4-Nitrobiphenyl
- Product Name
- 4-Nitrobiphenyl
- CAS No.
- 92-93-3
- Chemical Name
- 4-Nitrobiphenyl
- Synonyms
- Ba 2794;NSC 1324;AKOS 223-11;4-nitro-bipheny;4-Nitrodiphenyl;p-Nitrobiphenyl;p-Nitrodiphenyl;4-NITROBIPHENYL;4-nitrobiphenyle;4-NITROLBIPHENYL
- CBNumber
- CB7482649
- Molecular Formula
- C12H9NO2
- Formula Weight
- 199.21
- MOL File
- 92-93-3.mol
4-Nitrobiphenyl Property
- Melting point:
- 114 °C
- Boiling point:
- 340 °C
- Density
- 1.1919 (rough estimate)
- refractive index
- 1.5880 (estimate)
- Flash point:
- 43 °C
- solubility
- Soluble in acetic acid, benzene, chloroform, and ether (Weast, 1986)
- form
- Solid
- color
- White
- Water Solubility
- insoluble
- Stability:
- Stable. Incompatible with strong oxidizing agents.
- InChI
- InChI=1S/C12H9NO2/c14-13(15)12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H
- InChIKey
- BAJQRLZAPXASRD-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)=CC=C([N+]([O-])=O)C=C1
- CAS DataBase Reference
- 92-93-3(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,1'-Biphenyl, 4-nitro-(92-93-3)
- IARC
- 3 (Vol. 4, Sup 7) 1987
- EPA Substance Registry System
- 4-Nitrobiphenyl (92-93-3)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 45-51/53
- Safety Statements
- 53-45-61
- RIDADR
- 2811
- RTECS
- DV5600000
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29042090
- Hazardous Substances Data
- 92-93-3(Hazardous Substances Data)
- Toxicity
- Acute oral LD50 for rats 2,230 mg/kg, rabbits 1,970 mg/kg (quoted, RTECS, 1985).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H350May cause cancer
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- N493710
- Product name
- 4-Nitrobiphenyl
- Packaging
- 5g
- Price
- $180
- Updated
- 2021/12/16
- Product number
- 119400
- Product name
- 4-Nitrobiphenyl
- Purity
- 95+%
- Packaging
- 5g
- Price
- $216
- Updated
- 2021/12/16
- Product number
- OR26189
- Product name
- 4-Nitrobiphenyl
- Purity
- 95%
- Packaging
- 1g
- Price
- $44
- Updated
- 2021/12/16
- Product number
- 4654-1-43
- Product name
- 4-Nitrobiphenyl
- Purity
- 97%
- Packaging
- 1g
- Price
- $48
- Updated
- 2021/12/16
- Product number
- 119400
- Product name
- 4-Nitrobiphenyl
- Purity
- 95+%
- Packaging
- 1g
- Price
- $72
- Updated
- 2021/12/16
4-Nitrobiphenyl Chemical Properties,Usage,Production
Chemical Properties
Yellow Solid
Chemical Properties
4-Nitrobiphenyl exists as yellow plates or needles..
Uses
4-Nitrobiphenyl has some uses as a plasticizer, fungicide, and wood preservative.
Uses
Formerly used as an intermediate for 4-aminobiphenyl
Uses
Formerly in preparation of p-biphenylamine, q.v.
Definition
ChEBI: 4-Nitrobiphenyl is a member of biphenyls.
Synthesis Reference(s)
Tetrahedron Letters, 37, p. 4499, 1996 DOI: 10.1016/0040-4039(96)00924-0
General Description
White to yellow needle-like crystalline solid with a sweetish odor.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Nitrobiphenyl is incompatible with the following: Strong reducers .
Hazard
Toxic by ingestion and skin contact. Confirmed carcinogen.
Health Hazard
p-Nitrobiphenyl (PNB) is a urinary bladder carcinogen in dogs.
Toxicology
4-Nitrobiphenyl is no longer manufactured or used in the United States. Limited information is available on the health effects of 4-nitrobiphenyl. Acute (short-term) exposure to 4-nitrobiphenyl in humans results in irritation of the eyes, mucous membranes, and respiratory tract, such as headache, nausea, vomiting, and fatigue. Chronic (long-term) exposure to high concentrations of 4-nitrobiphenyl in workers has resulted in effects on the peripheral and central nervous systems as well as the liver and kidney. No information on the reproductive, developmental, or carcinogenic effects of 4-nitrobiphenyl in humans is available. EPA has not classified 4-nitrobiphenyl for carcinogenicity. 4-Nitrobiphenyl is no longer manufactured, imported, used, or sold in the United States.
Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
Potential Exposure
4-Nitrobiphenyl was formerly used in the synthesis of 4-aminodiphenyl. It is presently used only for research purposes; there are no commercial uses.
Carcinogenicity
The case for the carcinogenicity of PNB is supported by (1) the induction of urinary bladder cancer in dogs after administration of PNB; (2) the evidence that PNB is metabolized in vivo to 4-aminobiphenyl (a potent carcinogen); and (3) the possibility that the cases of human urinary bladder cancer attributed to 4- aminobiphenyl may also have been induced by exposure to PNB.1
Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Incompatibilities
Incompatible with strong reducing agents such as hydrides, oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Waste Disposal
Incineration @ 982℃/2.0 seconds (minimum) with scrubbing for nitrogen oxides abatement.
4-Nitrobiphenyl Preparation Products And Raw materials
Raw materials
Preparation Products
4-Nitrobiphenyl Suppliers
- Tel
- 15523000485
- xingcanyaoye@sina.com
- Country
- China
- ProdList
- 1687
- Advantage
- 58
- Tel
- 821-50328103-801 18930552037
- Fax
- 86-21-50328109
- 3bsc@sina.com
- Country
- China
- ProdList
- 15839
- Advantage
- 69
- Tel
- 0311-89250318 031166536426
- Fax
- 4000311741
- master@sjzsdyn.com
- Country
- China
- ProdList
- 2988
- Advantage
- 65
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12390
- Advantage
- 60
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32321
- Advantage
- 50
- Tel
- 0571-82693216
- Fax
- +86-571-82880190
- info@yuhaochemical.com
- Country
- China
- ProdList
- 9387
- Advantage
- 52
- Tel
- 021-58950125
- Fax
- (86) 21-58955996
- info@chemexpress.com
- Country
- China
- ProdList
- 7552
- Advantage
- 61
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 18209
- Advantage
- 56
- Tel
- 021-61995394 18916691159
- chemicalsea@163.com
- Country
- China
- ProdList
- 1972
- Advantage
- 58
- Tel
- 86-21-51086038
- Fax
- 86-21-51861608
- Country
- China
- ProdList
- 2930
- Advantage
- 58
- Tel
- 021-60345187 13671753212
- Fax
- 021-34702061
- lzz841106@aliyun.com
- Country
- China
- ProdList
- 10274
- Advantage
- 55
- Tel
- 021-61478794
- Fax
- 021-61478794
- sales@hcshhai.com
- Country
- China
- ProdList
- 9793
- Advantage
- 50
- Tel
- 02781293128
- orders@biochemsafebuy.com
- Country
- China
- ProdList
- 9923
- Advantage
- 55
- Tel
- 4009903999 13395398332
- Fax
- 0539-6365991
- sales@xiyashiji.com
- Country
- China
- ProdList
- 20806
- Advantage
- 60
- Tel
- 18126413629 0755-23311925 2355327053
- Fax
- 0755-23311925
- abel@ycgmp.com
- Country
- China
- ProdList
- 5113
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 18124570582 TEL：0755-23574479 2355327139
- Fax
- 0755-23229476 QQ: 2355327139
- siliao02@yccreate.com
- Country
- China
- ProdList
- 6116
- Advantage
- 58
- Tel
- 400-711-5280 86-571-81025280
- Fax
- 86-571-85806285
- sales@molcore.com
- Country
- China
- ProdList
- 9967
- Advantage
- 58
- Tel
- 021-021-52271985 17721149837
- Fax
- +86 (21) 52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 19800
- Advantage
- 60
- Tel
- 18578209868 2355327026
- Fax
- 18578209868 QQ：2355327026
- steroidbest@hotmail.com
- Country
- China
- ProdList
- 6501
- Advantage
- 58
- Tel
- 18062666947
- Fax
- 18062666959
- 2355880548@qq.com
- Country
- China
- ProdList
- 4228
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57423
- Advantage
- 58
- Tel
- +86-0551-65418671 +8618949823763
- Fax
- 0551-65418697
- sales@tnjchem.com
- Country
- China
- ProdList
- 34563
- Advantage
- 58
- Tel
- 86-21-51086038
- Fax
- 86-21-51861608
- chemwill_asia@126.com
- Country
- CHINA
- ProdList
- 23912
- Advantage
- 58
- Tel
- 86-13657291602
- Fax
- 027-59338440
- linda@hubeijusheng.com
- Country
- CHINA
- ProdList
- 22963
- Advantage
- 58
- Tel
- 153-07155313 15307155313
- Fax
- QQ：2274366233
- 2274366233@qq.com
- Country
- China
- ProdList
- 4787
- Advantage
- 58
- Tel
- +86-023-6139-8061 +86-86-13650506873
- sales@chemdad.com
- Country
- China
- ProdList
- 39894
- Advantage
- 58
- Tel
- +8618523575427
- sales@conier.com
- Country
- China
- ProdList
- 49374
- Advantage
- 58
- Tel
- 18017061086
- oled@richest-group.com
- Country
- CHINA
- ProdList
- 5600
- Advantage
- 58
- Tel
- 18501792038; 18501792038
- shanpel@anpel.com.cn
- Country
- China
- ProdList
- 9611
- Advantage
- 58
- Tel
- 13720274133
- Fax
- 027-83850377
- 2395204132@qq.com
- Country
- China
- ProdList
- 3657
- Advantage
- 58
- Tel
- 021-021-61109150
- Fax
- 021-61105897
- sales@tcisct.com
- Country
- China
- ProdList
- 31121
- Advantage
- 58
- Tel
- 18902340307 18902340307
- Fax
- 0751-2819901
- 3356812514@qq.com
- Country
- China
- ProdList
- 9244
- Advantage
- 58
- Tel
- 029-61856358 15229202216
- Fax
- 029-88380327
- 1020@dideu.com
- Country
- China
- ProdList
- 10011
- Advantage
- 58
- Tel
- 025-58748998 18951874644
- shanhui.zhan@king-pharm.com
- Country
- China
- ProdList
- 1316
- Advantage
- 58
- Tel
- 0751-2815987 13927875076
- Fax
- 0751-2828607
- 3007432263@qq.com
- Country
- China
- ProdList
- 9968
- Advantage
- 58
- Tel
- 400-0516-021 19121335088
- Fax
- 0516-86287676
- info@bcpharma.com
- Country
- China
- ProdList
- 2750
- Advantage
- 58
- Tel
- 027-87466205 15377579727
- 1228964013@qq.com
- Country
- China
- ProdList
- 8558
- Advantage
- 58
- Tel
- 025-66113011 18112977050
- cb5@aikonchem.com
- Country
- China
- ProdList
- 10528
- Advantage
- 58
- Tel
- +86-18521732826
- market@aladdin-e.com
- Country
- China
- ProdList
- 48461
- Advantage
- 58
- Tel
- 021-56698539 18019222030
- bxsw_sh@163.com
- Country
- China
- ProdList
- 3767
- Advantage
- 58
- Tel
- 4008-099-669
- 23419001name@qq.com
- Country
- CHINA
- ProdList
- 73043
- Advantage
- 58
- Tel
- 58896805
- 7993601name@qq.com
- Country
- CHINA
- ProdList
- 15620
- Advantage
- 58
- Tel
- 18153089275
- 3032079623@qq.com
- Country
- China
- ProdList
- 22695
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- sales@coreychem.com
- Country
- China
- ProdList
- 29880
- Advantage
- 58
- Tel
- +8613817748580
- Fax
- 021-50175322
- cooperation@kean-chem.com
- Country
- China
- ProdList
- 40066
- Advantage
- 58
- Tel
- +86-400-0516-021
- Fax
- 0516-86287676
- info@bcpharma.com
- Country
- China
- ProdList
- 2738
- Advantage
- 58
- Tel
- +8615350571055
- Sibel@weibangbio.com
- Country
- China
- ProdList
- 6087
- Advantage
- 58
- Tel
- yiyunchem@163.com
- Country
- China
- ProdList
- 5808
- Advantage
- 58
- Tel
- +86-371-86557731 +86-13613820652
- Fax
- 86-0371-86557731
- info@fdachem.com
- Country
- China
- ProdList
- 20282
- Advantage
- 58
View Lastest Price from 4-Nitrobiphenyl manufacturers
- Product
- 4-Nitrobiphenyl 92-93-3
- Price
- US $100.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10KG
- Release date
- 2018-07-24