Reaction
ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Reaction
Product Name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS No.
99326-34-8
Chemical Name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonyms
Bis(1,5-cyclooctadie;Bis(1,5-cyclooctadiene);ooctadiene)rhodium(I) trifL;Bis(1,5-cyclooctadiene)rhodium triflate;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&;Bis(1,5-cyclooctadiene)rhodium(I) triflate;BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I);BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) trifluoromethanesulfonate
CBNumber
CB7722901
Molecular Formula
C17H24F3O3RhS
Formula Weight
468.34
MOL File
99326-34-8.mol
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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Property

Melting point:
159 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in chloroform
form 
crystal
color 
dark red
Water Solubility 
insoluble
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
683159
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
2g
Price
$733
Updated
2024/03/01
Sigma-Aldrich
Product number
530840
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Purity
98%
Packaging
1g
Price
$164.4
Updated
2024/03/01
Alfa Aesar
Product number
039289
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
500mg
Price
$252
Updated
2023/06/20
Alfa Aesar
Product number
039289
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Packaging
2g
Price
$982
Updated
2023/06/20
Strem Chemicals
Product number
45-0110
Product name
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 99%
Packaging
100mg
Price
$88
Updated
2024/03/01
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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties,Usage,Production

Reaction

  1. Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
  2. Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
  3. Rhodium catalyzed asymmetric synthesis of Sitagliptin
  4. Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones

Chemical Properties

dark red crystals

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

reaction suitability

core: rhodium
reagent type: catalyst

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Beijing VSciChem Technology Co., Ltd.
Tel
13811761079
Email
vscichem@163.com
Country
China
ProdList
251
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
291
Advantage
62
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Longyan Tianhua Biological Technology Co., Ltd
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 99326-34-8
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-10
Career Henan Chemical Co
Product
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 9326-34-8
Price
US $1.00/g
Min. Order
100g
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-20

99326-34-8, Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonateRelated Search:


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  • 99326-34-8
  • 9326-34-8
  • CF3O3SC16H24Rh
  • Rh15C8H122SO3CF3
  • RhC8H122CF3SO3
  • C17H24F3O3RhS
  • C17H24F3O3SRh
  • RhCOD2OTf
  • 2C8H12CF3O3SRh
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium