETHER OCTABROMODIPHENYL ETHER 2,2',3,3',4,4',5,5',6-nonabromodiphenylether 3-Bromo-4'-fluorodiphenyl ether Decabromodiphenyl oxide 2,2',4,4',5-PENTABROMODIPHENYL ETHER p-phenoxybromobenzen 1,2,3,7,8-PENTABROMODIBENZO-P-DIOXIN 2,2',3,4,4',5,5',6'-OCTABROMODIPHENYL ETHER 4-(3-bromophenoxy)aniline 2,3,7,8-TETRABROMODIBENZO-P-DIOXIN bastadin 5 2-(3-BROMOPHENOXY)-5-(MORPHOLIN-4-YLSULFONYL)ANILINE

1-Bromo-3-phenoxybenzene

3-Bromodiphenyl ether,50 μL/mL in Isooctane

Benzene, 1-bromo-3-phenoxy-

1-Bromo-3-phenoxybenzene, 97+%

3-PHENOXYBROMOBENZENE

3-Phenoxyphenyl bromide

m-Bromodiphenyl ether

m-Bromophenoxybenzene

m-Bromophenyl phenyl ether

m-Phenoxybromobenzene

m-Phenoxyphenyl bromide

NSC 57095

PBDE 2

BDE No2

3-Bromodiphenyl ether in isooctane

PBDE No. 2

6876-00-2