ChemicalBook > CAS DataBase List > 2-Picoline-N-oxide

2-Picoline-N-oxide

Product Name
2-Picoline-N-oxide
CAS No.
931-19-1
Chemical Name
2-Picoline-N-oxide
Synonyms
2-picoline-oxide;-Picoline N-oxide;a-Picoline N-oxide;a-Picoline 1-oxide;2-PICOLINE-N-OXIDE;2-Picoline, 1-oxide;Alfa picoline oxide;2-Picoline-N-oxide,98%;alpha-Picoline 1-oxide;ALPHA-PICOLINE N-OXIDE
CBNumber
CB7748015
Molecular Formula
C6H7NO
Formula Weight
109.13
MOL File
931-19-1.mol
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2-Picoline-N-oxide Property

Melting point:
41-45 °C(lit.)
Boiling point:
259-261 °C
Density 
1.1143 (rough estimate)
refractive index 
1.5444 (estimate)
Flash point:
>230 °F
pka
pK1:1.029(+1) (25°C)
form 
powder to lump to clear liquid
color 
White or Colorless to Light yellow
Water Solubility 
soluble
Sensitive 
Hygroscopic
BRN 
106916
CAS DataBase Reference
931-19-1(CAS DataBase Reference)
NIST Chemistry Reference
Pyridine, 2-methyl-, 1-oxide(931-19-1)
EPA Substance Registry System
2-Methylpyridine-1-oxide (931-19-1)
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Safety

Hazard Codes 
Xi,Xn,F
Risk Statements 
36/37/38-20/21/22-10
Safety Statements 
26-36-24/25-16
WGK Germany 
3
F 
3
TSCA 
Yes
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
P42207
Product name
2-Methylpyridine N-oxide
Purity
≥96%
Packaging
100g
Price
$140
Updated
2023/06/20
TCI Chemical
Product number
P0418
Product name
2-Methylpyridine N-Oxide
Purity
>99.0%(GC)
Packaging
25g
Price
$34
Updated
2024/03/01
TCI Chemical
Product number
P0418
Product name
2-Methylpyridine N-Oxide
Purity
>99.0%(GC)
Packaging
500g
Price
$247
Updated
2024/03/01
Alfa Aesar
Product number
L04488
Product name
2-Picoline N-oxide, 98%
Packaging
25g
Price
$26.65
Updated
2024/03/01
Alfa Aesar
Product number
L04488
Product name
2-Picoline N-oxide, 98%
Packaging
100g
Price
$73.65
Updated
2024/03/01
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2-Picoline-N-oxide Chemical Properties,Usage,Production

Chemical Properties

light yellow to brown crystalline low melting mass

Uses

2-Picoline N-oxide is used in proteomics research. Also used as pharmaceutical intermediates.

Application

2-Methylpyridine 1-oxide is a useful building block for organic synthesis.

Definition

ChEBI: Picoline N-oxide is a member of methylpyridines and a member of pyridine N-oxides.

Purification Methods

Purify the N-oxide by fractional distillation, and it can be recrystallised from *C6H6/hexane but is hygroscopic. [Bullitt & Maynard J Am Chem Soc 76 1370 1954, Ross et al. J Am Chem Soc 78 3625 1956, IR: Wiley & SlaymAker J Am Chem Soc 79 2233 1957.] The picrate has m 125-126.5o (from EtOH) [Boekelheide & Linn J Am Chem Soc 76 1286 1954]. The phthalate has m 115-116o (from EtOH) [den Hertog et al. Recl Trav Chim Pays-Bas 70 591 1951.]. [Beilstein 20 III/IV 2689, 20/5 V 479.]

2-Picoline-N-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

4-(DIMETHYLAMINO)PYRIDINE-2-CARBOXYLIC ACID
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2-Picoline-N-oxide Suppliers

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View Lastest Price from 2-Picoline-N-oxide manufacturers

Career Henan Chemical Co
Product
2-Picoline-N-oxide 931-19-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2019-05-24

931-19-1, 2-Picoline-N-oxideRelated Search:

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  • 2-PICOLINE-N-OXIDE
  • 2-METHYLPYRIDINE N-OXIDE
  • 2-METHYLPYRIDINE 1-OXIDE
  • 2-PICOLINE N-OXIDE, 96+%
  • Alfa picoline oxide
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  • Pyridinium, 1-hydroxy-2-methyL
  • 2-Picoline-N-oxide ISO 9001：2015 REACH
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