(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE
- Product Name
- (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE
- CAS No.
- 1439-36-7
- Chemical Name
- (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE
- Synonyms
- 1-(TRIPHENYLPHOSPHORANYLIDENE)-2-PROPANONE;(2-Oxopropylidene)triphenylphosphorane;NSC 407394;1-(TriphenyL;phosphoranyL;AURORA KA-1177;idene)-2-propanone;Triphenyl(acetylMethylene)phospho;(Acetonylidene)triphenylphosphorane;(Triphenylphosphoranylidene)acetone
- CBNumber
- CB7371857
- Molecular Formula
- C21H19OP
- Formula Weight
- 318.35
- MOL File
- 1439-36-7.mol
(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE Property
- Melting point:
- 203-205 °C (lit.)
- Boiling point:
- 478.5±28.0 °C(Predicted)
- Density
- 1.14
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in chloroform. Slightly soluble in methanol.
- form
- Powder
- color
- White to off-white
- Sensitive
- Air Sensitive
- BRN
- 750077
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- CAS DataBase Reference
- 1439-36-7(CAS DataBase Reference)
Safety
- Risk Statements
- 22-36/37/38
- Safety Statements
- 22-24/25
- WGK Germany
- 3
- RTECS
- UC3900000
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 158755
- Product name
- 1-(Triphenylphosphoranylidene)-2-propanone
- Purity
- 99%
- Packaging
- 25g
- Price
- $197
- Updated
- 2024/03/01
- Product number
- 158755
- Product name
- 1-(Triphenylphosphoranylidene)-2-propanone
- Purity
- 99%
- Packaging
- 100g
- Price
- $444.6
- Updated
- 2024/03/01
- Product number
- A1439
- Product name
- (Acetylmethylene)triphenylphosphorane
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $89
- Updated
- 2024/03/01
- Product number
- A11410
- Product name
- (Acetylmethylene)triphenylphosphorane, 99%
- Packaging
- 10g
- Price
- $45.65
- Updated
- 2024/03/01
- Product number
- A11410
- Product name
- (Acetylmethylene)triphenylphosphorane, 99%
- Packaging
- 50g
- Price
- $153.65
- Updated
- 2024/03/01
(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE Chemical Properties,Usage,Production
Chemical Properties
white to light beige crystalline powder
Uses
(Acetylmethylene)triphenylphosphorane is used as a Wittig reagent in synthetic chemistry, especially for the synthesis of functionalized pyrrolidines and cyclobutanones. It plays as a vital role in asymmetric allylboration for enantioselective synthesis of (+)-awajanomycin.It is also employed as a reactant in the preparation of 1,2-dioxanes with antitrypanosomal activity. Further, it is used in the preparation of amphibian pyrrolizidine alkaloids through allylic aminations and silicon-containing acyclic dienone musk odorants. In addition to this, it is involved in Domino Suzuki/Heck coupling reactions to prepare fluorenylidenes.
(ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE manufacturers
- Product
- (AcetylMethylene)triphenylphosphorane 1439-36-7
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2020-01-15
- Product
- (ACETYLMETHYLENE)TRIPHENYLPHOSPHORANE 1439-36-7
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-09