ChemicalBook > CAS DataBase List > 1-Chloro-2-butene

1-Chloro-2-butene

Product Name
1-Chloro-2-butene
CAS No.
591-97-9
Chemical Name
1-Chloro-2-butene
Synonyms
CrotyL;Crotylchlorid;krotylchlorid;CROTYL CHLORIDE;1-Chlorbut-2-en;-Chloro-butylene;1-chloro-2-buten;1-chlorobut-2-ene;2-butenylchloride;1-CHLORO-2-BUTENE
CBNumber
CB7853911
Molecular Formula
C4H7Cl
Formula Weight
90.55
MOL File
591-97-9.mol
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1-Chloro-2-butene Property

Melting point:
-65°C
Boiling point:
85-86 °C(lit.)
Density 
0.923 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.430
Flash point:
-12°C
storage temp. 
0-6°C
solubility 
water: soluble14g/L at 20°C
form 
clear liquid
color 
Colorless to Light yellow
Water Solubility 
999mg/L(temperature not stated)
Merck 
14,2130
BRN 
605304
Stability:
Stable. Highly flammable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
591-97-9(CAS DataBase Reference)
NIST Chemistry Reference
2-Butene, 1-chloro-(591-97-9)
EPA Substance Registry System
2-Butene, 1-chloro- (591-97-9)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-22-34-43
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
2
RTECS 
EM4264000
19
HazardClass 
3
PackingGroup 
II
HS Code 
29049090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
28115
Product name
Crotyl chloride
Purity
technical, (
Packaging
100ml
Price
$280
Updated
2024/03/01
TCI Chemical
Product number
C0145
Product name
Crotyl Chloride (cis- and trans- mixture)
Purity
>95.0%(GC)
Packaging
25mL
Price
$111
Updated
2024/03/01
TCI Chemical
Product number
C1686
Product name
Crotyl Chloride (cis- and trans- mixture, contains ca. 25% 3-Chloro-1-butene)
Purity
>62.0%(GC)
Packaging
25mL
Price
$44
Updated
2024/03/01
TCI Chemical
Product number
C1686
Product name
Crotyl Chloride (cis- and trans- mixture, contains ca. 25% 3-Chloro-1-butene)
Purity
>62.0%(GC)
Packaging
500mL
Price
$233
Updated
2024/03/01
TCI Chemical
Product number
C0145
Product name
Crotyl Chloride (cis- and trans- mixture)
Purity
>95.0%(GC)
Packaging
100mL
Price
$228
Updated
2024/03/01
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1-Chloro-2-butene Chemical Properties,Usage,Production

Description

1-Chloro-2-butene is a butenylating agent via Grignard and other organometallic reagents, organoborane compounds, other nucleophiles, and organosilane compounds.

Chemical Properties

colourless liquid

Uses

Crotyl chloride has been used:

  • to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
  • in the preparation of (E)-crotyltrichlorosilane

Preparation

pure isomers of 1-Chloro-2-butene can be prepared by chloride displacement of corresponding alcohols via Ph3P in various solvents, and other chlorinating agents.

General Description

Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.

1-Chloro-2-butene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Chloro-2-butene Suppliers

Aladdin Scientific
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View Lastest Price from 1-Chloro-2-butene manufacturers

Speranza Chemical Co., Ltd.
Product
Crotyl Chloride 591-97-9
Price
US $20.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
300 Tons/ year
Release date
2019-12-25
Hebei Chuanghai Biotechnology Co,.LTD
Product
1-chloro-2-butene 591-97-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2024-08-20
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-Chloro-2-butene 591-97-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

591-97-9, 1-Chloro-2-buteneRelated Search:


  • (2E)-1-Chloro-2-butene
  • 1-chloro-2-buten
  • 1-chloro-but-2-ene
  • 1-chlorobut-2-ene
  • 2-Butene,1-chloro-
  • 2-Butenyl chloride
  • 2-butenylchloride
  • alpha-Chloro-beta-butylene
  • -Chloro-butylene
  • Crotylchlorid
  • gamma-Methallyl chloride
  • gamma-methallylchloride
  • Crotyl Chloride (<i>cis</i>- and <i>trans</i>- mixture)
  • Crotyl Chloride (cis- and trans- mixture, contains 38% 3-Chloro-1-butene at maximum)
  • 1-Chloro-2-butene, 95%, mixture of cis and trans
  • Crotyl Chloride (<i>cis</i>- and <i>trans</i>- mixture, contains <i>ca</i>. 25% 3-Chloro-1-butene)
  • 1-CHLORO-2-BUTENE
  • 1-CHLORO-2-BUTYLENE
  • GAMMA-METHYLALLYL CHLORIDE
  • CIS,TRANS-CROTYL CHLORIDE
  • CIS,TRANS-1-CHLORO-2-BUTENE
  • (E)CROTYL CHLORIDE
  • CROTYL CHLORIDE
  • krotylchlorid
  • α-Chloro-β-butylene
  • 2-BUTEN-1-YL CHLORIDE
  • TRANS-CROTYL CHLORIDE
  • Crotyl chloride, tech., 70%
  • 1-Chlorbut-2-en
  • CROTYL CHLORIDE (CIS- AND TRANS-MIXTURE)
  • Crotyl Chloride (cis- and trans- mixture, contains ca. 25% 3-Chloro-1-butene)
  • T-Methallyl chloride
  • 1-chloro-2-butene (crotyl chloride)
  • Crotyl chloride,70%,tech.
  • Crotyl chloride (cis- and trans- mixture) ,95%
  • Crotyl chloride ,90%
  • 2-Buten-1-yl Chloride 1-Chloro-2-butene
  • 1-Chloro-2-butene, Mixture of cis and trans
  • CrotyL
  • Crotyl Chloride (cis- and trans- mixture)&gt
  • Crotyl Chloride (cis- and trans- mixture, contains ca. 25% 3-Chloro-1-butene)&gt
  • 2-Buten-1-yl Chloride (cis- and trans- mixture)
  • 591-97-9
  • CH3CHCHCH2Cl
  • ClCH2CHCHCH3
  • HALOGEN
  • Organic Building Blocks
  • Acyclic
  • Alkenes
  • Building Blocks