Bromonitromethane

ChemicalBook > CAS DataBase List > Bromonitromethane

Bromonitromethane

Product Name: Bromonitromethane
CAS No.: 563-70-2
Chemical Name: Bromonitromethane
Synonyms: 255858_ALDRICH;EINECS 209-258-0;bromonitro-methan;nitrobromomethane;BROMONITROMETHANE;Nitromethyl bromide;Methane, bromonitro-;Bromonitromethane, tech.;bromonitromethane CH2BrNO2;Bromonitromethane, 90%,tech.
CBNumber: CB7381067
Molecular Formula: CH2BrNO2
Formula Weight: 139.94
MOL File: 563-70-2.mol

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Bromonitromethane Property

Melting point:: -28 °C
Boiling point:: 146-148 °C/750 mmHg (lit.)
Density: 2.007 g/mL at 25 °C (lit.)
refractive index: 1.485-1.495
Flash point:: 4°C
solubility: Chloroform (Soluble), DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Slig
pka: 7.22±0.29(Predicted)
form: Liquid
color: Clear yellow
Stability:: Light Sensitive, Volatile
CAS DataBase Reference: 563-70-2(CAS DataBase Reference)
EPA Substance Registry System: Methane, bromonitro- (563-70-2)

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Safety

Hazard Codes: Xn-O,Xi,O
Risk Statements: 8-36/37/38-20/21/22
Safety Statements: 36/37/39-26-17-36
RIDADR: 3098
WGK Germany: 3
RTECS: PA5360000
HazardClass: 5.1
PackingGroup: III
HS Code: 29049095

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 255858
Product name: Bromonitromethane
Purity: technical grade, 90%
Packaging: 1g
Price: $71.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 255858
Product name: Bromonitromethane
Purity: technical grade, 90%
Packaging: 10g
Price: $154
Updated: 2024/03/01

TRC

Product number: B686205
Product name: Bromonitromethane
Packaging: 10g
Price: $95
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB75111
Product name: Bromonitromethane
Packaging: 5G
Price: $150
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB75111
Product name: Bromonitromethane
Packaging: 25g
Price: $400
Updated: 2021/12/16

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Bromonitromethane Chemical Properties,Usage,Production

Chemical Properties

Bromonitromethane is a clear yellow liquid, It is a strong oxidizing agent with properties similar to nitromethane.
Bromonitromethane has been used:
in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesis.
in preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reaction.
in diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramolecular-alkylation strategy.

Uses

Bromonitromethane has received considerable attention as a one-carbon synthon for the synthesis of a variety of important organic intermediates.
Bromonitromethane is a key starting material for the preparation of the broad-spectrum antibiotic trovafloxacin, which contains the interesting 3-azabicyclo[ 3.1.0]hexane ring system.
it was used in the synthesis of 2-nitrobenzofuran and 2-nitro-2,3-dihydrobenzofuran-3-ols, nitrobenzothio-phenes, and nitrothiazoles, polyfunctionalized nitrocyclopropanes. It has also been utilized in the synthesis of 1-bromo-1-nitroalkan-2-ols and aryl nitromethanes. In addition, it could be used as a bromine donor.

Uses

Bromonitromethane has been used:

in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesis
in preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reaction
in diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramolecular-alkylation strategy

Preparation

Bromonitromethane is commercially available and can also be easily prepared according to the procedures reported by Fishwick et al. A typical procedure is as following: freshly distilled nitromethane was stirred at 0℃ and bromine was dropped in 5 seconds. The resulted bromonitromethane could be used without further purification.

Bromonitromethane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Bromonitromethane manufacturers

Career Henan Chemical Co

Product: BROMONITROMETHANE 563-70-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-07-03

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BROMONITROMETHANE

Bromonitromethane, tech.

bromonitro-methan

Methane, bromonitro-

nitrobromomethane

bromonitromethane CH2BrNO2

Bromonitromethane, 90%,tech.

Nitromethyl bromide

BroMonitroMethane, tech., 90% 10GR

BroMonitroMethane technical grade, 90%

255858_ALDRICH

EINECS 209-258-0

563-70-2

CH2BrNO2

BrCH2NO2

Nitro Compounds

Organic Building Blocks

Nitrogen Compounds

Building Blocks

PHARMACEUTICAL INTERMEDIATES

Nitro Compounds

Nitrogen Compounds

Organic Building Blocks