ChemicalBook > CAS DataBase List > 1,1-Di(tert-butylperoxy)cyclohexane

1,1-Di(tert-butylperoxy)cyclohexane

Product Name
1,1-Di(tert-butylperoxy)cyclohexane
CAS No.
3006-86-8
Chemical Name
1,1-Di(tert-butylperoxy)cyclohexane
Synonyms
1,1-bis(T-butylperoxy)cyclohexane;DP275B;Perhexa-C;Chaloxyd P;Trigonox 22;Lupersol 331;Trigonox 22C50;TRIGONOX(R) 22;Luperox 331M80;Luperox? 331P80
CBNumber
CB7451603
Molecular Formula
C14H28O4
Formula Weight
260.37
MOL File
3006-86-8.mol
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1,1-Di(tert-butylperoxy)cyclohexane Property

Melting point:
65 °C (SADT)
Boiling point:
52-54 °C (0.1 mmHg)
Density 
0.891 g/mL at 25 °C
vapor pressure 
4.88hPa at 25℃
refractive index 
n20/D 1.435
Flash point:
155 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear
Water Solubility 
miscible
InChI
InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
InChIKey
HSLFISVKRDQEBY-UHFFFAOYSA-N
SMILES
C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
LogP
7.2 at 25℃
CAS DataBase Reference
3006-86-8(CAS DataBase Reference)
EPA Substance Registry System
Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)
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Safety

Hazard Codes 
O,N,T
Risk Statements 
7-62-50/53-36/37/38-61-65-45-51/53
Safety Statements 
17-36/37/39-3/7-14A-61-60-45-26-14-53-62
RIDADR 
UN 3103 5.2
WGK Germany 
2
HazardClass 
5.2
PackingGroup 
II
HS Code 
29096000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H242Heating may cause a fire

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P235Keep cool.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531758
Product name
Luperox? 331M80, 1,1-Bis(tert-butylperoxy)cyclohexane solution
Purity
~80 wt. % in odorless mineral spirits
Packaging
500ml
Price
$147
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0005590
Product name
1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE
Purity
95.00%
Packaging
500ML
Price
$4102.1
Updated
2021/12/16
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1,1-Di(tert-butylperoxy)cyclohexane Chemical Properties,Usage,Production

Chemical Properties

clear liquid

Uses

Polymerization initiator.

Definition

1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].

Reactivity Profile

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1-Di(tert-butylperoxy)cyclohexane is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979.

Flammability and Explosibility

Not classified

Toxics Screening Level

The initial threshold screening level (ITSL) for 1,1-Di-(tert-butylperoxy)cyclohexane is set at trace, 0.1 μg/m3 based on an annual averaging time.

References

[1] Jo-Ming Tseng . “The thermal hazard evaluation of 1,1-di (tert-butylperoxy) cyclohexane by DSC using non-isothermal and isothermal-kinetic simulations.” Journal of Loss Prevention in The Process Industries 25 4 (2012): Pages 703-708.

1,1-Di(tert-butylperoxy)cyclohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1-Di(tert-butylperoxy)cyclohexane Suppliers

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View Lastest Price from 1,1-Di(tert-butylperoxy)cyclohexane manufacturers

Sinomore New Material Company Limited
Product
1,1-Di（tert-butylperoxy) cyclohexane 3006-86-8
Price
US $0.00-0.00/kg
Min. Order
500kg
Purity
70%
Supply Ability
200tons
Release date
2024-07-09

3006-86-8, 1,1-Di(tert-butylperoxy)cyclohexaneRelated Search:

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Butyl acetate Benzoyl peroxide Tetrabutylammonium hydroxide Monobutyltin oxide Buprofezin tert-Butanol Butyl acrylate tert-Butyl hydroperoxide Cyclohexane Bis(tributyltin) oxide 2-Butoxyethanol Butylated Hydroxytoluene Di-tert-butyl peroxide DI-TERT-BUTYL ETHER Hydrogen peroxide Dibutyltin oxide Dicumyl peroxide

  • 1,1-Di-(t-Butyl Peroxi)- cyclohexane (50% wt solution in mineral oil)
  • 1,1-di-(tert-butylperoxy)cyclohexane (more than 80%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (more than 52% but not more than 80%,and diluent type A not less than 20%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (more than 42% but not more than 52%,and diluent type A not less than 48%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (not more than 13%, and diluent type A not less than 13%,and diluent type B not less than 74%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (not more than 27%,and diluent type A not less than 25%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (not more than 42%,and diluent type A not less than 13%,and inert solid not less than 45%)
  • 1,1-di-(tert-butylperox)cyclohexane (not more than 42%,and diluent type A not less than 58%)
  • 1,1-di-(tert-butylperoxy)cyclohexane (not more than 72%,and diluent type B not less than 28%)
  • 1,1-BIS(T-BUPEROXY)CYCLOHEXANE, 80 WT. %
  • 1 1-BIS(T-BUTYLPEROXY)CYCLOHEXANE TECH&
  • 50%solutioninmineraloil
  • 1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in mineral oil
  • 1,1-Di-(tert.-butylperoxy)-cyclohexan
  • Cyclohexylidenebis[(1,1-dimethylethyl)peroxide]
  • Luperox(R) 331P80
  • 1,1-Bis(tert-butylperoxy)cyclohexane (Luperox(R) 331M80) solution
  • Chaloxyd P
  • Lupersol 331
  • Trigonox 22C50
  • 1,1-Bis(tert-butyldioxy)cyclohexane
  • Perhexa-C
  • 1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in aromatic free mineral spirit
  • Di-tert-butyl cyclohexylidene diperoxide
  • 1,1-Di(tert-butylperoxy)cyclohexaneTrigonox&reg: 22
  • 1,1-Di(tert-butylper
  • Luperox? 331M80, 1,1-Bis(tert-butylperoxy)cyclohexane solution
  • Dibutyl peroxycyclohexanone paste
  • Initiating agent DP275B
  • Luperox? 331P80
  • Luperox(R) 331M80, 1,1-Bis(tert-butylperoxy)cyclohexane solution ~80 wt. % in odorless mineral spirits
  • Peroxide,cyclohexylidenebis[(1,1-dimethylethyl)
  • TRIGONOX(R) 22
  • Trigonox 22
  • 1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE
  • 1,1-BIS(TERT-BUTYLPEROXY)CYCLOHEXANE
  • cyclohexylidenebis(tert-butyl)peroxide
  • LUPEROX(TM) 331M80
  • Luperox 331M80
  • DP275B
  • 1,1-bis(T-butylperoxy)cyclohexane
  • 1,1-Bis(tert-butylperoxy)cyclohexane solution
  • Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-d imethylethyl)
  • 1,1-Di-(Tert-Butyl Peroxy)
  • Luperox(R) 331M80, 1,1-Bis(tert-butylperoxy)cyclohexane solution
  • 3006-86-8
  • C6H10OOCCH332
  • C14H28O4
  • Industrial/Fine Chemicals