ChemicalBook > CAS DataBase List > 4-AMINO-2-METHOXY-BENZONITRILE

4-AMINO-2-METHOXY-BENZONITRILE

Product Name: 4-AMINO-2-METHOXY-BENZONITRILE
CAS No.: 7251-09-4
Chemical Name: 4-AMINO-2-METHOXY-BENZONITRILE
Synonyms: NSC 30614;5-Amino-2-cyanoanisole;4-Cyano-3-Methoxyaniline;4-AMINO-2-METHOXY-BENZONITRILE;Benzonitrile,4-aMino-2-Methoxy-;4-Amino-2-methoxybenzonitrile >
CBNumber: CB7797806
Molecular Formula: C8H8N2O
Formula Weight: 148.16
MOL File: 7251-09-4.mol

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4-AMINO-2-METHOXY-BENZONITRILE Property

Melting point:: 102℃
Boiling point:: 351.2±27.0 °C(Predicted)
Density: 1.17±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 1.30±0.10(Predicted)
color: White to Light yellow
InChI: InChI=1S/C8H8N2O/c1-11-8-4-7(10)3-2-6(8)5-9/h2-4H,10H2,1H3
InChIKey: KTDRJLRJAHBQDQ-UHFFFAOYSA-N
SMILES: C(#N)C1=CC=C(N)C=C1OC

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Safety

HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical

Product number: A2785
Product name: 4-Amino-2-methoxybenzonitrile
Purity: >97.0%(GC)(T)
Packaging: 1g
Price: $151
Updated: 2025/07/31

TCI Chemical

Product number: A2785
Product name: 4-Amino-2-methoxybenzonitrile
Purity: >97.0%(GC)(T)
Packaging: 5g
Price: $454
Updated: 2025/07/31

TRC

Product number: A898160
Product name: 4-Amino-2-methoxybenzonitrile
Packaging: 500mg
Price: $110
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA139505
Product name: 4-Amino-2-methoxybenzonitrile
Packaging: 250mg
Price: $52.5
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA139505
Product name: 4-Amino-2-methoxybenzonitrile
Packaging: 500mg
Price: $90
Updated: 2021/12/16

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4-AMINO-2-METHOXY-BENZONITRILE Chemical Properties,Usage,Production

Synthesis

101084-96-2

7251-09-4

1. 2-Methoxy-4-nitrobenzonitrile (750 mg, 4.21 mmol) and palladium catalyst (50 mg, 0.47 mmol) were dissolved in methanol (15 mL) at room temperature. 2. The reaction system was subjected to a hydrogen atmosphere (1 atm) with continuous stirring for 48 h. 3. Upon completion of the reaction the palladium catalyst was removed by filtration. 4. The filtrate was concentrated under reduced pressure to give the brownish-red powdery product 4-amino-2-methoxybenzonitrile (679 mg, 4.58 mmol, quantitative yield). 5. The structure of the product was determined by 1H-anionic digestion. 6. The filtrate was concentrated under reduced pressure to give a brown-red powdery product, 4-amino-2-methoxybenzonitrile (679 mg, 4.58 mmol, quantitative yield). 5. The structure of the product was confirmed by 1H-NMR (300 MHz, DMSO-d6): δ 3.32 (3H, s), 6.05-6.29 (4H, m), 7.23 (1H, d, J = 8.3 Hz). ).

References

[1] Patent: EP2759533, 2014, A1. Location in patent: Paragraph 0484; 0485
[2] Synthesis, 2006, # 19, p. 3316 - 3340
[3] Chemistry - A European Journal, 2014, vol. 20, # 31, p. 9504 - 9509
[4] Chemical and Pharmaceutical Bulletin, 2014, vol. 62, # 10, p. 979 - 988
[5] Patent: US2009/42967, 2009, A1. Location in patent: Page/Page column 22

4-AMINO-2-METHOXY-BENZONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-2-METHOXY-BENZONITRILE Suppliers

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View Lastest Price from 4-AMINO-2-METHOXY-BENZONITRILE manufacturers

Career Henan Chemical Co

Product: 4-AMINO-2-METHOXY-BENZONITRILE 7251-09-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95%
Supply Ability: 500KG
Release date: 2018-08-19

7251-09-4, 4-AMINO-2-METHOXY-BENZONITRILERelated Search:

4-amino-2-methoxybenzonitrile 6-AMINO-5-METHYLNICOTINONITRILE (4-CYANO-3-METHOXY-PHENYL)-CARBAMIC ACID PHENYL ESTER 2-ETHOXY-4-NITROBENZONITRILE 4-amino-2,6-dimethoxybenzonitrile CI NO 37170 4-nitro-2-(trifluoromethoxy)benzonitrile 4-AMINO-2-METHOXY-BENZONITRILE 4-amino-2-(trifluoromethoxy)benzonitrile 2,5-dimethoxy-4-nitrobenzonitrile 2,6-dimethoxy-4-nitrobenzonitrile 2-CYANO-5-NITROANISOLE

4-AMINO-2-METHOXY-BENZONITRILE

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7251-09-4