ChemicalBook > CAS DataBase List > (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
Reaction- Product Name
- (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
- CAS No.
- 307926-51-8
- Chemical Name
- (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
- Synonyms
- (S,S)Salen AI;(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-;(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminumchloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride,98%;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%;Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI)
- CBNumber
- CB7504613
- Molecular Formula
- C36H52AlClN2O2
- Formula Weight
- 607.254
- MOL File
- 307926-51-8.mol
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Property
- Melting point:
- >350 °C(lit.)
- form
- Powder
- color
- yellow
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 531979
- Product name
- (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
- Packaging
- 1g
- Price
- $82.4
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 13-5801
- Product name
- (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
- Packaging
- 1g
- Price
- $186
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 13-5801
- Product name
- (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%
- Packaging
- 5g
- Price
- $741
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- OGM0000048
- Product name
- (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $671.25
- Updated
- 2021/12/16
Ambeed
- Product number
- A913279
- Product name
- (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
- Purity
- 98%
- Packaging
- 25g
- Price
- $1365
- Updated
- 2021/12/16
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Chemical Properties,Usage,Production
Reaction
Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes.
Uses
(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
- In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
- In the cyanation of α,β-unsaturated imides to yield saturated imides.
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Preparation Products And Raw materials
Raw materials
Preparation Products
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(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Suppliers
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- United States
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