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Dichloroacetonitrile

Product Name
Dichloroacetonitrile
CAS No.
3018-12-0
Chemical Name
Dichloroacetonitrile
Synonyms
DICHLOROACETONITRILE;dichloro-acetonitril;Acetnitrile,dichloro-;dichloromethylcyanide;25kgs kfaft paper bag;Dichloromethyl cyanide;Dichloroacetonitrile>1,1-Dichlorocarbonitrile;2,2-Dichloroethanenitrile;Dichloroacetonitrile, 98+%
CBNumber
CB7853456
Molecular Formula
C2HCl2N
Formula Weight
109.94
MOL File
3018-12-0.mol
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Dichloroacetonitrile Property

Boiling point:
110-112 °C(lit.)
Density 
1.369 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.44(lit.)
Flash point:
96 °F
storage temp. 
0-6°C
solubility 
soluble in Methanol
color 
Colorless to Light yellow to Light orange
Specific Gravity
1.37
BRN 
1739029
Exposure limits
NIOSH: IDLH 25 mg/m3
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
3018-12-0(CAS DataBase Reference)
NIST Chemistry Reference
Acetonitrile, dichloro-(3018-12-0)
IARC
3 (Vol. 52, 71) 1999
EPA Substance Registry System
Dichloroacetonitrile (3018-12-0)
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Safety

Hazard Codes 
C
Risk Statements 
10-22-34
Safety Statements 
26-36/37/39-45-25-16
RIDADR 
UN 2920 8/PG 2
WGK Germany 
3
RTECS 
AL8465000
9-19
HazardClass 
3
PackingGroup 
II
HS Code 
29269090
Hazardous Substances Data
3018-12-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
125954
Product name
Dichloroacetonitrile
Purity
98%
Packaging
25g
Price
$101
Updated
2024/03/01
TCI Chemical
Product number
D2510
Product name
Dichloroacetonitrile
Purity
>98.0%(GC)
Packaging
25g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
D2510
Product name
Dichloroacetonitrile
Purity
>98.0%(GC)
Packaging
500g
Price
$857
Updated
2024/03/01
Alfa Aesar
Product number
A10612
Product name
Dichloroacetonitrile, 98+%
Packaging
5g
Price
$25.65
Updated
2024/03/01
Alfa Aesar
Product number
A10612
Product name
Dichloroacetonitrile, 98+%
Packaging
25g
Price
$78.65
Updated
2024/03/01
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Dichloroacetonitrile Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Dichloroacetonitrile can be used as a reactant to prepare:

  • Chiral α, α-dichloro-β-aminonitriles via Pd-catalyzed enantioselective Mannich-type reaction with imines.
  • α, α-dialkyl-substituted nitriles by an alkylation reaction with trialkylboranes in the presence of phenoxide base as a base.
  • Halogenated pyridines via copper-catalyzed reaction with methacrolein.
  • α,α-dichloro-β-hydroxy nitriles by condensation reaction with aldehydes and ketones in the presence of an alkoxide base.
  • Selenium heterocycle derivatives via Diels–Alder cyclization with selenoaldehydes.
  • Dichloroacetonitrile can also be used to develop an efficient method for the extraction and determination of common volatile halogenated disinfection by-products using the static headspace technique coupled with gas chromatography-mass spectrometry.

Definition

ChEBI: Dichloroacetonitrile is an aliphatic nitrile.

General Description

Clear liquid.

Air & Water Reactions

Burns slowly, emitting a thick black smoke, but will not flash . Water soluble.

Reactivity Profile

Dichloroacetonitrile is a halogenated nitrile. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition Dichloroacetonitrile emits toxic fumes of chlorine, cyanides and nitrogen oxides.

Fire Hazard

Dichloroacetonitrile is probably combustible.

Biochem/physiol Actions

Dichloroacetonitrile is direct-acting mutagen and induces DNA strand breaks in cultured human lymphoblastic cells. It induces apoptosis or necrosis in murine macrophage cell line via reactive oxygen intermediates-mediated oxidative mechanisms of cellular damage.

Purification Methods

Purify the nitrile by distillation or by gas chromatography. [Beilstein 2 IV 506.] FLAMMABLE.

Dichloroacetonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Dichloroacetonitrile manufacturers

Career Henan Chemical Co
Product
Dichloroacetonitrile 3018-12-0
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-21
Career Henan Chemical Co
Product
Dichloroacetonitrile 3018-12-0
Price
US $2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-23

3018-12-0, DichloroacetonitrileRelated Search:


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