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Phenyltrichlorosilane

Product Name
Phenyltrichlorosilane
CAS No.
98-13-5
Chemical Name
Phenyltrichlorosilane
Synonyms
TRICHLOROPHENYLSILANE;DK958;CP0280;KA 103;NSC 77080;Co-Formula CFS-135;Trichloro(phenyl)sil;Trichloro(phenyl)sila;TRICHLORPHENYLSILAN S;trichlorophenyl-silan
CBNumber
CB7468296
Molecular Formula
C6H5Cl3Si
Formula Weight
211.55
MOL File
98-13-5.mol
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Phenyltrichlorosilane Property

Melting point:
-127°C
Boiling point:
201 °C(lit.)
Density 
1.321 g/mL at 25 °C(lit.)
vapor pressure 
44.3Pa at 20℃
refractive index 
n20/D 1.523(lit.)
Flash point:
196 °F
solubility 
soluble in Chloroform,Benzene,Ether
form 
liquid
color 
colorless
Specific Gravity
1.324
explosive limit
1.6-9.2%(V)
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
508730
InChIKey
ORVMIVQULIKXCP-UHFFFAOYSA-N
CAS DataBase Reference
98-13-5(CAS DataBase Reference)
NIST Chemistry Reference
Phenyl trichlorosilane(98-13-5)
EPA Substance Registry System
Trichlorophenylsilane (98-13-5)
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Safety

Hazard Codes 
T,C,T+
Risk Statements 
21/22-23-34-21-37-35-26-14
Safety Statements 
23-26-36/37/39-45-28
RIDADR 
UN 1804 8/PG 2
WGK Germany 
1
RTECS 
VV6650000
10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29319019
Hazardous Substances Data
98-13-5(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 2390 mg/kg AMIHBC 10,61,54
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
440108
Product name
Trichloro(phenyl)silane
Purity
≥97.0%
Packaging
100ml
Price
$45.1
Updated
2024/03/01
Sigma-Aldrich
Product number
440108
Product name
Trichloro(phenyl)silane
Purity
≥97.0%
Packaging
1l
Price
$97.2
Updated
2024/03/01
TCI Chemical
Product number
P0240
Product name
Phenyltrichlorosilane
Purity
>98.0%(GC)
Packaging
25g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
P0240
Product name
Phenyltrichlorosilane
Purity
>98.0%(GC)
Packaging
500g
Price
$109
Updated
2024/03/01
Alfa Aesar
Product number
A16713
Product name
Phenyltrichlorosilane, 97%
Packaging
100g
Price
$32.5
Updated
2024/03/01
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Phenyltrichlorosilane Chemical Properties,Usage,Production

Chemical Properties

Phenyl trichlorosilane is a colorless to light yellow liquid.

Uses

Phenyltrichlorosilane can be used in the development of high-capacitance polymer dielectric for low-voltage organic transistors.

Preparation

The high-temperature condensation (HTC) technique proved to be very convenient and economical for the production of phenyltrichlorosilane and in recent years has become one of the main industrial techniques for its synthesis.
The synthesis of phenyltrichlorosilane by HTC technique is conducted according to the reaction:
HSiCI3 + C6H5CI →(HCI)→ C6H5SiCI3
In this case, similarly to the vinyltrichlorosilane case, in the conditions of synthesis (600-640 °C) there is a secondary reaction of reduction, which forms silicon tetrachloride and benzene. However, if the process is conducted in the presence of an initiator (5% of diazomethane), it is possible to reduce the temperature down to 500-550 °C. Then the secondary reaction proceeds very slowly, which increases the yield of phenyltrichlorosilane by 1.5 times. To suppress the reduction process, one can also add benzene and silicon tetrachloride into the reactive mixture. It is also possible to boost the yield of phenyltrichlorosilane and increase the degree of the chlorobenzene transformation by using two subsequent reactors.

General Description

A colorless liquid with a pungent odor. Flash point 91°F. Decomposed by moisture or water to hydrochloric acid with evolution of heat. Corrosive to metals and tissue.

Reactivity Profile

Chlorosilanes, such as Phenyltrichlorosilane are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

Health Hazard

Highly toxic; may cause death or permanent injury after short inhalation exposure to small quantity. Chemical burns to all exposed membranes and tissues with severe tissue destruction. Inhalation -- lungs may fill up with fluid or throat may swell causing suffocation. Eyes -- damage to corneas may cause blindness. Delayed: after oral exposure stomach and intestines may perforate or be obstructed by scar tissue.

Flammability and Explosibility

Non flammable

Potential Exposure

Phenyl trichlorosilane is used to make silicones for water repellants, insulating resins; heat resistant paints; and as a laboratory reagent

Shipping

UN1804 Phenyltrichlorosilane, Hazard class: 8; Labels: 8-Corrosive material.

Phenyltrichlorosilane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Phenyltrichlorosilane manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Phenyltrichlorosilane 98-13-5
Price
US $20.00-11.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-24
Hebei Chuanghai Biotechnology Co,.LTD
Product
Phenyltrichlorosilane 98-13-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99.%
Supply Ability
10 ton
Release date
2024-08-19
Hebei Mojin Biotechnology Co., Ltd
Product
Phenyltrichlorosilane 98-13-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-25

98-13-5, PhenyltrichlorosilaneRelated Search:


  • CP0280
  • phenyltrichloro-silan
  • Phenyltrichlorosilicane
  • Silane, phenyltrichloro-
  • Silane, trichlorophenyl-
  • silane,trichlorophenyl-
  • Silicon phenyl trichloride
  • siliconphenyltrichloride
  • trichlorophenyl-silan
  • TRICHLORPHENYLSILAN S
  • Trichloro(phenyl)sila
  • (Trichlorosilyl)benzene
  • Benzene,(trichlorosilyl)-
  • Co-Formula CFS-135
  • KA 103
  • NSC 77080
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  • Phenyltrichlorosilane,97%
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  • DK958
  • 98-13-5
  • C6H5SiCl3
  • C6H5SiC13
  • C6H5SiH2Cl
  • C6H5Cl3Si
  • Silane Coupling Agents (Intermediates)
  • Si-Cl Compounds
  • Trichlorosilanes
  • Silane Coupling Agents
  • Si (Classes of Silicon Compounds)
  • organosilicon compounds
  • Organics
  • Functional Materials
  • Si (Classes of Silicon Compounds)
  • Si-Cl Compounds
  • Silane Coupling Agents
  • Silane Coupling Agents (Intermediates)
  • Trichlorosilanes
  • Phenyl Silanes