PHENYL AZIDE

Product Name: PHENYL AZIDE
CAS No.: 622-37-7
Chemical Name: PHENYL AZIDE
Synonyms: Azidobenzene;PHENYL AZIDE;Azido-benzene;triazobenzene;phenylazoimide;Benzene, triazo-;diazobenzeneimide;Phenyl azide solution;Azidobenzene solution;Azidomethane solution - 0.5M solution intert-butyl methyl ether
CBNumber: CB7390841
Molecular Formula: C6H5N3
Formula Weight: 119.12
MOL File: 622-37-7.mol

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PHENYL AZIDE Property

Melting point:: -27.5°C
Boiling point:: 212.39°C (rough estimate)
Density: 1.0860
vapor density: 73.5 at 22-24 mm
refractive index: 1.5589
Flash point:: -12°C
storage temp.: -20°C
color: Pale-yellow oil
BRN: 742248

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Safety

Hazard Codes: F,Xn
Risk Statements: 11-19-48/20/21/22-38
Safety Statements: 16
RIDADR: UN 2398 3 / PGII
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 727490
Product name: Azidobenzene solution
Purity: ~0.5 M in tert-butyl methyl ether, ≥95.0%
Packaging: 10ml
Price: $189
Updated: 2024/03/01

Sigma-Aldrich

Product number: 727490
Product name: Azidobenzene solution
Purity: ~0.5 M in tert-butyl methyl ether, ≥95.0%
Packaging: 50ml
Price: $347.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 778583
Product name: Azidobenzene solution
Purity: ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
Packaging: 10ml
Price: $159
Updated: 2024/03/01

Sigma-Aldrich

Product number: 778583
Product name: Azidobenzene solution
Purity: ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
Packaging: 50ml
Price: $429
Updated: 2024/03/01

TRC

Product number: B407570
Product name: Azidobenzene
Packaging: 100mg
Price: $45
Updated: 2021/12/16

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PHENYL AZIDE Chemical Properties,Usage,Production

Uses

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8

General Description

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

PHENYL AZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENYL AZIDE Suppliers

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622-37-7, PHENYL AZIDERelated Search:

4-AZIDOBENZOIC ACID 2,6-BIS(4-AZIDOBENZYLIDENE)CYCLOHEXANONE 2,6-BIS(4-AZIDOBENZYLIDENE)-4-METHYLCYCLOHEXANONE PHENYL AZIDE 4-AZIDOPHENACYL BROMIDE 4-FLUORO-3-NITROPHENYL AZIDE 3,3'-DIAZIDODIPHENYL SULFONE 4-AZIDOPHENYL ISOTHIOCYANATE P-AZIDOPHENYL SULFONE 2-NITRO-5-AZIDOBENZOIC ACID 4-azidosalicylic acid N-hydroxysuccinimide ester N-HYDROXYSUCCINIMIDYL-4-AZIDOBENZOATE DTBPA SANPAH ANB-NOS 4-AZIDOANILINE HYDROCHLORIDE N-((4-azidophenyl)thio)phthalimide azapride

Azidomethane solution - 0.5M solution intert-butyl methyl ether

Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC)

Azidobenzene

Azido-benzene

Benzene, triazo-

Azidobenzene solution

Phenyl azide solution

diazobenzeneimide

phenylazoimide

triazobenzene

PHENYL AZIDE

Azidobenzene solution ~0.5 M in tert-butyl Methyl ether, >=95.0%

622-37-7

N3C6H5

Aromatic Azides

Azides

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks