ChemicalBook > CAS DataBase List > Allyl chloroformate

Allyl chloroformate

Product Name
Allyl chloroformate
CAS No.
2937-50-0
Chemical Name
Allyl chloroformate
Synonyms
Alloc-Cl;Allyl carbonochloridate;ACF;2-propenylchloroformate;ALLYL CHLOROCARBONATE;CHLOROFORMIC ACID ALLYL ESTER;A1CF;Ally chloroformate;allyl chlorofomate;ALLYL CHLOROFORMATE
CBNumber
CB7338849
Molecular Formula
C4H5ClO2
Formula Weight
120.53
MOL File
2937-50-0.mol
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Allyl chloroformate Property

Melting point:
106℃
Boiling point:
109 °C
Density 
1.134 g/mL at 20 °C(lit.)
vapor pressure 
3.67 psi ( 20 °C)
refractive index 
n20/D 1.422(lit.)
Flash point:
88 °F
storage temp. 
2-8°C
solubility 
Chloroform
form 
Liquid
color 
Clear slightly yellow to light orange to reddish brown
Odor
Extremely irritating, causes tears; pungent.
BRN 
773915
Stability:
Moisture Sensitive
CAS DataBase Reference
2937-50-0(CAS DataBase Reference)
NIST Chemistry Reference
Allyl chloroformate(2937-50-0)
EPA Substance Registry System
Carbonochloridic acid, 2-propen-1-yl ester (2937-50-0)
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Safety

Hazard Codes 
T+
Risk Statements 
10-22-26-34
Safety Statements 
26-28-36/37/39-45
RIDADR 
UN 1722 6.1/PG 1
WGK Germany 
3
RTECS 
LQ5775000
F 
19
HazardClass 
6.1(b)
PackingGroup 
I
HS Code 
29159000
Hazardous Substances Data
2937-50-0(Hazardous Substances Data)
Toxicity
mouse,LC50,inhalation,23100ug/m3 (23.1mg/m3),LUNGS, THORAX, OR RESPIRATION: DYSPNEA,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(5), Pg. 51, 1984.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
242306
Product name
Allyl chloroformate
Purity
97%
Packaging
5g
Price
$53.9
Updated
2024/03/01
Sigma-Aldrich
Product number
242306
Product name
Allyl chloroformate
Purity
97%
Packaging
100g
Price
$150
Updated
2024/03/01
TRC
Product number
A549640
Product name
Allyl chloroformate
Packaging
1g
Price
$45
Updated
2021/12/16
Oakwood
Product number
099832
Product name
Allyl chloroformate
Packaging
100g
Price
$60
Updated
2021/12/16
Oakwood
Product number
099832
Product name
Allyl chloroformate
Packaging
10g
Price
$20
Updated
2021/12/16
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Allyl chloroformate Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Allyl Chloroformate is used in the synthesis of poly(ethylene oxide) hybrid systems for therapeutic applications and drug delivery. Also used in the synthesis of benzothiazole derivatives with potent anti-tumor properties.

General Description

A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced.

Reactivity Profile

Acid halides, such as Allyl chloroformate, are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach.

Chemical Reactivity

Reactivity with Water Reacts slowly generating hydrogen chloride; Reactivity with Common Materials: Corrosive metals; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water, rinse with sodium bicarbonate solution; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and ESTERS.

Allyl chloroformate Preparation Products And Raw materials

Raw materials

Preparation Products

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Allyl chloroformate Suppliers

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View Lastest Price from Allyl chloroformate manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
Allyl Chloroformate 2937-50-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
R&D Scientific Inc.
Product
Allyl Chloroformate 2937-50-0
Price
US $1900.00/Kg
Min. Order
1Kg
Purity
95
Supply Ability
500 Kg
Release date
2024-04-05
Career Henan Chemical Co
Product
Allyl chloroformate 2937-50-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-15

2937-50-0, Allyl chloroformateRelated Search:

Diallyl phthalate Allyl methacrylate Isopropyl chloroformate Allyl glycidyl ether Diisopropyl azodicarboxylate ALLYL FORMATE Isopropylparaben Allyl phenoxyacetate 2'-Hydroxy-3-phenylpropiophenone Allyl hexanoate Allylbenzene Propyl chloroformate Butyl chloroformate HEXYL CHLOROFORMATE Lauryl chloroformate Cetyl chloroformate Heptyl chloroformate Pentyl chloroformate

  • 2-propenylchloroformate
  • ALLYLCHLOROFORMATE(ACF)
  • Allyl carbonochloridate
  • Prop-1-enylchlorocarbonate
  • (Allyloxycarbonyl) chloride
  • Chloridocarbonic acid allyl
  • Chloridocarbonic acid allyl ester
  • Allyl chloroformate,97%
  • Alloc-Clallyloxycarbonylchloride
  • Alloc-Cl
  • Chlorine forMic acid allyl ester
  • A1CF
  • APOBEC1 complementation factor
  • Carbonochloridicacid, 2-propen-1-yl ester
  • Allyl chloroforMate, 98+%
  • ALOC-CL allyloxycarbonylchloride
  • CHLOROFORMIC ACID ALLYL ESTER
  • allylesterkyselinychlormravenci
  • carbonochloridicacid,2-propenylester
  • chlorocarbonicacidallylester
  • chloro-formicaciallylester
  • ALLYL CHLOROCARBONATE
  • ALLYL CHLOROFORMATE
  • ACF
  • Ally chloroformate
  • ALLYL CHLOROFORMATE, STAB.
  • allyl chlorofomate
  • Allyl Chloroformate &gt
  • Allyl chloroformate ISO 9001：2015 REACH
  • prop-2-enyl carbonochloridate
  • ANTI-ACF(C-TERMINAL) antibody produced in rabbit
  • Allyi Chloro Formate
  • 2937-50-0
  • 2397-50-0
  • C4H5CIO2
  • ClCOOCH2CHCH2
  • CH2CHCH2OCOCl
  • Synthetic Reagents
  • Others
  • Protection and Derivatization
  • Protecting and Derivatizing Reagents
  • Amine ProtectionProtection and Derivatization
  • Others
  • Peptide Synthesis
  • Protecting and Derivatizing Reagents
  • Specialty Synthesis
  • Pharmaceutical Intermediates
  • CHLOROFORMATES