ChemicalBook > CAS DataBase List > 3-Fluorophenethyl alcohol

3-Fluorophenethyl alcohol

Product Name
3-Fluorophenethyl alcohol
CAS No.
52059-53-7
Chemical Name
3-Fluorophenethyl alcohol
Synonyms
Pratraxa impurity 1;3-Fluorobenzeneethanol;3-Fluorophenylethanol ;3-fluorophenyl alcohol;3-FLUOROPHENETHYL ALCOHOL;2-(M-FLUOROPHENYL)ETHANOL;2-(3-FLUOROPHENYL)ETHANOL;3-Fluorophenethylealcohol;Benzeneethanol, 3-fluoro-;2-(3-Fluorophenyl)ethan-1-ol
CBNumber
CB7491498
Molecular Formula
C8H9FO
Formula Weight
140.15
MOL File
52059-53-7.mol
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3-Fluorophenethyl alcohol Property

Boiling point:
90 °C/3 mmHg (lit.)
Density 
1.125 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.509(lit.)
Flash point:
225 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
pka
14.76±0.10(Predicted)
color 
Clear colorless
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Safety

Hazard Codes 
C,Xn
Risk Statements 
36/37/38-21/22-34
Safety Statements 
26-36/37/39-45-27
RIDADR 
2810
WGK Germany 
3
HS Code 
29062990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
F0776
Product name
2-(3-Fluorophenyl)ethanol
Purity
>98.0%(GC)
Packaging
1g
Price
$36
Updated
2025/07/31
TCI Chemical
Product number
F0776
Product name
2-(3-Fluorophenyl)ethanol
Purity
>98.0%(GC)
Packaging
5g
Price
$106
Updated
2025/07/31
TRC
Product number
F632318
Product name
2-(3-Fluorophenyl)ethanol
Packaging
500mg
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
PC5701
Product name
3-Fluorophenethyl alcohol
Purity
98%
Packaging
1g
Price
$10
Updated
2021/12/16
SynQuest Laboratories
Product number
2601-3-Y1
Product name
3-Fluorophenethyl alcohol
Purity
98%
Packaging
1g
Price
$16
Updated
2021/12/16
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3-Fluorophenethyl alcohol Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

General Description

3-Fluorophenethyl alcohol is a fluorinated β-phenethyl alcohol. Regioselective synthesis of 3-fluorophenethyl alcohol via regioselective hydroboration has been reported.

Synthesis

331-25-9

52059-53-7

The general procedure for the synthesis of 3-fluorophenylethanol from 3-fluorophenylacetic acid was as follows: to a stirred solution of 3-fluorophenylacetic acid (5.0 g, 32.0 mmol) in ether (100 ml) was slowly added dropwise an ether solution of lithium aluminum hydroxide (32.4 ml, 1 M, 32.4 mmol) at -10 °C. The reaction mixture was gradually warmed to 25°C and stirred continuously for 1 hour. Subsequently, the reaction mixture was cooled again to -10°C and the reaction was quenched by sequential addition of methanol (20 ml) and 4M sodium hydroxide solution (20 ml). The resulting slurry was filtered and the filtrate was concentrated by evaporation under vacuum. The crude product was purified by silica gel column chromatography using CH2Cl2/MeOH/NH3 (80:8:1) as eluent to give 3-fluorophenylethanol (3.80 g, 84% yield) finally. The product was confirmed by NMR hydrogen spectrum (250 MHz, CDCl3): δ 2.87 (3H, t, J = 6.5 Hz, CH2), 3.87 (3H, t, J = 6.5 Hz, CH2), 6.89-7.02 (3H, m, Ar-H), 7.23-7.33 (1H, m, Ar-H).

References

[1] Journal of Organic Chemistry, 2005, vol. 70, # 14, p. 5528 - 5535
[2] Tetrahedron Asymmetry, 2001, vol. 12, # 4, p. 585 - 596
[3] Patent: US5889008, 1999, A
[4] Helvetica Chimica Acta, 1973, vol. 56, p. 2460 - 2479
[5] Journal of the American Chemical Society, 1978, vol. 100, p. 228 - 246

3-Fluorophenethyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Fluorophenethyl alcohol Suppliers

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52059-53-7, 3-Fluorophenethyl alcoholRelated Search:

Ethyl acetate 4-Fluorobenzaldehyde Phenethyl alcohol 1,2-Difluorobenzene Florfenicol Transfluthrin DL-1-Phenethylalcohol 3-Fluorophenylacetic acid 3,4-DIFLUOROMANDELIC ACID 3,5-Difluorophenylacetic acid AMINO-(3-FLUORO-PHENYL)-ACETIC ACID 2,5-Difluoromandelic acid 3,4-Difluorophenylacetic acid 2,3,6-TRIFLUOROPHENYLACETIC ACID 4-FLUOROPHENETHYL ALCOHOL,para-Fluorophenethyl alcohol,4-Fluorophenethyl alcohol 97% FENFLURAMINE 2,3,4,5,6-PENTAFLUOROPHENYLACETIC ACID 2,3-Difluorophenylacetic acid

  • 3-Fluorophenethyl alcohol ,98%
  • 3-Fluorobenzeneethanol
  • 3-Fluorophenethyl alcohol,99%
  • 2-(3-Fluorophenyl)ethyl Alcohol 3-Fluorophenethyl Alcohol
  • 2-(3-Fluorophenyl)ethan-1-ol
  • 3-Fluorophenethylealcohol
  • 2-(3-FLUOROPHENYL)ETHANOL
  • 2-(M-FLUOROPHENYL)ETHANOL
  • 3-FLUOROPHENETHYL ALCOHOL
  • 2-(3-Fluorophenyl)ethylalcohol
  • 3-FLUOROPHENETHYL ALCOHOL 99%
  • 3-Fluorophenylethanol
  • 2-(3-Fluorophenyl)ethanol&gt
  • Benzeneethanol, 3-fluoro-
  • 52059-53-7 2-(3-Fluorophenyl)ethanol
  • 3-fluorophenyl alcohol
  • Pratraxa impurity 1
  • 52059-53-7
  • ALCOHOL
  • Building Blocks
  • Alcohols
  • C7 to C8
  • Organic Building Blocks
  • Oxygen Compounds
  • Fluorine series
  • Oxygen Compounds
  • Phenyls & Phenyl-Het
  • Phenyls & Phenyl-Het
  • Alcohols
  • C7 to C8