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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

Product Name
METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
CAS No.
369-26-6
Chemical Name
METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
Synonyms
Methyl 3-amino-4-fluorobenzoate;Methyl 3-amino-4-fluorobenzoate 99%;2-Fluoro-5-(methoxycarbonyl)aniline;METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE;Benzoic acid, 3-amino-4-fluoro-, methyl ester;methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O);3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI);Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)
CBNumber
CB7830853
Molecular Formula
C8H8FNO2
Formula Weight
169.15
MOL File
369-26-6.mol
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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Property

Melting point:
66-69
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
crystalline solid
color 
Beige
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Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M328678
Product name
Methyl3-amino-4-fluorobenzoate
Packaging
100mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
4658-3-W0
Product name
Methyl 3-amino-4-fluorobenzoate
Packaging
5G
Price
$50
Updated
2021/12/16
AK Scientific
Product number
W5803
Product name
Methyl3-Amino-4-fluorobenzoate
Packaging
1g
Price
$67
Updated
2021/12/16
Matrix Scientific
Product number
047241
Product name
Methyl 3-amino-4-fluorobenzenecarboxylate
Purity
>95%
Packaging
5g
Price
$71
Updated
2021/12/16
Apolloscientific
Product number
PC7646
Product name
Methyl3-amino-4-fluorobenzoate
Purity
99%
Packaging
25g
Price
$103
Updated
2021/12/16
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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Chemical Properties,Usage,Production

Synthesis

329-59-9

369-26-6

Step B: Synthesis of methyl 3-amino-4-fluorobenzoate; Methyl 4-fluoro-3-nitrobenzoate (6.57 g, 33 mmol) was dissolved in EtOAc (75 mL) and 10% palladium carbon catalyst (0.66 g) was added. The reaction mixture was transferred to a Fisher-Porter flask and mounted on a hydrogenation unit. The flask was charged with hydrogen (25 psi) and the reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad, followed by concentration of the filtrate to give a yellow oily product which deepened in color on standing and in quantitative yield (5.51 g, 33 mmol). Mass spectrometry (ESI) showed m/z = 170 [M + H]+.

References

[1] Patent: WO2009/76140, 2009, A1. Location in patent: Page/Page column 186
[2] Journal of Organic Chemistry, 1990, vol. 55, # 7, p. 2034 - 2044
[3] Synlett, 2010, # 20, p. 3019 - 3022
[4] Patent: WO2010/126922, 2010, A1. Location in patent: Page/Page column 62
[5] Zhurnal Organicheskoi Khimii, 1972, vol. 8, p. 803,804; engl. Ausg. S. 813, 814

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE Suppliers

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View Lastest Price from METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Methyl 3-amino-4-fluorobenzoate 369-26-6
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-06-25
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl3-amino-4-fluorobenzenecarboxylate 369-26-6
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-07
Shaanxi Dideu Medichem Co. Ltd
Product
4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid 56447-54-2
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-07

369-26-6, METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATERelated Search:

2,6-Dioxopiperidine-3-ammonium chloride 3-AMINO-1H-PYRROLE-2,4-DICARBOXYLIC ACID DIETHYL ESTER 3-AMINO-2-PIPERIDINONE HYDROCHLORIDE METHYL 4-AMINO-3-FLUOROBENZENECARBOXYLATE methyl 4-fluoro-3-(3-oxobutanamido)benzoate Methyl 5-amino-2,4-difluorobenzoate METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE METHYL 2-CHLORO-4-FLUORO-5-NITROBENZOATE Methyl 4-fluoro-3-nitrobenzoate 2,4-DIFLUORO-5-NITROBENZOIC ACID METHYL ESTER 4-FLUORO-3-NITROMETHYLBENZOATE, [CARBONYL-14C]- Ethyl 3-amino-4-fluorobenzoate

  • METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE
  • Methyl 3-amino-4-fluorobenzoate
  • Methyl 3-amino-4-fluorobenzoate 99%
  • methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O)
  • 2-Fluoro-5-(methoxycarbonyl)aniline
  • Benzoic acid, 3-amino-4-fluoro-, methyl ester
  • Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)
  • 3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI)
  • 369-26-6