Benzyl cinnamate

ChemicalBook > CAS DataBase List > Benzyl cinnamate

Product Name: Benzyl cinnamate
CAS No.: 103-41-3
Chemical Name: Benzyl cinnamate
Synonyms: CINNAMEIN;FEMA 2142;guisuanbianzhi;Benzyl ciamate;BENZYL CINNAMATE;Benzylcinnamoate;BENZYL CINNAMATE(P);Benzyl cinnamate-RM;Benzyl cinnamate,99%;BENZYL CINNAMATE(SG)
CBNumber: CB7413201
Molecular Formula: C16H14O2
Formula Weight: 238.28
MOL File: 103-41-3.mol

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Benzyl cinnamate Property

Melting point:: 34-37 °C (lit.)
Boiling point:: 195-200 °C/5 mmHg (lit.)
Density: 1.11
vapor pressure: <0.1 hPa (20 °C)
FEMA: 2142 | BENZYL CINNAMATE
refractive index: 1.4025-1.4045
Flash point:: >230 °F
storage temp.: Store below +30°C.
solubility: alcohol: soluble(lit.)
form: Crystalline Mass or Liquid After Melting
color: Clear colorless to yellow
Odor: aromatic odor
Odor Type: balsamic
Water Solubility: PRACTICALLY INSOLUBLE
Merck: 14,1130
JECFA Number: 670
BRN: 2051339
LogP: 4.18 at 23.7℃
CAS DataBase Reference: 103-41-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzyl cinnamate(103-41-3)
EPA Substance Registry System: Benzyl cinnamate (103-41-3)

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Safety

Risk Statements: 36/37/38
Safety Statements: 22-24/25
RIDADR: 3077
WGK Germany: 2
RTECS: GD8400000
TSCA: Yes
HS Code: 29163900
Hazardous Substances Data: 103-41-3(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 5530 mg/kg (Jenner)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W214205
Product name: Benzyl cinnamate
Purity: ≥98%
Packaging: sample-k
Price: $59.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214205
Product name: Benzyl cinnamate
Purity: ≥98%, stabilized
Packaging: 1kg
Price: $183
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214205
Product name: Benzyl cinnamate
Purity: ≥98%, stabilized
Packaging: 5kg
Price: $761
Updated: 2024/03/01

Sigma-Aldrich

Product number: 234214
Product name: Benzyl cinnamate
Purity: 99%
Packaging: 100g
Price: $61.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214205
Product name: Benzyl cinnamate
Purity: ≥98%, stabilized
Packaging: 10Kg
Price: $995
Updated: 2023/06/20

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Benzyl cinnamate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellowish crystalline mass or liquid after meltin

Chemical Properties

Benzyl Cinnamate occurs in balsams and balsam oils. It forms white, sweet-balsamic-smelling crystals (mp 35-36°C). Benzyl cinnamate is used as a fixative in perfumes and as a component of heavy, oriental perfumes.

Chemical Properties

Benzyl cinnamate has a sweet, balsamic odor and a honey-like taste.

Occurrence

Reported found in Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituent of copaiba balsam.

Uses

Benzyl cinnamate has been employed as internal standard during the determination of compounds commonly added to personal care products such as UV filters and antimicrobial agents in environmental samples.

Uses

Mild. sweet-balsamic and somewhat floral odor of great tenacity. Used quite frequently in perfumery, mainly as a fixative, and particularly in perfumes for Talcum (powders). It blends well with floral bases, spicy fragrances and Ambre types.
Used in flavor compositions for imitation Apricot, Cherry, Chocolate, Honey, Peach, Pineapple, Liquor, Raspberry, Rum, Prune, etc.
Concentration may be little more than traces, usually about 6 ppm, except in chewing gum: up to 125 ppm.

Definition

ChEBI: Benzyl cinnamate is the cinnamate ester derived from cinnamic acid and benzyl alcohol. Occuring in Balsam of Peru and Tolu balsam, in Sumatra and Penang benzoin, and as the main constituent of copaiba balsam, it is used in heavy oriental perfumes, as a fixative and as a flavouring agent. It has a role as a flavouring agent, a fragrance, a fixative, an antigen and an epitope.

Preparation

By heating benzyl chloride and excess sodium cinnamate in water to 100 to 115°C; by heating sodium cinnamate with an excess of benzyl chloride in the presence of diethylamine.

Production Methods

Benzyl cinnamate is produced by the direct esterification of benzyl alcohol with cinnamic acid.

Taste threshold values

Taste characteristics at 50 ppm: spicy, floral, fruity, balsamic.

General Description

Benzyl cinnamate is widely used as a fragrance ingredient.

Hazard

Moderately toxic.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. Amild allergen and skin irritant. Combustible liquid. When heated to decomposition it emits acridsmoke and irritating fumes.

target

Immunology & Inflammation related

Metabolism

See monograph on Benzyl alcohol (p. 1011).

Purification Methods

Recrystallise the ester to a constant melting point from 95% EtOH. It has the odour of balsam. Alternatively dissolve it in Et2O, wash it with 10% aqueous Na2CO3, H2O, dry (Na2SO4), evaporate and fractionate it under reduced pressure using a short Vigreux column (p 11). It decomposes when boiled at atmospheric pressure. [Eliel & Anderson J Am Chem Soc 74 547 1952, Bender & Zerner J Am Chem Soc 84 2550 1962, Beilstein 9 IV 2012.]

Benzyl cinnamate Preparation Products And Raw materials

Raw materials

Benzyl chloride Benzyl alcohol Diethylamine trans-Cinnamic acid Sodium cinnamate

Preparation Products

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Benzyl cinnamate Suppliers

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View Lastest Price from Benzyl cinnamate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Benzyl cinnamate 103-41-3
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000KG/Week
Release date: 2024-04-24

Hebei Weibang Biotechnology Co., Ltd

Product: Benzyl cinnamate 103-41-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Hebei Chuanghai Biotechnology Co,.LTD

Product: Benzyl cinnamate 103-41-3
Price: US $19.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 ton
Release date: 2024-08-23

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103-41-3

C6H5CHCHCOOCH2C6H5