PHENYL AZIDE
- Product Name
- PHENYL AZIDE
- CAS No.
- 622-37-7
- Chemical Name
- PHENYL AZIDE
- Synonyms
- Azidobenzene;PHENYL AZIDE;Azido-benzene;triazobenzene;phenylazoimide;Benzene, triazo-;diazobenzeneimide;Phenyl azide solution;Azidobenzene solution;Azidomethane solution - 0.5M solution intert-butyl methyl ether
- CBNumber
- CB7390841
- Molecular Formula
- C6H5N3
- Formula Weight
- 119.12
- MOL File
- 622-37-7.mol
PHENYL AZIDE Property
- Melting point:
- -27.5°C
- Boiling point:
- 212.39°C (rough estimate)
- Density
- 1.0860
- vapor density
- 73.5 at 22-24 mm
- refractive index
- 1.5589
- Flash point:
- -12°C
- storage temp.
- -20°C
- color
- Pale-yellow oil
- BRN
- 742248
Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-19-48/20/21/22-38
- Safety Statements
- 16
- RIDADR
- UN 2398 3 / PGII
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 727490
- Product name
- Azidobenzene solution
- Purity
- ~0.5 M in tert-butyl methyl ether, ≥95.0%
- Packaging
- 10ml
- Price
- $189
- Updated
- 2024/03/01
- Product number
- 727490
- Product name
- Azidobenzene solution
- Purity
- ~0.5 M in tert-butyl methyl ether, ≥95.0%
- Packaging
- 50ml
- Price
- $347.2
- Updated
- 2024/03/01
- Product number
- 778583
- Product name
- Azidobenzene solution
- Purity
- ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
- Packaging
- 10ml
- Price
- $159
- Updated
- 2024/03/01
- Product number
- 778583
- Product name
- Azidobenzene solution
- Purity
- ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
- Packaging
- 50ml
- Price
- $429
- Updated
- 2024/03/01
- Product number
- B407570
- Product name
- Azidobenzene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
PHENYL AZIDE Chemical Properties,Usage,Production
Uses
Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Synthesis Reference(s)
Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8
General Description
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Safety Profile
Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.