PHENYL AZIDE

Product Name: PHENYL AZIDE
CAS No.: 622-37-7
Chemical Name: PHENYL AZIDE
Synonyms: Azidobenzene;PHENYL AZIDE;Azido-benzene;triazobenzene;phenylazoimide;Benzene, triazo-;diazobenzeneimide;Phenyl azide solution;Azidobenzene solution;Azidomethane solution - 0.5M solution intert-butyl methyl ether
CBNumber: CB7390841
Molecular Formula: C6H5N3
Formula Weight: 119.12
MOL File: 622-37-7.mol

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PHENYL AZIDE Property

Melting point:: -27.5°C
Boiling point:: 212.39°C (rough estimate)
Density: 1.0860
vapor density: 73.5 at 22-24 mm
refractive index: 1.5589
Flash point:: -12°C
storage temp.: -20°C
color: Pale-yellow oil
BRN: 742248

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Safety

Hazard Codes: F,Xn
Risk Statements: 11-19-48/20/21/22-38
Safety Statements: 16
RIDADR: UN 2398 3 / PGII
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 727490
Product name: Azidobenzene solution
Purity: ~0.5 M in tert-butyl methyl ether, ≥95.0%
Packaging: 10ml
Price: $189
Updated: 2024/03/01

Sigma-Aldrich

Product number: 727490
Product name: Azidobenzene solution
Purity: ~0.5 M in tert-butyl methyl ether, ≥95.0%
Packaging: 50ml
Price: $347.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 778583
Product name: Azidobenzene solution
Purity: ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
Packaging: 10ml
Price: $159
Updated: 2024/03/01

Sigma-Aldrich

Product number: 778583
Product name: Azidobenzene solution
Purity: ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
Packaging: 50ml
Price: $429
Updated: 2024/03/01

TRC

Product number: B407570
Product name: Azidobenzene
Packaging: 100mg
Price: $45
Updated: 2021/12/16

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PHENYL AZIDE Chemical Properties,Usage,Production

Uses

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8

General Description

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

PHENYL AZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENYL AZIDE Suppliers

China 19 India 2 United Kingdom 2 United States 5 Global 28

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Zhengzhou Ruke Biological Co., Ltd.

Tel: 15981811963
Fax: QQ：1410472904
Email: 1410472904@qq.com
Country: China
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Henan Alfachem Co.,Ltd.

Tel: 0371-0371-55051623 18137891487
Fax: QQ：2853979817
Email: 2853979817@qq.com
Country: China
ProdList: 9961
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

Zhengzhou Edward Biology Co.,Ltd

Tel: 15538176268 1875164801 15538176268
Fax: QQ：1875164801
Email: jacschem@163.com
Country: China
ProdList: 10108
Advantage: 58

Wuhan Shanhai Zhihe Biotechnology Co., Ltd.

Tel: 17771424646
Email: shoubull@126.com
Country: China
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Shaanxi DIDU pharmaceutical and Chemical Co., Ltd

Tel: 15229059051
Email: 1027@dideu.com
Country: China
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Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd

Tel: 0431-80514535 19917294565
Email: et@chemextension.com
Country: China
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Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-50706066 15221275939
Email: shenlinxing@macklin.cn
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622-37-7, PHENYL AZIDERelated Search:

4-AZIDOBENZOIC ACID 2,6-BIS(4-AZIDOBENZYLIDENE)CYCLOHEXANONE 2,6-BIS(4-AZIDOBENZYLIDENE)-4-METHYLCYCLOHEXANONE PHENYL AZIDE 4-AZIDOPHENACYL BROMIDE 4-FLUORO-3-NITROPHENYL AZIDE 3,3'-DIAZIDODIPHENYL SULFONE 4-AZIDOPHENYL ISOTHIOCYANATE P-AZIDOPHENYL SULFONE 2-NITRO-5-AZIDOBENZOIC ACID 4-azidosalicylic acid N-hydroxysuccinimide ester N-HYDROXYSUCCINIMIDYL-4-AZIDOBENZOATE DTBPA SANPAH ANB-NOS 4-AZIDOANILINE HYDROCHLORIDE N-((4-azidophenyl)thio)phthalimide azapride

Azidomethane solution - 0.5M solution intert-butyl methyl ether

Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC)

Azidobenzene

Azido-benzene

Benzene, triazo-

Azidobenzene solution

Phenyl azide solution

diazobenzeneimide

phenylazoimide

triazobenzene

PHENYL AZIDE

Azidobenzene solution ~0.5 M in tert-butyl Methyl ether, >=95.0%

622-37-7

N3C6H5

Aromatic Azides

Azides

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks