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ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

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Product Name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS No.
99326-34-8
Chemical Name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonyms
Bis(1,5-cyclooctadie;Bis(1,5-cyclooctadiene);ooctadiene)rhodium(I) trifL;Bis(1,5-cyclooctadiene)rhodium triflate;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&;Bis(1,5-cyclooctadiene)rhodium(I) triflate;BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I);BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) trifluoromethanesulfonate
CBNumber
CB7722901
Molecular Formula
C17H24F3O3RhS
Formula Weight
468.34
MOL File
99326-34-8.mol
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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Property

Melting point:
159 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in chloroform
form 
crystal
color 
dark red
Water Solubility 
insoluble
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
683159
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
2g
Price
$733
Updated
2024/03/01
Sigma-Aldrich
Product number
530840
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Purity
98%
Packaging
1g
Price
$164.4
Updated
2024/03/01
Alfa Aesar
Product number
039289
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
500mg
Price
$252
Updated
2023/06/20
Alfa Aesar
Product number
039289
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
2g
Price
$982
Updated
2023/06/20
Strem Chemicals
Product number
45-0110
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 99%
Packaging
100mg
Price
$88
Updated
2024/03/01
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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties,Usage,Production

Reaction

  1. Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
  2. Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
  3. Rhodium catalyzed asymmetric synthesis of Sitagliptin
  4. Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones

Chemical Properties

dark red crystals

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Suppliers

Belgium 3 China 118 France 1 Germany 4 India 3 Switzerland 1 United Kingdom 7 United States 24 Global 161
CHEMOS GmbH & Co. KG
Tel
--
Fax
--
Email
chemos@chemos.de
Country
Germany
ProdList
6727
Advantage
58
Alfa Aesar, Thermo Fisher Scientific
Tel
--
Fax
--
Email
es@alfa.com
Country
Germany
ProdList
5123
Advantage
58
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Longyan Tianhua Biological Technology Co., Ltd
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-10
Career Henan Chemical Co
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 9326-34-8
Price
US $1.00/g
Min. Order
100g
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-20

99326-34-8, Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonateRelated Search:

Trifluoromethanesulfonic acid 1,5-Cyclooctadiene Levofloxacin Methylate Rhodium Pefloxacin mesylate Trifluoromethanesulfonic anhydride 1,3-CYCLOOCTADIENE Danofloxacin mesylate BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Trifluoromethane Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

  • Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulphonate99%
  • Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate
  • BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I)
  • BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&
  • Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate,99%
  • Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 99%
  • Bis(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate 98%
  • Bis(1,5-cyclooctadiene)rhodium triflate
  • Bis(1,5-cyclooctadiene)rhodium(I) triflate
  • 1,5-Cyclooctadiene(hydroquinone)rhodiuM(I) tetrafluoroborate,98%
  • Bis(1,5-cyclooctadiene)rhodium(Ⅰ) trifluoromethanesulfonate
  • Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate,97%
  • Bis(1,5-cyclooctadie
  • Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 98+%
  • Bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulphonate 98+%
  • bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulfonate
  • Bis(1,5-cyclooctadiene)
  • ooctadiene)rhodium(I) trifL
  • Rhodium(1+), bis[(1,2,5,6-h)-1,5-cyclooctadiene]-, salt withtrifluoromethanesulfonic acid (1:1)
  • Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate ISO 9001：2015 REACH
  • Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, 1,1,1-trifluoromethanesulfonate (1:1)
  • Bis(1,5-cyclooctadiene)rhodium(I) trifluromethane sulfonate
  • 99326-34-8
  • 9326-34-8
  • CF3O3SC16H24Rh
  • Rh15C8H122SO3CF3
  • RhC8H122CF3SO3
  • C17H24F3O3RhS
  • C17H24F3O3SRh
  • RhCOD2OTf
  • 2C8H12CF3O3SRh
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium