3-BROMO-2-CHLORO-4-PICOLINE
- Product Name
- 3-BROMO-2-CHLORO-4-PICOLINE
- CAS No.
- 55404-31-4
- Chemical Name
- 3-BROMO-2-CHLORO-4-PICOLINE
- Synonyms
- 3-BROMO-2CHLORL-4-PICOLINE;3-BROMO-2-CHLORO-4-PICOLINE;2-CHLORO-3-BROMO-4-PICOLINE;3-Bromo-2-chloro-4-methyl...;3-Bromo-2-chloro-4-methylprinine;2-Chloro-3-bromo-4-methylpyridine;3-BROMO-2-CHLORO-4-METHYLPYRIDINE;Pyridine, 3-bromo-2-chloro-4-methyl-;3-Bromo-2-chloro-4-methylpyridine 97%;2 - chloro 4 - methyl 3 - bromo pyridine
- CBNumber
- CB7702440
- Molecular Formula
- C6H5BrClN
- Formula Weight
- 206.47
- MOL File
- 55404-31-4.mol
3-BROMO-2-CHLORO-4-PICOLINE Property
- Boiling point:
- 250.3±35.0 °C(Predicted)
- Density
- 1.624±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 0.17±0.10(Predicted)
- form
- solid
- color
- Light yellow
- CAS DataBase Reference
- 55404-31-4(CAS DataBase Reference)
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B682748
- Product name
- 3-Bromo-2-chloro-4-picoline
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B682748
- Product name
- 3-Bromo-2-chloro-4-picoline
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FC55550
- Product name
- 2-Chloro-3-bromo-4-methylpyridine
- Packaging
- 500mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- OR301029
- Product name
- 3-Bromo-2-chloro-4-methylpyridine
- Purity
- 97%
- Packaging
- 25g
- Price
- $203
- Updated
- 2021/12/16
- Product number
- 3H32-D-04
- Product name
- 3-Bromo-2-chloro-4-methylpyridine
- Purity
- 95%
- Packaging
- 5G
- Price
- $100
- Updated
- 2021/12/16
3-BROMO-2-CHLORO-4-PICOLINE Chemical Properties,Usage,Production
Synthesis
133627-45-9
55404-31-4
(1) Synthesis of 3-bromo-2-chloro-4-methylpyridine 3-Amino-2-chloro-4-methylpyridine (2 g) was dissolved in a solvent mixture of 48% aqueous hydrogen bromide solution (17 mL) and water (12 mL). Sodium nitrite (2.5 g) was added to the solution in batches at 0 °C. Subsequently, bromine (22 mL) was added slowly and dropwise. The reaction mixture was gradually warmed to room temperature and stirred continuously for 12 hours. Upon completion of the reaction, the pH was adjusted to neutral with 5N aqueous sodium hydroxide and extracted with ethyl acetate. The organic layer was washed with saturated brine and dried over anhydrous magnesium sulfate. After filtration to remove the drying agent, the filtrate was concentrated under reduced pressure to afford the target product 3-bromo-2-chloro-4-methylpyridine (1.7 g). The product was characterized by 1H-NMR (400 MHz, CDCl3): δ 2.51 (s, 3H), 7.01-7.24 (m, 1H), 8.06-8.35 (m, 1H).
References
[1] Patent: US2013/143907, 2013, A1. Location in patent: Paragraph 0475; 0476
3-BROMO-2-CHLORO-4-PICOLINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-BROMO-2-CHLORO-4-PICOLINE manufacturers
- Product
- 3-BROMO-2-CHLORO-4-PICOLINE 55404-31-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-29
- Product
- 3-BROMO-2-CHLORO-4-PICOLINE 55404-31-4
- Price
- US $5.00-0.10/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- 3-BROMO-2-CHLORO-4-PICOLINE 55404-31-4
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 1000KGS
- Release date
- 2019-12-20