1,1,1-Tris(hydroxymethyl)ethane
- Product Name
- 1,1,1-Tris(hydroxymethyl)ethane
- CAS No.
- 77-85-0
- Chemical Name
- 1,1,1-Tris(hydroxymethyl)ethane
- Synonyms
- TME;TRIMETHYLOLETHANE;Metriol;Trimet;pentaglycerine;Methyltrimethanolmethane;methyltrimethylolmethane;1,1,1-Tri(hydroxymethyl)ethane;2-METHYL-2-HYDROXYMETHYL-1,3-PROPANEDIOL;Methriol
- CBNumber
- CB7453874
- Molecular Formula
- C5H12O3
- Formula Weight
- 120.15
- MOL File
- 77-85-0.mol
1,1,1-Tris(hydroxymethyl)ethane Property
- Melting point:
- 193-195 °C(lit.)
- Boiling point:
- 137°C 15mm
- Density
- 1.0456 (rough estimate)
- refractive index
- 1.4056 (estimate)
- Flash point:
- 160°C
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 14.03±0.10(Predicted)
- form
- Crystalline Powder, Crystals, and/or Chunks
- color
- White
- Water Solubility
- soluble
- Sensitive
- Hygroscopic
- BRN
- 1304452
- CAS DataBase Reference
- 77-85-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,3-Propanediol, 2-(hydroxymethyl)-2-methyl-(77-85-0)
- EPA Substance Registry System
- 1,3-Propanediol, 2-(hydroxymethyl)-2-methyl- (77-85-0)
Safety
- Safety Statements
- 22-24/25
- WGK Germany
- 3
- RTECS
- TY7137500
- F
- 3
- TSCA
- Yes
- HS Code
- 29054910
- Hazardous Substances Data
- 77-85-0(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- T87807
- Product name
- 1,1,1-Tris(hydroxymethyl)ethane
- Purity
- ≥98%
- Packaging
- 2kg
- Price
- $142
- Updated
- 2024/03/01
- Product number
- T87807
- Product name
- 1,1,1-Tris(hydroxymethyl)ethane
- Purity
- ≥98%
- Packaging
- 12kg
- Price
- $788
- Updated
- 2023/06/20
- Product number
- T0479
- Product name
- Trimethylolethane
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $16
- Updated
- 2024/03/01
- Product number
- T0479
- Product name
- Trimethylolethane
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $35
- Updated
- 2024/03/01
- Product number
- B24324
- Product name
- 1,1,1-Tris(hydroxymethyl)ethane, 97%
- Packaging
- 500g
- Price
- $30.65
- Updated
- 2024/03/01
1,1,1-Tris(hydroxymethyl)ethane Chemical Properties,Usage,Production
Chemical Properties
white crystalline powder, crystals and/or chunks
Uses
Conditioning agent, manufacture of varnishes, alkyd and polyester resins, synthetic drying oils.
Uses
1,1,1-Tris(hydroxymethyl)ethane is an intermediate in the production of alkyd and polyester resins, powder coating resins, synthetic lubricants based on polyol esters, stabilizers for plastics, plasticizers, and pigment coatings. It is used in some phase change materials.
Production Methods
1,1,1-Tris(hydroxymethyl)ethane (2-hydroxymethyl-2-methyl-1,3-propanediol) is made by aldol condensation of propionaldehyde with formaldehyde, followed by reaction of the intermediate 2,2-bis(hydroxymethyl)propanal with excess formaldehyde in the presence of sodium hydroxide or lime as basic component. The resulting aqueous solution is freed from excess formaldehyde by distillation under pressure and further concentrated. The formate byproduct can be separated by extracting the trimethylolethane from the residue with organic solvents such as 2-propanol or by almost complete removal of the water and dissolving the trimethylolethane in acetone or methanol.
Purification Methods
Dissolve it in hot tetrahydrofuran, filter and precipitate it with hexane. It has also been crystallised from acetone/water (1:1). Dry it in a vacuum. [Beilstein 1 H 520, 1 IV 2780.]
1,1,1-Tris(hydroxymethyl)ethane Preparation Products And Raw materials
Raw materials
Preparation Products
1,1,1-Tris(hydroxymethyl)ethane Suppliers
- Tel
- --
- Fax
- --
- b.barendse@ecem.com
- Country
- The Netherlands
- ProdList
- 187
- Advantage
- 51
View Lastest Price from 1,1,1-Tris(hydroxymethyl)ethane manufacturers
- Product
- 1,1,1-Tris(hydroxymethyl)ethane 77-85-0
- Price
- US $99.00-35.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-11
- Product
- 1,1,1-Tris(hydroxymethyl)ethane 77-85-0
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-09-06
- Product
- 1,1,1-Tris(hydroxymethyl)ethane 77-85-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-30