1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE

Product Name: 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE
CAS No.: 132414-50-7
Chemical Name: 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE
Synonyms: 1-Benzylhexahydropyrrolo[3,4-b]pyrrole;1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE;octahydro-1-(phenylmethyl)-Pyrrolo[3,4-b]pyrrole;Pyrrolo[3,4-b]pyrrole, octahydro-1-(phenylmethyl)-;1-benzyl-3,3a,4,5,6,6a-hexahydro-2H-pyrrolo[2,3-c]pyrrole;1-(phenylmethyl)-3,3a,4,5,6,6a-hexahydro-2H-pyrrolo[2,3-c]pyrrole
CBNumber: CB7453687
Molecular Formula: C13H18N2
Formula Weight: 202.3
MOL File: 132414-50-7.mol

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1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE Property

Boiling point:: 304.4±17.0 °C(Predicted)
Density: 1.074±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 10.80±0.20(Predicted)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B285325
Product name: 1-Benzyloctahydropyrrolo[3,4-b]pyrrole
Packaging: 250mg
Price: $145
Updated: 2021/12/16

AK Scientific

Product number: X9831
Product name: 1-Benzyloctahydropyrrolo[3,4-b]pyrrole
Packaging: 1g
Price: $159
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB143062
Product name: 1-Benzyloctahydropyrrolo[3,4-b]pyrrole
Packaging: 2g
Price: $209
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB143062
Product name: 1-Benzyloctahydropyrrolo[3,4-b]pyrrole
Packaging: 500mg
Price: $70
Updated: 2021/12/16

Matrix Scientific

Product number: 072082
Product name: 1-Benzyloctahydropyrrolo[3,4-b]pyrrole
Purity: 95+%
Packaging: 1g
Price: $347
Updated: 2021/12/16

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1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE Chemical Properties,Usage,Production

Uses

1-Benzyloctahydropyrrolo[3,4-b]pyrrole is used in the synthesis of intermediates as quinolone anti-bacterials.

Synthesis

132414-78-9

132414-50-7

General procedure for the synthesis of 1-benzyl octahydropyrrolo[3,4-B]pyrrole-5(1H)-carboxylic acid from ethyl 1-benzylhexahydropyrrolo[3,4-B]pyrrole: Ethyl 1-benzyl octahydropyrrolo[2,3-c]pyrrole-5-carboxylate (2.1 g, 7.65 mmol) was dissolved in 37% hydrochloric acid (11 mL), and the reaction was heated and refluxed for 24 hours. Upon completion of the reaction, the pH of the reaction solution was adjusted to 8 with sodium carbonate, followed by multiple extractions of the product with dichloromethane. The organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford 1.4 g of 1-benzyl octahydropyrrolo[3,4-B]pyrrole (90% yield) as a brown oil, which could be used for the next reaction without further purification. Mass spectral analysis (m/z): 203.2 [MH]+.

References

[1] Patent: WO2017/21920, 2017, A1. Location in patent: Paragraph 0633; 0634
[2] Patent: US5071999, 1991, A

1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE Suppliers

China 58 Germany 2 India 1 United Kingdom 1 United States 12 Global 74

NovoChemy Ltd.

Tel: 021-31261262/ 49 (0)17662837245
Fax: (0)21-33250524
Email: sales@novochemy.com
Country: Germany
ProdList: 6328
Advantage: 58

Service Chemical Inc.

Tel: --
Fax: --
Email: sales@chemos-group.com
Country: Germany
ProdList: 6350
Advantage: 71

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View Lastest Price from 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE manufacturers

Career Henan Chemical Co

Product: 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE 132414-50-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-24

132414-50-7, 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLERelated Search:

4-OXO-HEXAHYDRO-CYCLOPENTA[C]PYRROLE-2-CARBOXYLIC ACID TERT-BUTYL ESTER TERT-BUTYL 1-OXO-2,7-DIAZASPIRO[4.5]DECANE-7-CARBOXYLATE BICYCLO[2.2.2]OCTANE-1,4-DICARBOXYLIC ACID HEMIMETHYL ESTER Tert-butyl 1,7-diazaspiro[4,4]nonane-1-carboxylate Tert-butyl 2,6-diazaspiro[3.4]octane-2-carboxylate benzyl 5-oxohexahydrocyclopenta[c]pyrrole-2(1H)-carboxylate 2S-7-Aza-bicyclo[2.2.1]heptane-2,7-dicarboxylic acid 7-tert-butyl ester 7-(TERT-BUTOXYCARBONYL)-1-OXA-2,7-DIAZASPIRO[4.4]NON-2-ENE-3-CARBOXYLIC ACID TERT-BUTYL 1-BENZYLHEXAHYDROPYRROLO[3,4-B]PYRROLE-5(1H)-CARBOXYLATE 1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE 2-Benzyl-Octahydro-Pyrrolo[3,4-C]Pyrrole HCl,2-BENZYL-OCTAHYDRO-PYRROLO [3,4-C] PYRROLE OCTAHYDRO-PYRROLO[3,4-B]PYRROLE 5-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE 2-BENZYL-OCTAHYDRO-PYRROLO[3,4-C]PYRROLE DIHYDROCHLORIDE ETHYL 1-BENZYL-HEXAHYDROPYRROLO[3,4-B]PYRROLE-5(1H)-CARBOXYLATE 1-BENZYL-2-METHYLOCTAHYDROPYRROLO[3,4-B]PYRROLE 2-BENZYL-OCTAHYDRO-PYRROLO[3,4-C]PYRROLE HYDROCHLORIDE (3AS,6AS)-1-BENZYLOCTAHYDROPYRROLO[3,4-B]PYRROLE

1-BENZYL-OCTAHYDRO-PYRROLO[3,4-B]PYRROLE

1-Benzylhexahydropyrrolo[3,4-b]pyrrole

octahydro-1-(phenylmethyl)-Pyrrolo[3,4-b]pyrrole

1-benzyl-3,3a,4,5,6,6a-hexahydro-2H-pyrrolo[2,3-c]pyrrole

1-(phenylmethyl)-3,3a,4,5,6,6a-hexahydro-2H-pyrrolo[2,3-c]pyrrole

Pyrrolo[3,4-b]pyrrole, octahydro-1-(phenylmethyl)-

132414-50-7

Heterocycles series