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Bipariden

Product Name
Bipariden
CAS No.
514-65-8
Chemical Name
Bipariden
Synonyms
kl373;KL 373;Akineton;biperiden;Beperiden;bipariden;Akinophyl;Bibristan;Biperidine;BiperidenHcl
CBNumber
CB7501632
Molecular Formula
C21H29NO
Formula Weight
311.46106
MOL File
514-65-8.mol
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Bipariden Property

Melting point:
114°C
Boiling point:
451.49°C (rough estimate)
Density 
1.0202 (rough estimate)
refractive index 
1.5614 (estimate)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly,Sonicated), Methanol (Slightly, Sonicated)
form 
Solid
pka
14.05±0.29(Predicted)
color 
White to Off-White
Water Solubility 
25.1 mg/L
NIST Chemistry Reference
Biperiden(514-65-8)
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Safety

Hazardous Substances Data
514-65-8(Hazardous Substances Data)
Toxicity
LD50 in mice (mg/kg): 195 s.c., 56 i.v. (Klavehn)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B397820
Product name
Biperiden
Packaging
50mg
Price
$160
Updated
2021/12/16
Biorbyt Ltd
Product number
orb611544
Product name
Bipariden
Packaging
50mg
Price
$224.4
Updated
2021/12/16
AK Scientific
Product number
P695
Product name
Biperiden
Packaging
5mg
Price
$34
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
API0009339
Product name
BIPERIDEN
Purity
95.00%
Packaging
100MG
Price
$329.7
Updated
2021/12/16
Biorbyt Ltd
Product number
orb611544
Product name
Bipariden
Packaging
100mg
Price
$345.1
Updated
2021/12/16
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Bipariden Chemical Properties,Usage,Production

Originator

Akineton HCl,Knoll,US,1959

Uses

amoebicide

Definition

ChEBI: N-Propylpiperidine in which the methyl hydrogens are substituted by hydroxy, phenyl, and 5-norbornen-2-yl groups. A muscarinic antagonist affecting both the central and peripheral nervous systems, it is used in the treatment of all form of Parkinson's disease.

Manufacturing Process

65 grams of 3-piperidino-1-phenyl propanone-1 of the summary formula C14H29ON, produced according to Mannich's reaction by reacting acetophenone with formaldehyde and piperidine hydrochloride are dissolved in 300 cc of benzene. The resulting solution is added to an organo-magnesium solution prepared from 96 grams of [δ5-bicyclo-(2,2,1)-heptenyl-2]-chloride (also known as 5-chloro-2-norbomene) 18.5 grams of magnesium shavings, and 300 cc of ether.
The reaction mixture is boiled for half an hour under reflux. Thereafter the ether is removed by distillation, until the inside temperature reaches 65°- 70°C. The resulting benzene solution is added to 95 cc concentrated hydrochloric acid containing ice for further processing. Thereby, 3-piperidino- 1-phenyl-1-[δ5-bicyclo-(2,2,1)-heptenyl-2]-propanol-1 of the summary formula C21H29ON is obtained. The compound melts at 101°C and its chlorohydrate has a melting point of about 238°C. The compound is difficultly soluble in water, slightly soluble in ethanol, and readily soluble in methanol.

brand name

Akineton (Abbott).

Therapeutic Function

Antiparkinsonian

General Description

Biperiden,α-5-norbornen-2-yl- -phenyl-1-piperidinepropanol (Akineton), introduced in 1959,has a relatively weak visceral anticholinergic, but a strongnicotinolytic, action in terms of its ability to block nicotineinducedconvulsions. Therefore, its neurotropic action israther low on intestinal musculature and blood vessels. It hasa relatively strong musculotropic action, which is aboutequal to that of papaverine, in comparison with most syntheticanticholinergic drugs. Its action on the eye, althoughmydriatic, is much lower than that of atropine. These weakanticholinergic effects add to its usefulness in Parkinson syndromeby minimizing side effects.

Clinical Use

Biperiden is used in all types of Parkinson disease (postencephalitic,idiopathic, arteriosclerotic) and helps toeliminate akinesia, rigidity, and tremor. It is also usedin drug-induced extrapyramidal disorders to eliminatesymptoms and permit continued use of tranquilizers.Biperiden is also of value in spastic disorders not related toparkinsonism, such as multiple sclerosis, spinal cord injury,and cerebral palsy. It is contraindicated in all formsof epilepsy.

Safety Profile

Poison by ingestion,subcutaneous, intraperitoneal, and intravenous routes.When heated to decomposition, it emits toxic fumes ofNOx.

Synthesis

Biperiden, 1-(5-norbornen-2-yl)-1-phenyl-3-piperidinopropan-1-ol (10.2.4), is also synthesized according to the method of making trihexyphenidyl, except by reacting 2-(1-piperidino)propiophenone (10.2.1) with 5-norbornen-2-ylmagnesiumbromide [33,34].

Bipariden Preparation Products And Raw materials

Raw materials

Preparation Products

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Bipariden Suppliers

kemikalieimport
Tel
--
Fax
--
Email
Sales@kemikalieimport.dk
Country
Europe
ProdList
6685
Advantage
47
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View Lastest Price from Bipariden manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Bipariden 514-65-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bipariden 514-65-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bipariden 514-65-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

514-65-8, BiparidenRelated Search:


  • alpha-(bicyclo(2.2.1)hept-5-en-2-yl)-alpha-phenyl-1-piperidinopropanol
  • alpha-5-norbornen-2-yl-alpha-phenyl-1-piperidinepropano
  • alpha-5-Norbornen-2-yl-alpha-phenyl-1-piperidinepropanol
  • alpha-bicyclo(2.2.1)hept-5-en-2-yl-alpha-phenyl-1-piperidinepropano
  • alpha-phenyl-alpha-(2-piperidinoethyl)-5-norbornene-2-methano
  • Beperiden
  • -Bicyclo[2,2,1]hept-5-en-2yl-phenyl-1-piperidinepropanol
  • Bicyclo[2.2.1]hept-5-ene-2-methanol, alpha-phenyl-alpha-[2-(1-piperidinyl)ethyl]-
  • biperiden
  • Biperidine
  • KL 373
  • BIPERIDEN (200 MG)
  • 1-(5-bicyclo[2.2.1]hept-2-enyl)-1-phenyl-3-(1-piperidyl)propan-1-ol
  • 1-Bicyclo[2.2.1]hept-5-en-2-yl-1-phenyl-3-(1-piperidinyl)-1-propanol
  • 1-Bicycloheptenyl-1-phenyl-3-piperidino-propanol-1
  • 1-Piperidinepropanol, alpha-5-norbornen-2-yl-alpha-phenyl-
  • 1-Piperidinepropanol, alpha-bicyclo[2.2.1]hept-5-en-2-yl-alpha-phenyl-
  • 3-Piperidino-1-phenyl-1-bicyclo-
  • 3-Piperidino-1-phenyl-1-bicyclo(2.2.1)hepten-(5)-yl-propanol-(1)
  • 3-Piperidino-1-phenyl-1-bicycloheptenyl-1-propanol
  • bipariden
  • -5-Norbornen-2-yl-phenyl-1-piperidinepropanol
  • 5-Norbornene-2-methanol, alpha-phenyl-alpha-(2-piperidinoethyl)-
  • a-bicyclo[2.2.1]hept-5-en-2yl-a-phenyl-1-piperidinepropanol
  • Akineton
  • Akinophyl
  • alpha-(Bicyclo(2.2.1)hept-5-en-2-yl)-alpha-phenyl-1-piperidino propanol
  • kl373
  • 1-phenyl-3-piperidino-1-(8,9,10-trinorborn-5-en-2-yl)propan-1-ol
  • BiperidenHcl
  • 1-Piperidinepropanol, a-5-norbornen-2-yl-a-phenyl- (6CI, 7CI, 8CI)
  • 1-Piperidinepropanol, a-bicyclo[2.2.1]hept-5-en-2-yl-a-phenyl-
  • α-(Bicyclo[2.2.1]hept-5-en-2-yl)-α-phenyl-1-piperidinopropanol
  • α-(Bicyclo[2.2.1]hept-5-en-2-yl)-α-phenyl-1-piperidine-1-propanol
  • Biperiden, USP
  • Biperiden Hydrochloride USP
  • Biperiden (Mixture of diastereomers)
  • Bibristan
  • 1-Piperidinepropanol, α-bicyclo[2.2.1]hept-5-en-2-yl-α-phenyl-
  • Bipariden USP/EP/BP
  • Alpha-5-Norbornene-2-yl-alphaphentl-1-piperidinepropanol (Biperiden base)
  • Biperiden Hcl -USP/ EP/IP/JP
  • Biperiden (1072001)
  • 1-(Bicyclo[2.2.1]hept-5-en-2-yl)-1-phenyl-3-(piperidin-1-yl)propan-1-ol
  • Bipariden Impurity
  • 514-65-8
  • C21H29NO