METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

Product Name: METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
CAS No.: 369-26-6
Chemical Name: METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
Synonyms: Methyl 3-amino-4-fluorobenzoate;Methyl 3-amino-4-fluorobenzoate 99%;2-Fluoro-5-(methoxycarbonyl)aniline;METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE;Benzoic acid, 3-amino-4-fluoro-, methyl ester;methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O);3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI);Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)
CBNumber: CB7830853
Molecular Formula: C8H8FNO2
Formula Weight: 169.15
MOL File: 369-26-6.mol

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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Property

Melting point:: 66-69
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: crystalline solid
color: Beige

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2922498590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M328678
Product name: Methyl3-amino-4-fluorobenzoate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: PC7646
Product name: Methyl3-amino-4-fluorobenzoate
Purity: 99%
Packaging: 1g
Price: $10
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4658-3-W0
Product name: Methyl 3-amino-4-fluorobenzoate
Packaging: 1g
Price: $16
Updated: 2021/12/16

Matrix Scientific

Product number: 047241
Product name: Methyl 3-amino-4-fluorobenzenecarboxylate
Purity: >95%
Packaging: 1g
Price: $21
Updated: 2021/12/16

Apolloscientific

Product number: PC7646
Product name: Methyl3-amino-4-fluorobenzoate
Purity: 99%
Packaging: 5g
Price: $31
Updated: 2021/12/16

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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Chemical Properties,Usage,Production

Synthesis

329-59-9

369-26-6

Step B: Synthesis of methyl 3-amino-4-fluorobenzoate; Methyl 4-fluoro-3-nitrobenzoate (6.57 g, 33 mmol) was dissolved in EtOAc (75 mL) and 10% palladium carbon catalyst (0.66 g) was added. The reaction mixture was transferred to a Fisher-Porter flask and mounted on a hydrogenation unit. The flask was charged with hydrogen (25 psi) and the reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad, followed by concentration of the filtrate to give a yellow oily product which deepened in color on standing and in quantitative yield (5.51 g, 33 mmol). Mass spectrometry (ESI) showed m/z = 170 [M + H]+.

References

[1] Patent: WO2009/76140, 2009, A1. Location in patent: Page/Page column 186
[2] Journal of Organic Chemistry, 1990, vol. 55, # 7, p. 2034 - 2044
[3] Synlett, 2010, # 20, p. 3019 - 3022
[4] Patent: WO2010/126922, 2010, A1. Location in patent: Page/Page column 62
[5] Zhurnal Organicheskoi Khimii, 1972, vol. 8, p. 803,804; engl. Ausg. S. 813, 814

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Suppliers

China 82 France 1 Germany 1 India 3 Ukraine 2 United Kingdom 3 United States 11 Global 103

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
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Energy Chemical

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Nanjing Chemlin Chemical Co., Ltd

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Shanghai Hanhong Scientific Co.,Ltd.

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Shanghai civi chemical technology co.,Ltd

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9ding chemical ( Shanghai) Limited

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Shanghai Raise Chemical Technology Co.,Ltd

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Fax: +86-021-33847795
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View Lastest Price from METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Methyl 3-amino-4-fluorobenzoate 369-26-6
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-25

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl3-amino-4-fluorobenzenecarboxylate 369-26-6
Price: US $0.00-0.00/KG
Min. Order: 5mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-07

Shaanxi Dideu Medichem Co. Ltd

Product: 4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid 56447-54-2
Price: US $0.00-0.00/KG
Min. Order: 5mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-07

369-26-6, METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATERelated Search:

2,6-Dioxopiperidine-3-ammonium chloride 3-AMINO-1H-PYRROLE-2,4-DICARBOXYLIC ACID DIETHYL ESTER 3-AMINO-2-PIPERIDINONE HYDROCHLORIDE METHYL 4-AMINO-3-FLUOROBENZENECARBOXYLATE methyl 4-fluoro-3-(3-oxobutanamido)benzoate Methyl 5-amino-2,4-difluorobenzoate METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE METHYL 2-CHLORO-4-FLUORO-5-NITROBENZOATE Methyl 4-fluoro-3-nitrobenzoate 2,4-DIFLUORO-5-NITROBENZOIC ACID METHYL ESTER 4-FLUORO-3-NITROMETHYLBENZOATE, [CARBONYL-14C]- Ethyl 3-amino-4-fluorobenzoate

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

Methyl 3-amino-4-fluorobenzoate

Methyl 3-amino-4-fluorobenzoate 99%

methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O)

2-Fluoro-5-(methoxycarbonyl)aniline

Benzoic acid, 3-amino-4-fluoro-, methyl ester

Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)

3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI)

369-26-6