ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Reaction

Product Name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS No.: 99326-34-8
Chemical Name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonyms: Chiralyst P468;Bis(1,5-cyclooctadie;Bis(1,5-cyclooctadiene);ooctadiene)rhodium(I) trifL;Bis(1,5-cyclooctadiene)rhodium triflate;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&;Bis(1,5-cyclooctadiene)rhodium(I) triflate;BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I);BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate
CBNumber: CB7722901
Molecular Formula: C17H24F3O3RhS
Formula Weight: 468.34
MOL File: 99326-34-8.mol

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Property

Melting point:: 159 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in chloroform
form: crystal
color: dark red
Water Solubility: insoluble
Sensitive: Air Sensitive
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
Hazard Note: Irritant
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 683159
Product name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging: 2g
Price: $529.2
Updated: 2025/07/31

Sigma-Aldrich

Product number: 530840
Product name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Purity: 98%
Packaging: 1g
Price: $296.8
Updated: 2025/07/31

Strem Chemicals

Product number: 45-0110
Product name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 99%
Packaging: 100mg
Price: $88
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0110
Product name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 99%
Packaging: 500mg
Price: $349
Updated: 2024/03/01

Sigma-Aldrich

Product number: 683159
Product name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging: 500mg
Price: $123
Updated: 2025/07/31

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties,Usage,Production

Reaction

Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
Rhodium catalyzed asymmetric synthesis of Sitagliptin
Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones

Chemical Properties

dark red crystals

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

reaction suitability

core: rhodium
reagent type: catalyst

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Suppliers

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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Bis(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate 99326-34-8
Price: US $2.00-6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-29

Zhuozhou Wenxi import and Export Co., Ltd

Product: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Longyan Tianhua Biological Technology Co., Ltd

Product: Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-10

99326-34-8, Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonateRelated Search:

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bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulfonate

Bis(1,5-cyclooctadiene)

ooctadiene)rhodium(I) trifL

Rhodium(1+), bis[(1,2,5,6-h)-1,5-cyclooctadiene]-, salt withtrifluoromethanesulfonic acid (1:1)

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate ISO 9001：2015 REACH

Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, 1,1,1-trifluoromethanesulfonate (1:1)

Bis(1,5-cyclooctadiene)rhodium(I) trifluromethane sulfonate

Chiralyst P468

Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, 1,1,1-trifluoromethanesulfona…

Bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulphonate

99326-34-8

9326-34-8

CF3O3SC16H24Rh

Rh15C8H122SO3CF3

RhC8H122CF3SO3

C17H24F3O3RhS

C17H24F3O3SRh

RhCOD2OTf

2C8H12CF3O3SRh

Catalysis and Inorganic Chemistry

organometallic complex

Catalysis and Inorganic Chemistry

Chemical Synthesis

Rhodium