TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- Product Name
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- CAS No.
- 370-69-4
- Chemical Name
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- Synonyms
- TTFP;Phosphite, tris(2,2,2-trifluoroethyl);Tris(2,2,2-trifluoroethyl) phosphite 99%;TTEP;TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE;Ethanol, 2,2,2-trifluoro-, phosphite (3:1);TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %
- CBNumber
- CB7449383
- Molecular Formula
- C6H6F9O3P
- Formula Weight
- 328.07
- MOL File
- 370-69-4.mol
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Property
- Boiling point:
- 130-131 °C743 mm Hg(lit.)
- Density
- 1.487 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.324(lit.)
- Flash point:
- >230 °F
- BRN
- 1714041
- InChI
- InChI=1S/C6H6F9O3P/c7-4(8,9)1-16-19(17-2-5(10,11)12)18-3-6(13,14)15/h1-3H2
- InChIKey
- CBIQXUBDNNXYJM-UHFFFAOYSA-N
- SMILES
- P(OCC(F)(F)F)(OCC(F)(F)F)OCC(F)(F)F
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 270954
- Product name
- Tris(2,2,2-trifluoroethyl) phosphite
- Purity
- 99%
- Packaging
- 25g
- Price
- $172
- Updated
- 2024/03/01
- Product number
- 270954
- Product name
- Tris(2,2,2-trifluoroethyl) phosphite
- Purity
- 99%
- Packaging
- 100g
- Price
- $311.4
- Updated
- 2024/03/01
- Product number
- T876718
- Product name
- Tris(2,2,2-trifluoroethyl) phosphite
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- HCH0067306
- Product name
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- Purity
- 95.00%
- Packaging
- 25G
- Price
- $1200.62
- Updated
- 2021/12/16
- Product number
- HCH0067306
- Product name
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- Purity
- 95.00%
- Packaging
- 100G
- Price
- $2783.87
- Updated
- 2021/12/16
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Chemical Properties,Usage,Production
Uses
Tris(2,2,2-trifluoroethyl) phosphite was used in the synthesis of N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide via the Arbuzov reaction with 2-bromo-N-methoxy-N-methylacetamide.
Purification Methods
Fractionate it through a 10inch Helipak column [Krogh et al. J Org Chem 19 1124 1954]. Tris-[(3-trifluoromethylhydroxymethylene)-d-camphorato] europium (III) [Eu(tfc)3] [34830-11-0] M 893.6, m 195-299o (dec), ~220o, [ ] D +152o (c 2, CCl4, and varies markedly with concentration). Purify it by extraction with pentane, filter and the filtrate is evaporated and the residual bright yellow amorphous powder is dried at 100o/0.1mm for 36hours. A sample purified by fractional molecular distillation at 180-200o/0.004mm gave a liquid which solidified and softened at ~130o, and melted at ~180o and was analytically pure. IR (CCl4) 1630-1680cm-1 and NMR (CCl4) broad: -1.3 to 0.5, -0.08 (s), 0.41 max (s), 1.6-2.3 and 3.39 (s). [McCreary et al. J Am Chem Soc 96 1038 1974, Goering et al. J Am Chem Soc 93 5913 1971.]
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Suppliers
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- +1-+1(833)-552-7181
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- United States
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View Lastest Price from TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE manufacturers
- Product
- Tris(2,2,2-trifluoroethyl) phosphite 370-69-4
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50 tons
- Release date
- 2020-01-17
- Product
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE 370-69-4
- Price
- US $7.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2018-12-17