ChemicalBook > CAS DataBase List > Thifensulfuron methyl

Thifensulfuron methyl

Product Name
Thifensulfuron methyl
CAS No.
79277-27-3
Chemical Name
Thifensulfuron methyl
Synonyms
THIFENSULFURON-METHYL;PINNACLE;HARMONY;dpx-m6316;ThifensuL;thiameturon;Harmony(TM);furon MethyL;PINNACLE (TM);Harmony(Du Pont)
CBNumber
CB7439269
Molecular Formula
C12H13N5O6S2
Formula Weight
387.39
MOL File
79277-27-3.mol
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Thifensulfuron methyl Property

Melting point:
176°C
Density 
1.560±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Water Solubility 
Practically insoluble in water
solubility 
DMSO (Slightly, Heated), Methanol (Slightly, Heated)
pka
pKa at 25°: 4.0
form 
Solid
color 
White to Almost white
λmax
280nm(Acidic aq.)(lit.)
Merck 
14,9316
BRN 
7448062
LogP
1.560
CAS DataBase Reference
79277-27-3(CAS DataBase Reference)
EPA Substance Registry System
Thifensulfuron-methyl (79277-27-3)
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Safety

Hazard Codes 
N
Risk Statements 
50/53
Safety Statements 
60-61
RIDADR 
UN3077 9/PG 3
WGK Germany 
2
RTECS 
XM8463000
HazardClass 
9
PackingGroup 
III
HS Code 
29350090
Hazardous Substances Data
79277-27-3(Hazardous Substances Data)
Toxicity
LC50 (96-hour) for both bluegill sun?sh and rainbow trout >100 mg/L; LC50 (48-hour) for Daphnia magna >1,000 mg/L (Humburg et al., 1989); acute oral LD50 for rats >5,000 mg/kg (Hartley and Kidd, 1987).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
46028
Product name
Thifensulfuron-methyl
Purity
PESTANAL
Packaging
100mg
Price
$113
Updated
2024/03/01
TCI Chemical
Product number
T3166
Product name
Thifensulfuron-methyl
Packaging
1G
Price
$131
Updated
2024/03/01
TCI Chemical
Product number
T3166
Product name
Thifensulfuron-methyl
Packaging
5G
Price
$428
Updated
2024/03/01
Usbiological
Product number
290949
Product name
Thifensulfuron-methyl
Packaging
50mg
Price
$468
Updated
2021/12/16
TRC
Product number
T344700
Product name
Thifensulfuron-methyl
Packaging
5g
Price
$340
Updated
2021/12/16
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Thifensulfuron methyl Chemical Properties,Usage,Production

Uses

Postemergence herbicide used to control wild garlic and many broad-leaved weeds in barley and spring wheat.

Uses

Herbicide.

Definition

ChEBI: A methyl ester resulting from the formal condensation of the carboxy group of thifensulfuron with methanol. It is used as a post-emergence herbicide for the control of grass and broad-leaved weeds.

Agricultural Uses

Herbicide: A herbicide for postemergence broadleaf weed control in crops for food such as soybeans and cotton. Not listed for use in EU countries.

Trade name

ALLY®; BASIS® (rimsulfuron + thifensulfuron methyl); CANVAS® (thifensulfuron methyl + tribenuron methyl + metsulfuron-methyl); DPX-M6316®; EXPRESS®; HARMONY® Extra (thifensulfuron methyl + tribenuron methyl); INM-6316®; PINNACLE®; PROSPECT®; RELIANCE® SYNCHRONY®, (chlorimuron- ethyl + thifensulfuron methyl)

Environmental Fate

Chemical/Physical. May hydrolyze in aqueous solutions forming methyl alcohol and 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)-2- thiophenecarboxylic acid.

Metabolic pathway

The hydrolytic degradation of thifensulfuron methyl is pH dependent and, in alkaline condition, specifically yields the corresponding free acid. Primary degradation cleaves the sulfonylurea moiety to give two typical hydrolyzed products, sulfonamide and aminotriazine analogs, derived from thifensulfuron methyl in acidic and neutral conditions. Hydrolysis of the ester linkage proceeds in mammals, plants, soils, and also chemical hydrolysis, and opening of the triazine ring occurs to yield the acetyltriuret analog identified. On the other hand, by hydrolysis, O- demethylated thifensulfuron methyl undergoes opening of the triazine ring to give the corresponding acetyltriuret analog. Under photolytic conditions, methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2- yl)aminothiophene-2-carboxylate is identified.

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View Lastest Price from Thifensulfuron methyl manufacturers

qingdao trust agri chemical co.,ltd
Product
Thifensulfuron methyl 79277-27-3
Price
US $0.00/kg
Min. Order
100kg
Purity
75%
Supply Ability
20tons
Release date
2024-07-03
Hebei Weibang Biotechnology Co., Ltd
Product
Thifensulfuron methyl 79277-27-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-25
Hebei Mojin Biotechnology Co., Ltd
Product
Thifensulfuron methyl 79277-27-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000kg/week
Release date
2021-07-01

79277-27-3, Thifensulfuron methylRelated Search:


  • PINNACLE
  • PINNACLE (TM)
  • THIFENSULFURON-METHYL
  • 2-thiophenecarboxylicacid,3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)
  • dpx-m6316
  • methyl3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)-2-thenoate
  • thiameturon-methyl
  • HARMONY
  • METHYL 3-[[[[(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL)AMINO]CARBONYL]AMINO]-SULFONYL]-2-THIOPHENECARBOXYLATE
  • METHYL 3-(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL-CARBAMOYLSULFAMOYL)-THIOPHEN-2-CARBOXYLATE
  • Thifensulfuron-methyl Solution, 1000ppm
  • DPX-M6316(Du Pont)
  • Harmony(Du Pont)
  • thiameturon
  • Methyl 3-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-2-thiophenecarboxylate
  • THIFENSULFURON-METHYL PESTANAL 100 MG
  • Methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)thiophene-2-carboxylate
  • 2-Thiophenecarboxylic acid, 3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonylaminosulfonyl-, methyl ester
  • thifensulfuron-methyl (bsi,iso)
  • THIFENSULPHURON-METHYL
  • 3-(4-Methoxy-6-methyl-1,3,5-triazine-2-ylcarbamoylsulfamoyl)-2-thiophenecarboxylic acid methyl ester
  • 3-[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]aminosulfonyl]thiophene-2-carboxylic acid methyl ester
  • Pinnacle (TM) 100mg [79277-27-3]
  • Thifensulfuron-Methy
  • Methyl 3-(N-((4-Methoxy-6-Methyl-1,3,5-triazin-2-yl)carbaMoyl)sulfaMoyl)thiophene-2-carboxylate
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  • 79277-27-3
  • C12H13N5O6S2
  • H
  • HA -HTPesticides&Metabolites
  • H-MAlphabetic
  • Alpha sort
  • Herbicides
  • Pesticides&Metabolites
  • Q-ZAlphabetic
  • TF - TOPesticides&Metabolites
  • Urea structure