METHYL (2-AMINO-PHENYL)-ACETATE

Product Name: METHYL (2-AMINO-PHENYL)-ACETATE
CAS No.: 35613-44-6
Chemical Name: METHYL (2-AMINO-PHENYL)-ACETATE
Synonyms: METHYL 2-(2-AMINOPHENYL)ACETATE;Methyl 2-(2-aminophenyl);1H-Pyrrole-2,5-dione,5-methyl-;METHYL (2-AMINO-PHENYL)-ACETATE;Benzeneacetic acid, 2-aMino-, Methyl ester
CBNumber: CB7356760
Molecular Formula: C9H11NO2
Formula Weight: 165.19
MOL File: 35613-44-6.mol

More

Less

METHYL (2-AMINO-PHENYL)-ACETATE Property

Boiling point:: 277.5±15.0 °C(Predicted)
Density: 1.143±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
pka: 3.39±0.10(Predicted)
InChI: InChI=1S/C9H11NO2/c1-12-9(11)6-7-4-2-3-5-8(7)10/h2-5H,6,10H2,1H3
InChIKey: BWQBYHGDMBHIIQ-UHFFFAOYSA-N
SMILES: C1(CC(OC)=O)=CC=CC=C1N

More

Less

Safety

HS Code: 2922498590

More

Less

Hazard and Precautionary Statements (GHS)

More

Less

N-Bromosuccinimide Price

TRC

Product number: M328685
Product name: Methyl(2-amino-phenyl)-acetate
Packaging: 25mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 074591
Product name: Methyl 2-(2-aminophenyl)acetate
Purity: 95+%
Packaging: 250mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 074591
Product name: Methyl 2-(2-aminophenyl)acetate
Purity: 95+%
Packaging: 5g
Price: $560
Updated: 2021/12/16

Matrix Scientific

Product number: 074591
Product name: Methyl 2-(2-aminophenyl)acetate
Purity: 95+%
Packaging: 1g
Price: $140
Updated: 2021/12/16

AK Scientific

Product number: W5714
Product name: Methyl2-(2-aminophenyl)acetate
Packaging: 1g
Price: $182
Updated: 2021/12/16

More

Less

METHYL (2-AMINO-PHENYL)-ACETATE Chemical Properties,Usage,Production

Uses

Methyl 2-(2-aminophenyl)acetate is used as an intermediate in organic synthesis.

Synthesis

30095-98-8

35613-44-6

General procedure for the synthesis of methyl (2-aminophenyl)acetate from methyl (2-nitrophenyl)acetate: [00231] A mixture of compounds 1-2 ((2-nitrophenyl)acetic acid methyl ester, 9.75 g, 50 mmol), 10% palladium carbon catalyst (dry, 530 mg, 5 mmol) in methanol (100 mL) was subjected to a hydrogen atmosphere and stirred at room temperature overnight. Upon completion of the reaction, the reaction mixture was filtered to remove the palladium-carbon catalyst, and the filtrate was concentrated to afford compound 6-1 ((2-aminophenyl)acetic acid methyl ester, 8.02 g, yield: 97%) as a light yellow oil. MS (ES): m/z: 166 [M + H]. 1H NMR (400MHz, DMSO-d6) δ: 6.94 (m, 2H), 6.64 (d, 1H, J=8.0Hz), 6.51 (m, 1H), 4.88 (s, 2H), 3.59 (s, 3H), 3.52 (s, 2H).

References

[1] Journal of Medicinal Chemistry, 2003, vol. 46, # 5, p. 691 - 701
[2] European Journal of Organic Chemistry, 2017, vol. 2017, # 14, p. 1889 - 1893
[3] Patent: WO2014/106238, 2014, A1. Location in patent: Paragraph 00231
[4] Patent: WO2014/106238, 2014, A1. Location in patent: Paragraph 00269; 00397
[5] Patent: WO2009/3970, 2009, A1. Location in patent: Page/Page column 42-43

METHYL (2-AMINO-PHENYL)-ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

METHYL (2-AMINO-PHENYL)-ACETATE Suppliers

China 76 Germany 1 India 2 United States 10 Global 89

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 52923
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Chem-Impex International, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6730
Advantage: 64

Beta Pharma, Inc.

Tel: --
Fax: --
Email: sales@betapharma.com
Country: United States
ProdList: 6226
Advantage: 60

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

CGeneTech, Inc.

Tel: --
Fax: --
Email: qyu@cgenetech.com
Country: United States
ProdList: 959
Advantage: 30

More

Less

View Lastest Price from METHYL (2-AMINO-PHENYL)-ACETATE manufacturers

Career Henan Chemical Co

Product: METHYL (2-AMINO-PHENYL)-ACETATE 35613-44-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 1000kg
Release date: 2018-12-25

35613-44-6, METHYL (2-AMINO-PHENYL)-ACETATERelated Search:

Methyl anthranilate METHYL 2,4-DINITROPHENYLACETATE ETHYL 3-HYDROXY-4,6-DIMETHOXY-2-OXOINDOLINE-3-CARBOXYLATE Aceclofenac BIS(2,4-DINITROPHENYL)ACETIC ACID ETHYL ESTER METHYL 2-(4,5-DICHLORO-2-NITROPHENYL)ACETATE (2-AMINO-PHENYL)-ACETIC ACID ETHYL ESTER 2-NITROPHENYL ACETIC ACID ETHYL ESTER METHYL (2-AMINO-PHENYL)-ACETATE DIMETHYL 2-(2-CHLORO-6-NITROPHENYL)MALONATE ETHYL ALPHA-CYANO-2-NITRO-4-(TRIFLUOROMETHYL)PHENYLACETATE DIMETHYL 2-(4-CHLORO-2-NITROPHENYL)MALONATE AKOS AU36-M255 METHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE METHYL 2-CYANO-2-[2-NITRO-4-(TRIFLUOROMETHYL)PHENYL]ACETATE (2-AMINO-PHENYL)-ACETIC ACID ETHYL ESTER HCL METHYL (2-NITRO-PHENYL)-ACETATE (4,5-DIMETHOXY-2-NITRO-PHENYL)-ACETIC ACID ETHYL ESTER

METHYL (2-AMINO-PHENYL)-ACETATE

METHYL 2-(2-AMINOPHENYL)ACETATE

Benzeneacetic acid, 2-aMino-, Methyl ester

Methyl 2-(2-aminophenyl)

1H-Pyrrole-2,5-dione,5-methyl-

35613-44-6